Search results for "WASTE"
showing 10 items of 2580 documents
Patterns of presence and concentration of pesticides in fish and waters of the Júcar River (Eastern Spain).
2013
The Jucar River, in a typical Mediterranean Basin, is expected to suffer a decline in water quality and quantity as a consequence of the climate change. This study is focused on the presence and distribution of pesticides in water and fish, using the first extensive optimization and application of the QuEChERS method to determine pesticides in freshwater fish. Majority pesticides in water - in terms of presence and concentration - were dichlofenthion, chlorfenvinphos, imazalil, pyriproxyfen and prochloraz (associated with a frequent use in farming activities), as well as buprofezin, chlorpyriphos and hexythiazox. In fish, the main compounds were azinphos-ethyl, chlorpyriphos, diazinon, dime…
Evaluation of biodegradation of nonylphenol ethoxylate and lignin by combining toxicity assessment and chemical characterization.
2009
Abstract The aerobic biodegradation of commercial nonylphenol ethoxylate (NPE) mixture and alkali lignin was studied using the OECD headspace test accompanied by the simultaneous measurement of ecotoxicity directly from the biodegradation liquors and by the follow-up of the chemical composition of the studied chemicals. NPE degradation was dependent on the inoculum source: approximately 40% of NPE was mineralized into CO2 during the 4-week experiment when inoculum from Helsinki City wastewater treatment plant (WWTP) was used, and only 12% was mineralized when inoculum from Jyvaskyla City WWTP was used. Chemical analyses revealed a shift in the ethoxylate chain length from longer to shorter …
Levels, fingerprint and daily intake of polycyclic aromatic hydrocarbons (PAHs) in bread baked using wood as fuel
2009
Concentrations, fingerprint and daily intake of 16 PAHs in 15 bread samples baked using wood as fuel are examined in this work. Analysis was performed by GC/MS after saponification of the samples and clean up of the extract. The total concentration of the 16 analytes varies from 6 to 230 microg/kg on dry weight (d.w.). The better extraction procedure was estimated by analyzing test-samples and using different extraction methods. Additionally, for every analyzed sample, the extraction yield has been determined by the use of surrogate standards. Extraction yields were never less than 77% and in most cases almost 100%. The profiles of PAHs (percentage) are similar for all the analyzed samples …
Heterogeneous catalytic degradation of phenolic substrates: catalysts activity
2009
This review article explored the catalytic degradation of phenol and some phenols derivates by means of advanced oxidation processes (AOPs). Among them, only the heterogeneous catalyzed processes based on catalytic wet peroxide oxidation. catalytic ozonation and catalytic wet oxidation were reviewed. Also selected recent examples about heterogeneous photocatalytic AOPs; will be presented. In details, the present review contains: (i) data concerning catalytic wet peroxide oxidation of phenolic compounds over metal-exchanged zeolites, hydrotalcites, metal-exchanged clays and resins. (ii) Use of cobalt-based catalysts, hydrotalcite-like compounds, active carbons in the catalytic ozonation proc…
The use of fish bile metabolite analyses as exposure biomarkers to pulp and paper mill effluents
1998
The exposure of caged one-year-old whitefish (Coregonus lavaretus) to wood extractives and chlorophenolics from pulp and paper mill effluents in Lake Saimaa (SE Finland) was investigated. Whitefish were exposed at 17 locations affected by effluents from pulp and paper mills and at 5 reference areas. Resin and fatty acids and chlorophenolics in bile were analysed by GC and GC-MS. Cholesterol concentration in bile was also measured. Results show that despite of process changes to ECF and waste water treatment improvements employed by the pulp and paper industry in the study area, it is still possible to detect elevated concentrations of these substances in the bile of fish exposed in the vici…
Novel modified poly vinyl chloride blend membranes for removal of heavy metals from mixed ion feed sample
2017
Herein, an attempt has been made to prepare a novel membrane with good efficiency for removal of heavy metal ions namely lead (Pb), cadmium (Cd) and chromium (Cr). 4-amino benzoic acid (ABA) was covalently grafted onto the poly vinyl chloride (PVC) backbone by CN bond to enhance the hydrophilicity. 1H NMR and ATR-IR spectroscopy analysis confirmed the chemical modification of PVC. Further the modified polymer was blended in different compositions with polysulfone (PSf) for optimization. Morphological changes that occurred in blend membranes, due to the incorporation of modified PVC was studied by AFM and SEM techniques. The effect on hydrophilicity and performance of blends owing to incorpo…
Towards the design of organocatalysts for nerve agents remediation: The case of the active hydrolysis of DCNP (a Tabun mimic) catalyzed by simple ami…
2015
We report herein a study of the hydrolysis of Tabun mimic DCNP in the presence of different amines, aminoalcohols and glycols as potential suitable organocatalysts for DCNP degradation. Experiments were performed in CD3CN in the presence of 5% D2O, which is a suitable solvent mixture to follow the DCNP hydrolysis. These studies allowed the definition of different DCNP depletion paths, resulting in the formation of diethylphosphoric acid, tetraethylpyrophosphate and phosphoramide species as final products. Without organocatalysts, DCNP hydrolysis occurred mainly via an autocatalysis path. Addition of tertiary amines in sub-stoichiometric amounts largely enhanced DCNP depletion whereas non-te…
Assessing population exposure to phthalate plasticizers in thirteen Spanish cities through the analysis of wastewater
2021
Phthalates are widely used plasticizers that produce endocrine-disrupting disorders. Quantifying exposure is crucial to perform risk assessments and to develop proper health measures. Herein, a wastewater-based epidemiology approach has been applied to estimate human exposure to six of the mostly used phthalates within the Spanish population. Wastewater samples were collected over four weekdays from seventeen wastewater treatment plants serving thirteen cities and ca. 6 million people (12.8 % of the Spanish population). Phthalate metabolite loads in wastewater were transformed into metabolite concentrations in urine and into daily exposure levels to the parent phthalates. Considering all th…
Competitive arsenate and phosphate adsorption on α-FeOOH, LaOOH, and nano-TiO2: Two-dimensional correlation spectroscopy study
2021
Abstract Competitive adsorption of arsenate (AsO43−) and phosphate (PO43−) on α-FeOOH, LaOOH, and nano-TiO2 was studied using batch adsorption experiments and in-situ flow cell ATR-FTIR coupled with two-dimensional correlation spectroscopy (2D-COS) for the first time. With a higher temporal resolution, our results found a highly dynamic adsorption sequence for AsO43− and PO43−. When AsO43− and PO43− were simultaneously exposed to the adsorbents at the same concentrations, AsO43− was preferentially adsorbed by α-FeOOH and TiO2, but PO43− adsorption was dominant on LaOOH. The results implied that the PO43− adsorbed on LaOOH had to be remobilized to allow for AsO43− adsorption, but that PO43− …
A new foam-based method for the (bio)degradation of hydrocarbons in contaminated vadose zone
2020
International audience; An innovative foam-based method for Fenton reagents (FR) and bacteria delivery was assessed for the in situ remediation of a petroleum hydrocarbon-contaminated unsaturated zone. The surfactant foam was first injected, then reagent solutions were delivered and propagated through the network of foam lamellae with a piston-like effect. Bench-scale experiments demonstrated the feasibility of the various treatments with hydrocarbon (HC) removal efficiencies as high as 96 %. Compared to the direct injection of FR solutions, the foam-based method led to larger radii of influence and more isotropic reagents delivery, whereas it did not show any detrimental effect regarding H…