Search results for "WASTE"
showing 10 items of 2580 documents
Prediction of Long-Term Chemical Evolution of a Low-pH Cement Designed for Underground Radioactive Waste Repositories
2012
Low-pH cements, also referred as low-alkalinity cements, are binders with a pore solution pH ≤ 11. They can be designed by replacing significant amounts of Portland cement (OPC) (≥40 %) by silica fume, which can be associated in some cases to low-CaO fly ash and/or ground granulated blast furnace slag to decrease the heat output during hydration by dilution of OPC and improve the mechanical strength of the final material. With the prospect of using these materials in a geological repository, it is of main importance to estimate their long-term properties and the influence of external and internal factors (chemical composition of the binder, storage temperature) on their characteristics. For…
Some factors affecting an increase in magnetic susceptibility of cement dusts
2001
The aim of the research was to explain reasons of fluctuation in magnetic susceptibility of cement dusts and the consequences for the environment. The research comprised measurements of magnetic susceptibility and Fe content in dusts, and also in raw materials, additives, fuels, mixtures and clinkers used for cement production. The samples were taken in four cement plants located in Opole Province (southern Poland). In addition to this, the influence of two production methods (dry and wet) on magnetic susceptibility of dusts and some aspects of ferrimagnetic minerals formation in the process of clinker burning were considered. It was proven that magnetic susceptibility of dusts depends on r…
On the physico-chemical evolution of low-pH and CEM I cement pastes interacting with Callovo-Oxfordian pore water under its in situ CO2 partial press…
2014
International audience; Abstract Within the framework of geological repositories for radioactive waste, structural concretes must be adapted to the underground chemical conditions. CEM I cement-based materials are characterised by high pH that may produce an alkaline plume in the near-field of the repository. In order to avoid this problem, low-pH cements have been designed. This study compares the physico-chemical behaviour of a low-pH material with a CEM I cement paste, both being subjected to leaching by an aqueous solution. An original experimental setup was designed to reproduce the underground conditions using a specific CO2 regulation device. Under these conditions, the low-pH materi…
Photocatalytic Properties of Cement-Based Plasters and Paints Containing Mineral Pigments
2010
Innovative cement-based premix products for surface coating of buildings that possess photocatalytic activity arouse great interest because of the results they can achieve in reducting air pollution and maintaining aesthetics. This photoactivity is induced by a photocatalyst, titanium dioxide, that can accelerate the oxidation processes of air pollutants, particularly nitrogen oxides and volatile organic compounds, which are mainly produced by incomplete combustion of fuel and are present in urban environments through the exhaust gases of motor vehicles. Surfaces that are coated with these products acquire a self-cleaning characteristic (maintenance of original color) because the decomposi…
Optimization of Radioactive Waste Cementation for Decommissioning of Salaspils Research Reactor
2011
This paper deals with information on the radioactive waste cementation technology for decommissioning of Salaspils Research Reactor (SRR). Dismantled and segmented radioactive materials were cemented in concrete containers using tritiated water-cement mixture. The viscosity of water-cement mortar, mechanical tests of solidified mortar’s samples, change of temperature of the samples during solidification time and long time leakage of 137Cs, 14C, 60Co and 3T radionuclides was studied for different water-cement compositions with additives. The pH and electro conductivity of the solutions during leakage tests were controlled. It was shown, that water/cement ratio significantly influences on wat…
Hydration of cementitious materials, present and future
2011
This paper is a keynote presentation from the 13th International Congress on the Chemistry of Cement. It discusses the underlying principles of hydration and recent evidence for the mechanisms governing this process in both Portland cements and other cementitious materials. Given the overriding imperative to improve the sustainability of cementitious materials, routes to reducing CO2 emissions are discussed and the impact of supplementary materials on hydration considered. (C) 2011 Elsevier Ltd. All rights reserved.
Development of a performance threshold approach for identifying the management options for stabilisation/solidification of lead polluted soils
2014
Two soils spiked with lead at different rates were stabilised/solidified using Portland cement and fy ash at different soil:binder ratios, and tested for their setting time, unconfined compressive strength, leachability and durability. A performance threshold approach was used in order to identify optimal management options for the products of the S/S treatment. Results show that soil texture, percentage of binders and lead concentration play an important part in the treatment, significantly influencing the performance of the resulting products in terms of curing, compressive strength and durability. Pb soil concentrations higher than 15000 mg kg-1 were found to heavily reduce the applicab…
Valorisation of industrial iron oxide waste to produce magnetic barium hexaferrite
2016
Barium M-type hexagonal ferrite (BaM, BaFe12O19) is an immensely important magnetic material, which we have successfully made from the simple valorisation of Fe-rich industrial waste from steel wire drawing, with addition of BaCO3 and heating in air to 1000 degrees C. The optimum ratio of Fe. Ba (producing 86 wt% BaM) was found to be 11: 1 (non-stoichiometric), and secondary phases of alpha-Fe2O3 (non-magnetic) and ZnFe2O4 (poorly antiferromagnetic) were always present. This material consisted of small submicron platelets. A hard magnetic ferrite was produced with Ms=48.6 A m(2) kg(-1) and H-c=211.5 kA m(-1). The highest density was achieved by sintering samples with Fe: Ba ratios of 11: 1 …
Total oxidation of naphthalene with high selectivity using a ceria catalyst prepared by a combustion method employing ethylene glycol.
2009
Abstract During the catalytic combustion of naphthalene, compounds other than CO 2 are often obtained. These products, as polymerized polycyclic aromatic hydrocarbons, oxygenated aromatic compounds and benzene derivate compounds, are usually more toxic than naphthalene. At the present work it is shown a nanocrystalline cerium oxide prepared by a combustion method employing a proper ethylene glycol concentration that exhibits very high activity in the decomposition of naphthalene in the presence of air and, most importantly, a selectivity value towards CO 2 of 100% for any range of conversions and/or temperatures used. In addition, it has been demonstrated that the amount of ethylene glycol …
Observations on mucus aggregates along Sicilian coasts during 1991–1992
1995
Abstract The results of some observations on gelatinous material accumulating on the sea ground and free floating in the water column along Sicilian coasts are reported. The phenomenon showed different development patterns moving from the Tyrrherian to the Jonian coast and to the Sicilian Channel. Moreover, in 1991, mucus aggregates in the Tyrrhenian sea showed a similar structure, behaviour and origin to those observed in the Adriatic sea, whereas, in 1992, only a massive growth of metaphytic threadlike algae, more or less producing gelatinous sheaths, occurred.