Search results for "Viscosity."
showing 10 items of 537 documents
Apparent and Real Distribution in GPC (Experiments with PMMA Samples)
1971
Abstract Molecular weight distribution curves obtained by GPC are broadened if concentration and flow rate are fixed in the usual range. Therefore, the apparent nonuniformity U app of the samples is larger than the real non-uniformity U = (Mw/Mn) −1. For a number of fractionated and unfractionated samples of polymethyl methacrylate we determined M n and M w by osmotic, light-scattering, and viscosity measurements. Thus, the real value of U can be compared to U app obtained by GPC at different concentrations and flow rates, υ. The excess nonuniformity U exc is evaluated as function of concentration c, polydispersity, molecular weight, and flow rate. For c = 0 and υ = 0, U exc is not far from…
Gelchromatographie mit zwei Detektoren. Ein verfahren zur Korrektur von Gelchromatogrammen
1978
The relationship between the experimental function E(v) for the viscosity and the chromatogram after correction of instrumental spreading, w(v0) can be expressed by the integral equation where v0 is the elution volume under the integral sign and D(v, v0) is a function that describes the shape of the band spreading curve of a monodisperse sample. The relationship between the experimental chromatogram e(v) is given by the Tung equation. If the function D(v, v0) is independent of the molecular weight, then it is possible to solve these equations simultaneously and to calculate the functions w(v0) and D(v, v0). A mathematical method is given.
Viscoelastic properties of concentrated dispersions in water of soy lecithin
2003
Abstract Viscoelastic properties of soy lecithin dispersions at 60, 120, 180 and 240 g l−1 in water have been studied as a function of ionic strength (NaCl concentrations in the range 10−5–10−2 mol l−1) and of preparation method (sonication, freezing–unfreezing). Viscosity measurements of sonicated dispersions in a rotatory viscometer show Newtonian and plastic (Bingham) behavior, whereas the frozen–unfrozen dispersions show a spectacular change in their viscoelastic properties, that is, a non-Newtonian behavior with pseudoplastic characteristics and rheopexy. These properties have been related to electrokinetic characteristics of the segregated vesicles in each case. A decrease in ζ-potent…
Microgels of polyaspartamide and poly(ethylene glycol) derivatives obtained by γ-irradiation
2002
Abstract The copolymer PHG based on α , β -poly( N -2-hydroxyethyl)- dl -aspartamide (PHEA) functionalized with glycidyl methacrylate has been exposed in aqueous solution to a γ -ray source at different irradiation doses (2, 2.5 and 3.5 kGy), alone or in combination with poly(ethylene glycol)dimethacrylate (PEGDMA) or poly(ethylene glycol)diacrylate (PEGDA). The irradiation produces microgel systems that have been characterized by viscosity measurements. Lyophilization of microgels gives rise to samples able to swell instantaneously in water whereas their treatment with acetone produces swellable microparticles that have been characterized.
Extensional flow of HDPE/LDPE blends
1982
Elongational viscosity data, obtained through the converging flow analysis by Cogswell, are presented for two types of HDPE/LDPE blends at various compositions and different temperatures. The results relative to the homopolymer parents compare favourably with literature data obtained also with different and more sophisticated techniques. Those relative to blends show peculiar features for the two cases: when the newtonian viscosity of the LDPE is higher all the blends show a behaviour typical of the LDPE with a maximum in η el /η0 enhanced at small percentage of HDPE; when the newtonian viscosity of the LDPE is similar to that of the HDPE there is only a gradual change in the properties.
Effect of TiO2 on the mullite formation and mechanical properties of alumina porcelain
2010
Abstract The effect of adding TiO 2 to standard alumina porcelain on its microstructure and flexural strength was investigated. A series of alumina porcelain bodies containing increasing amounts of TiO 2 were prepared by extruding mixtures of raw materials and TiO 2 . Porcelain rods were fired under industrial scheduling in a manufacturing kiln. The overall degree of crystalline and amorphous phase content within the porcelain bodies was quantitatively determined using a Rietveld analysis. Results indicated a higher amount of mullite formation in porcelain bodies containing TiO 2 . Examination of the product materials using field emission scanning electron microscopy showed a high density o…
DSC Studies and Stability of Frozen Foods
1991
This paper discusses the role played by the “WLF decrease in viscosity” above the temperature of the glass transition (Tg) in the temperature dependence of the stability of frozen foods. In the first part, the complex features observed before the melting endotherm on DSC/DTA thermograms of sugar-water solutions are examined; they are suggested to be representative of a glass transition associated with enthalpy relaxation. In the second part, the values of Tg for some complex foods are discussed. It is shown that ice melting adds an important contribution to the WLF effect on the decrease of the viscosity of the freeze-concentrated phase. The temperature dependence of the deterioration proce…
Some new polyelectrolytes
1989
Revue de methodes de preparation de polyelectrolytes: alkylation du poly(iminohexamethylene), homo- et copolymeres sequences de l'aza-1 bicyclo [4.2.0] octane, polymeres-peignes prepares a partir de macromeres obtenus par polymerisation de la phenyl-2 oxazoline. Preparation de polyampholytes ayant une distribution statistique ou sequencee des motifs ioniques
Three dimensional numerical simulation of wind driven flows in closed channels and basins
2008
In the paper, a fully 3D finite-volume numerical model is developed and employed for the prediction of wind-induced flows in a regular channel and in a square basin with a complex bathymetry. Numerical results are compared with laboratory experiments.Numerical tests are then performed to investigate whether simplifying assumptions about the pressure distribution and the turbulente stresses representation can be employed in the simulation of wind-driven flows. The hydrostatic pressure assumption, resulting in the use of “quasi-3D” models, proved to be reasonably acceptable in order to obtain the vertical profile of the streamwise velocity component away from the boundaries. The quasi-3D mode…
Die viskosität von polymerlösungen in der nähe von oberen und unteren entmischungstemperaturen
1977
Die Viskositat flussiger Mischungen zeigt in der Nahe des kritischen Entmischungspunktes eine charakteristische Temperaturabhangigkeit. fur Polymerlosungen ist diese Erscheinung bei der oberen kritischen Entmischungstemperatur gut untersucht, wahrend in der Umgebung der unteren kritischen Entmischungstemperatur keine derartigen Messungen vorliegen. ES wurden Viskositatsmessungen im System Cyclohexan/Polystyrol (obere kritische Entmischungstemperatur) und im System Orthotrimethylformiat/Diathylather/Polystyrol (untere kritische Entmischungstemperatur) durchgefuhrt. Beim ersten System ergab sich qualitative Ubereinstimmung mit den Ergebnissen von Debye und Mitarbeitern. Die Untersuchungen in …