Search results for "Volt"

Synthesis, electrochemistry, and spectroelectrochemistry of (P)Ge(Fc)2 and (P)Ge(C6H5)(Fc): first example of metal-carbon-.sigma.-bonded porphyrins w…

1988

Selective area vapor-phase epitaxy and structural properties of Hg1 − xCdxTe on sapphire

1997

Selective area (SA) Hg1 − xCdxTesapphire layers have been grown using the recently developed technique of the vapor-phase epitaxy (VPE) of Hg1 − xCdxTe layers on CdTesapphire heteroepitaxial substrates (HS), which we have called “VPE on HS technique” (Sochinskii et al., J. Crystal Growth 149 (1995) 35; 161 (1996) 195). First, planar CdTe (1 1 1) 5–7 μm thick layers were grown on sapphire (0 0 0 1) wafers by metalorganic vapor-phase epitaxy (MOVPE) at 340°C for 1–2.5 h using dimethylcadmium and di-isopropyltellurium as precursors. Second, CdTe/sapphire mesas were formed using standard photolithography in the form of alternating parallel linear arrays consisting of 500 × 70 μm2 elements. Thir…

Carbazole-based green and blue-BODIPY dyads and triads as donors for bulk heterojunction organic solar cells.

2020

Two BODIPY derivatives with one (B2) and two (B3) carbazole moieties were synthesized and applied as electron-donor materials in organic photovoltaic cells (OPV). Their optical and electrochemical properties were systematically investigated. These BODIPY dyes exhibit excellent solubility in organic solvents and present high molar extinction coefficients (1.37–1.48 × 105 M−1 cm−1) in solutions with absorption maxima at 586 nm for mono-styryl groups and at 672 nm for di-styryl groups. The introduction of the styryl moieties results in a large bathochromic shift and a significant decrease in the HOMO–LUMO energy-gaps. The BODIPY dyes show relatively low HOMO energies ranging from −4.99 to −5.1…

Tetraurea calix[4]arenes with sulfur functions: synthesis, dimerization to capsules, and self-assembly on gold.

2007

Various calix[4]arene derivatives, fixed in the cone conformation by decylether groups and functionalized at their wide rim by urea residues, were synthesized. In two compounds (4f,g) sulfur functions were attached to the urea groups via different spacers in order to allow binding to metal surfaces. While they exist as single molecules in polar solvents, tetraurea calix[4]arenes of this type (4) combine to form dimeric capsules in aprotic, apolar solvents. A solvent molecule is usually included in such a capsule, if no guest with a higher affinity is present. In the presence of an equimolar amount of the tetratosylurea 5, the exclusive formation of heterodimers, consisting of one molecule o…

Solvent-dependent formation of Os(0) complexes by electrochemical reduction of [Os(CO)(2,2'-bipyridine)(L)Cl2]; L = Cl(-), PrCN.

2014

Cyclic voltammetry and ultraviolet-visible/infrared (UV-vis/IR) spectroelectrochemistry were used to study the cathodic electrochemical behavior of the osmium complexes mer-[Os(III)(CO) (bpy)Cl3] (bpy = 2,2'-bipyridine) and trans(Cl)-[Os(II)(CO) (PrCN)(bpy)Cl2] at variable temperature in different solvents (tetrahydrofuran (THF), butyronitrile (PrCN), acetonitrile (MeCN)) and electrolytes (Bu4NPF6, Bu4NCl). The precursors can be reduced to mer-[Os(II)(CO) (bpy(•-))Cl3](2-) and trans(Cl)-[Os(II)(CO)(PrCN) (bpy(•-))Cl2](-), respectively, which react rapidly at room temperature, losing the chloride ligands and forming Os(0) species. mer-[Os(III)(CO) (bpy)Cl3] is reduced in THF to give ultimate…

Electrochemistry and germanium porphyrins in nonaqueous media. Reactions of water and hydroxide ligands associated with (P)Ge(ClO4)2 and (P)Ge(OH)2, …

1988

Does cyclic GMP mediate the negative inotropic effect of acetylcholine in the heart?

1977

DURING vagal stimulation the pacemaker activity of the heart is diminished. The reduction in heart rate is due to a release of acetylcholine (ACh) from the parasympathetic nerve terminals that increases the permeability of the myocardial cell membrane for potassium ions (for review see ref. 1). This is accompanied by a shortening of the action potential duration in atrial muscle and a diminished calcium uptake2, which in turn results in a negative inotropic effect. Voltage clamp experiments in mammalian atrial muscle have shown that with higher concentrations of ACh not only is the potassium current augmented but also the slow inward current of calcium is reduced3. It is not clear how the c…

A Finite Difference Model of a PV-PCM System

2012

Abstract The performances of a photovoltaic panel (PV) are defined according to the “peak power” that identifies the maximum electric power supplied by the panel when it receives an insolation of 1 kW/m2 and the temperature of the cell is maintained at 25 °C. These conditions are only nominal since the solar radiation has a variable intensity and also the panel is subjected to thermal excursions; due to these reasons the real power efficiency of the panel is considerably lower than that obtainable in the nominal conditions. The study focused on assessing a method to reduce the peak temperatures of PV systems using Phase Change Materials (PCM). To this aim it was created a numerical model ca…

Interconnections criteria of grounding grids in global grounding systems

2018

A Global Grounding System is defined as the combination of local grounding systems, obtained by their interconnection, which ensures, thanks to their proximity, that no dangerous touch voltages can arise. The interconnection of grounding systems via the armors of the MV cables, between secondary substations and HV/MV stations is herein analyzed to verify the effects on touch voltages in ground-fault conditions. In particular, two main issues are discussed: 1) the transfer of dangerous voltages to secondary substations, due to ground-faults occurring at the HV/MV station; 2) the reduction in the magnitude of the ground potential rise due to ground-fault conditions at secondary substations, t…

Integration Issues of Distributed Generators Considering Faults in Electrical Distribution Networks

2014

In the recent years there is a great interest in integration of distributed generation (DG) units at distribution level; this integration leads to planning as well as operational challenges. Some possibilities to handle grid planning issues are addressed in this paper. Effects on grid protection, fault current level, and voltage profile are investigated and described for different types of DG units; the classification of DG units is based on their terminal characteristics in terms of real and reactive power delivering capability. Different scenarios for mis-coordination problems caused by DG interconnection are discussed. The effect of the DG on the voltage profile of a distribution network…