Search results for "Weathering"
showing 10 items of 138 documents
The role of hydrological processes on enhanced weathering for carbon sequestration in soils in tropical areas
2021
<p>To mitigate global warming, a noticeable research effort is being devoted to NCS (Natural Climate Solutions) as means to reduce greenhouse gas emissions or sequester carbon within the oceans or terrestrial environments by exploiting natural processes. Enhanced weathering<strong> </strong>is a NCS that aims to increase the weathering reaction rates of silicate minerals, by amending soils with crushed reactive minerals. Various studies have shown that this technique is favored by hot and humid climates (i.e., tropical ecosystems), since weathering reactions are mostly effective under high temperature and soil moisture. Despite olivine dissolution d…
Petrography and decay of a marly limestone in the cloister of a medieval cathedral in Sicily
2004
This paper deals with a significant process of decohesion of a marly limestone, taking place in the cloister of the medieval Cathedral of Cefalu, a pleasant town on the northern coast of Sicily. After desalination with deionised water and consolidation with ethyl silicate, the decay of the stone became faster. The aim of our study is to characterise the stony material and investigate the observed decay phenomena. The stone, that is a poor building material indeed, is characterised by means of petrographical, chemical and physical analyses on samples taken from the monument. Furthermore, experimental tests are performed in the laboratory in order to highlight the causes of incompatibility be…
Weathering of evaporites: natural versus anthropogenic signature on the composition of river waters
2015
Weathering of evaporites strongly influences the chemistry of continental runoff, making surface waters poorly exploitable for civil uses. In south-central Sicily, this phenomenon is worsened by the occurrence of abandoned landfills of old sulphur and salt mines. The industrial evolution of the Bosco-S. Cataldo mining site leaved two landfills from the early exploitation of a sulphur mine followed by that of a kainite deposit. In particular, the weathering of these landfills leads the dissolved salt (TDS) values up to about 200 g l−1 in the Stincone–Salito Stream waters. This process induces the V, Cr and Fe desorption from sediments and particulates in the aqueous phase under reducing cond…
Osmium and lithium isotope evidence for weathering feedbacks linked to orbitally paced organic carbon burial and Silurian glaciations
2022
Abstract The Ordovician (∼487 to 443 Ma) ended with the formation of extensive Southern Hemisphere ice sheets, known as the Hirnantian glaciation, and the second largest mass extinction in Earth History. It was followed by the Silurian (∼443 to 419 Ma), one of the most climatically unstable periods of the Phanerozoic as evidenced by several large scale ( > 5 ‰ ) carbon isotope (δ13C) perturbations associated with further extinction events. Despite several decades of research, the cause of these environmental instabilities remains enigmatic. Here, we provide osmium (187Os/188Os) and lithium (δ7Li) isotope measurements of marine sedimentary rocks that cover four Silurian δ13C excursions. Osmi…
Occurrence and Genesis of Palygorskite and Associated Clay Minerals in a Pleistocene Calcrete Complex, Sde Boqer, Negev Desert, Israel
1996
AbstractPalygorskite and associated clay minerals have been studied in a Pleistocene calcrete complex from the Negev desert (Sde Boqer, Israel). This complex is divided into five main parts: the chalky and marly bedrock overlain by its weathered product, a brecciated calcrete hardpan; the laminar crust; loess pockets trapped in the calcrete; and the overlying soft surficial soil. The distribution of clay minerals is directly dependent on the position of the sample in the calcrete complex. Smectite is inherited from the bedrock in the calcrete with an aeolian enrichment in loess pockets and upper soft soil. The source of kaolinite is mainly detrital, related to desert dust. Illite is partly …
Weathering Products of a Dismantled Variscan Basement. Minero-Chemical Proxies to Insight on Cretaceous Palaeogeography and Late Neogene Palaeoclimat…
2020
This study compares, for the first time, the mineralogy and geochemistry of two residual-clay deposits in NW Sardinia (Nurra district) that formed at different times in tropical and sub-tropical climates. Both deposits represent palaeosols with deep-weathered residual profiles and overlie Mesozoic carbonate rocks that were deposited on the south European palaeomargin. The older alterite is Cenomanian–Turonian in age and grades upward into a horizon of karstic bauxite, whereas the younger unit occurs within alluvial deposits of Late Neogene age. The Cretaceous palaeosol represents the precursor of the overlying bauxite and formed from unknown sedimentary parent rocks. In contrast, the Messin…
Mineralogy at Gusev Crater from the Mössbauer spectrometer on the Spirit Rover.
2004
Mössbauer spectra measured on Mars by the Spirit rover during the primary mission are characterized by two ferrous iron doublets (olivine and probably pyroxene) and a ferric iron doublet (tentatively associated to nanophase ferric iron oxide). Two sextets resulting from nonstoichiometric magnetite are also present, except for a coating on the rock Mazatzal, where a hematite-like sextet is present. Greater proportions of ferric-bearing phases are associated with undisturbed soils and rock surfaces as compared to fresh rock surfaces exposed by grinding. The ubiquitous presence of olivine in soil suggests that physical rather than chemical weathering processes currently dominate at Gusev crat…
Transformation of clay-sized minerals in soils exposed to prolonged regular alternation of redox conditions
2016
Abstract The direction of the transformation of Fe-bearing minerals under harshly changing redox conditions is still under debate. Some studies suggest preferential accumulation of weakly crystalline Fe oxides while other studies showed that repeated redox cycles favour the presence of crystalline phases. Since characterized by distinct redox cycles, paddy soils are ideal for studying redox-related transformations of Fe oxides and Fe-bearing clay minerals. We analysed changes in the Fe mineral assemblage upon long-term reduction–oxidation cycles along a chronosequence of 100, 700, and 2000-year-old paddy soils developed on comparable parent material relative to two non-irrigated counterpart…
Mineralverwitterung, tonmineralbildung und rubefizierung in Terrae calcis der slowakei Ein beitrag zum paläoklimatischen aussagewert von kalkstein-Ro…
1984
Mineral weathering, clay mineral formation and rubefication of Terrae calcis in Slovakia — A contribution to paleoclimatic evidence of limestone Rotlehm (terra rossa) in Central Europe Limestone Rotlehm (Terra rossa) is very often interpreted as a product of intensive mineral weathering and clay formation under subtropic (to tropic) climate. Especially the formation of hematite in soils as the main process of rubefication is generally believed to occur only in warm climates with a seasonal alternation of precipitation and drought. Fossil or relict Terrae rossae in Central Europe are therefore very often considered as witnesses of a corresponding paleoclimate. On the other side many authors …
Review of the relationship between aggregates geology and Los Angeles and micro-Deval tests
2021
Rock aggregates constitute the enormous volume of inert construction material used around the globe. The petrologic description as igneous, sedimentary, and metamorphic types establishes the intrinsic formation pattern of the parent rock. The engineering properties of these rocks vary due to the differences in the transformation process (e.g. hydrothermal deposits) and weathering effect. The two most common mechanical tests used to investigate the performance of aggregates are the Los Angeles (LA) and micro-Deval (MD) tests. This study reviewed the geological parameters (including mineralogy, grain and crystal size, grain shape, and porosity) and the relationship to Los Angeles and micro-De…