Search results for "Vapo"
showing 10 items of 1217 documents
The Scope of Zinc Oxide Bulk Growth
2005
The techniques classically used for the growth of bulk ZnO crystals, melt-growth, vapour growth, solution-growth and hydrothermal growth, are reviewed. In the case of vapor growth, numerical simulations suggest that such species as H2 + H2O, CH4, Zn, C or Fe could act as sublimation activators. The electrical and structural properties of crystals obtained by these various techniques are compared.
The influence of water and of alkali promotor on the carbon number distribution of fischer-tropsch products formed over iron catalysts
1987
The carbon number distribution of Fischer-Tropsch products formed over an alkalized precipitated iron catalyst has been studied as a function of the water vapor pressure of the synthesis gas. The carbon number distribution of formed hydrocarbons is characterized by a bimodal Schulz-Flory distribution of growth probabilities P1 ≈ 0.6 and P2 ≈ 0.87 attributed to unpromoted and promoted (alkalized) sites on the catalyst surface. Promoted sites are more stable with respect to oxidation (deactivation) by water than unpromoted sites. The growth probability of unpromoted sites decreases with increasing ratio P/P — Studies using Mossbauer spectroscopy have shown that iron foils treated with water c…
Chemical Vapour Deposition of Pure Titanium Using a Heated Wire Reactor and TiI4
2017
Master's thesis Renewable Energy ENE500 - University of Agder 2017 An experimental reactor system has been optimized throughout a series of experiments for making titanium tubes from an electrically heated titanium coil filament by a chemical vapour deposition method, based on the original van Arkel-de Boer -process. The titanium is thermally decomposed on the filament from vapourized titanium tetraiodide in a method not seen in similar experiments. The small-scale reactor is built for this purpose, and the associated systems and methods are developed to maintain the optimal conditions for a continuous metal deposition. A filament current control system is made of an Arduino micro-controlle…
A laboratory study on the scavenging of SO2 by snow crystals
1990
Abstract A laboratory experiment is described where the uptake of SO2 by dendritic snow crystals was studied. In a first experimental series the uptake of SO2 was investigated during the growth of the snow crystals from water vapor with and without the presence of H2O2 in the air. In a second series of experiments we studied the uptake of SO2 by snow crystals which had completed their growth. The results of our experiments showed that under both conditions SO2 became scavenged by snow crystals. The uptake of SO2 was particularly pronounced during the growth of the snow crystals, and at temperatures close to 0°C where a quasi-liquid layer exists at the surface of ice. As expected, the SO2 up…
Predicting mass fluxes in the pervaporation process using Maxwell-Stefan diffusion coefficients
2018
Abstract In the past decades, it has been proven that pervaporation is an effective and energy-efficient membrane process for the separation of liquids that are difficult to separate in classical processes. The demand for new process applications has increased the need for mass transfer simulation methods, considering the interactions between the system components and the influence of process parameters on the permeation fluxes and at the same time requiring as few experiments as possible. The aim of the study was to find out whether the calculation of mass fluxes of multicomponent fluids based on the system of generalized Maxwell-Stefan equations (GMSE), using Maxwell-Stefan (M-S) diffusio…
Water vapour adsorption onto Ca2+ Camp–Berteau montmorillonite and comparison with properties of Na+ sample
2004
Abstract In this paper, we present an analysis of the adsorbed amounts and adsorption heats of water vapour of Ca2+ Camp–Berteau montmorillonite. Measurements were obtained at 298 K using thermogravimetry and calorimetry as a function of relative pressure and the study was completed by the adsorption of nitrogen at 77 K. Experimental data were analysed with BET and t-method theories and compared with those of the Na+ sample. A correlation was shown between models and two domains observed on the calorimetric curves. These domains have been attributed to a multilayer equivalent adsorption. However, the determination of the surface area of clays remains a difficulty. So, the areas of interlaye…
MoO (x≤2) ultrathin film growth from reactions between metallic molybdenum and TiO2 surfaces
2001
Abstract Exposures to oxygen at room temperature and annealings under vacuum were carried out on deposits obtained from molybdenum interacting with (1 1 0) TiO 2 surfaces in order to obtain molybdenum oxide ultra thin films. Exposures to oxygen at room temperature show that the interfacial molybdenum oxide layers resulting from the TiO 2 /Mo interactions are inactive towards oxygen whereas the metallic molybdenum clusters, which grew on top of the interfacial layers, oxidise into MoO 3 . Besides, during annealings under vacuum, substrate oxygen anions can diffuse into the deposit. Thus, between 400 and 500°C, molybdenum oxide layers are progressively oxidised into MoO 2 . Moreover, from the…
Multiphase chemistry in a microphysical radiation fog model—A numerical study
1993
A microphysical radiation fog model is coupled with a detailed chemistry module to simulate chemical reactions in the gas phase and in fog water during a radiation fog event. In the chemical part of the model the microphysical particle spectrum is subdivided into three size classes corresponding to non-activated aerosol particles, small and large fog droplets. Chemical reactions in the liquid phase are separately calculated in the small and in the large droplet size class. The impact of the chemical constitution of activated aerosols on fogwater chemistry is considered in the model simulations. The mass transfer of chemical species between the gas phase and the two liquid phases is treated …
Numerical study of the ZnO growth by MOCVD
2004
Abstract In order to analyze the growth of zinc oxide by metalorganic chemical vapor deposition, a numerical model has been developed to simulate the gas flow in a horizontal reactor. A two-inlet system, one for the Zn precursor and the other for the oxygen one, has been studied in the framework of this numerical simulation. This model takes into account the momentum conservation equation coupled with the heat transfer and mass transport of chemical species. Different Zn precursors, DiethylZinc (DEZn), DimethylZinc (DMZn) and DimethylZinc-TriethylAmine (DMZn-TEA) and oxygen precursors, ( tert -butanol, iso -propanol and acetone) as well as carrier gases (H 2 and N 2 ) have been considered. …
DSC study on hyaluronan drying and hydration
2011
Abstract The processes of hyaluronan (HYA) drying and hydration were studied using differential scanning calorimetry. In the first approach the isoconversional Kissinger–Akahita–Sunose (KAS) method was applied in order to determine actual activation energies of evaporation of pure water and water from concentrated HYA solutions. Since the evaporation is a single-step process, the activation energies for pure water provided results consistent with tabulated values of evaporation enthalpies. In the course of water evaporation from hyaluronan solution a break in increasing enthalpy followed by a decrease below 0.34 g of water per 1 g of HYA was observed. This result confirmed earlier observati…