Search results for "Viscoelasticity"
showing 10 items of 224 documents
Modulating carbohydrate-based hydrogels as viscoelastic lubricant substitute for articular cartilages
2017
Viscosupplementation is a therapeutic approach for osteoarthritis treatment, where the synovial fluid, the natural lubricant of the joints, is replaced by viscoelastic solutions with rheological properties comparable or better than the starting material. This study presents the development of an innovative platform for viscosupplementation, based on the optimization of polysaccharide-based colloidal hydrogel, aiming to reduce on-site enzyme degradation and enhance the possibility of hyaluronic acid substitution with alternative biomaterials. Catanionic vesicles are proposed as physical crosslinker that can guarantee the formation of a 'soft', tunable network, offering a dual-therapeutic app…
Dynamic mode rheology of cement and tricalcium silicate pastes from mixing to setting
2001
Dynamic mode rheometry was used to study the evolution of the structure of cement and pure tricalcium silicate pastes from mixing up to setting and even after setting, together with the nature of the forces responsible for the mechanical properties of the pastes. A special mixer-type tool was used to study rheology during the very first minutes following the end of mixing, which are out of reach with classical tools. Both kinds of pastes have the same behavior. It was found that the main evolution of the structure of the pastes occurs during the very first minutes following the end of mixing, while there is no change in interparticular forces up to setting and even a few hours later. Settin…
Creep and recovery of epoxy/MWCNT nanocomposites
2012
Abstract Creep and creep–recovery of epoxy/multi-wall carbon nanotube (MWCNT) composites was studied in a wide range of applied loads in order to evaluate the contribution of nanotubes on the time-dependent behaviour of the epoxy matrix. Incorporation of up to 1 wt.% of C150P MWCNTs has negligible influence on the elastic, viscoelastic and viscoplastic response of the epoxy system. No systematic changes of the creep characteristics depending on the content of nanotubes are noticed in the range of stresses from 0.3 up to 0.75 from the ultimate strength. Creep resistance and recovery performance of the epoxy matrix is not negatively affected by the addition of MWCNTs and the same analytical m…
Commercial thickeners used by patients with dysphagia: Rheological and structural behaviour in different food matrices
2015
In order to achieve a safe swallowing in patients with dysphagia, liquids must be thickened. In this work, two commercial starch based thickeners dissolved inwater,whole milk, apple juice and tomato juice were studied. The thickeners were Resource®, composed of modified maize starch and Nutilis®, composed of modified maize starch and gums. They were formulated at two different concentrations corresponding to nectar- and pudding-like consistencies. Influence of composition, concentration and food matrix on rheological properties and structure of the resulting pastes were analysed. Viscoelastic measurements and microscopic observations of the thickeners dissolved in water revealed structural …
Relevance of creep and oscillatory tests for understanding how cellulose emulsions function as fat replacers in biscuits
2015
Abstract The fats that are mostly employed in biscuit manufacturing contain a high percentage of saturated fatty acids, giving them the solid consistency that is needed for biscuit manufacture. For health reasons, lower levels of saturated fatty acids and elimination of trans fatty acids are desirable. An emulsion of sunflower oil, water and a cellulose ether was employed to replace all the conventional fat in a short dough recipe. The structure of the different doughs was measured by oscillatory and creep rheological tests and the results were related to dough performance during baking. The effect of the methoxyl and hydroxypropyl content of the cellulose was also evaluated. The compliance…
Thermal aggregation and ion-induced cold-gelation of bovine serum albumin
2009
Protein cold-gelation has recently received particular attention for its relevance in bio and food technology. In this work, we report a study on bovine serum albumin cold-gelation induced by copper or zinc ions. Metal-induced cold-gelation of proteins requires two steps: during the first one, the heat treatment causes protein partial unfolding and aggregation; then, after cooling the solution to room temperature, gels are formed upon the addition of metal ions. The thermally induced behaviour has been mainly investigated through different techniques: Fourier transform infrared (FTIR) spectroscopy, circular dichroism, dynamic light scattering (DLS) and rheology. Data have shown that the agg…
Combining Atomic Force Microscopy and Depth-Sensing Instruments for the Nanometer-Scale Mechanical Characterization of Soft Matter
2009
Complex materials exhibit a hierarchical structure where a gradient of features on nanometer scale is induced by the synthetic route eventually enhanced by the loading condition. The nanometer scale at which individual components arrange, determining their properties, is a current challenge of mechanical testing. In this work, a survey on nanoindentation is outlined based on the comparison of results obtained by Atomic Force Microscopy and Depth-Sensing Instruments and their combination. An Atomic Force Microscope equipped with a Force Transducer gives indeed the possibility to scan the sample surface in contact mode, thereby allowing one to choose a suitable position for the nanoindentatio…
EQCM and Quartz Crystal Impedance Measurements for the Characterization of Thiophene-Based Conducting Polymers
1999
AbstractEQCM was extensively used to investigate ion-transport phenomena during dopingundoping processes of electronically conducting polymers. Several early studies assumed that the polymer films were rigidly coupled to the quartz crystal so as to relate the mass change to the quartz crystal resonant frequency change via the Sauerbrey equation. However, the rigidity of electronically conducting polymer films is doubtful and it has to be demonstrated. Quartz crystal impedance analysis near the resonance is of paramount importance to get insight into the viscoelastic properties of the film [1] and to avoid misleading in the interpretation of EQCM data.This contribution presents and discusses…
Dynamic analysis for axially moving viscoelastic panels
2012
In this study, stability and dynamic behaviour of axially moving viscoelastic panels are investigated with the help of the classical modal analysis. We use the flat panel theory combined with the Kelvin–Voigt viscoelastic constitutive model, and we include the material derivative in the viscoelastic relations. Complex eigenvalues for the moving viscoelastic panel are studied with respect to the panel velocity, and the corresponding eigenfunctions are found using central finite differences. The governing equation for the transverse displacement of the panel is of fifth order in space, and thus five boundary conditions are set for the problem. The fifth condition is derived and set at the in-…
Fractional visco-elastic Euler–Bernoulli beam
2013
Abstract Aim of this paper is the response evaluation of fractional visco-elastic Euler–Bernoulli beam under quasi-static and dynamic loads. Starting from the local fractional visco-elastic relationship between axial stress and axial strain, it is shown that bending moment, curvature, shear, and the gradient of curvature involve fractional operators. Solution of particular example problems are studied in detail providing a correct position of mechanical boundary conditions. Moreover, it is shown that, for homogeneous beam both correspondence principles also hold in the case of Euler–Bernoulli beam with fractional constitutive law. Virtual work principle is also derived and applied to some c…