Search results for "X-RAY SPECTROSCOPY"
showing 10 items of 93 documents
The Athena X-ray Integral Field Unit (X-IFU)
2016
Event: SPIE Astronomical Telescopes + Instrumentation, 2016, Edinburgh, United Kingdom.
DETECTION LIMITS FOR NATURAL CIRCULAR-DICHROISM OF CHIRAL COMPLEXES IN THE X-RAY RANGE
1993
Whereas both Magnetic Circular Dichroism and Faraday Rotation studies have been successfully carried out at the K-, L- and M-absorption edges of metal atoms in ferromagnetic systems, Natural optical activity of chiral complexes has not yet been detected quite unambiguously in the X-ray range. We review a number of theoretical arguments which confirm that the optical asymmetry factor gσ should be very small in the X-ray range for unoriented powdered samples, especially at the K-absorption edges. This stimulating challenge prompted us to start an intensive programme of measurements aimed at detecting natural circular dichroism in both the soft and “firm” X-ray ranges. Although some of our ex…
Digital filtering and analysis for a semiconductor X-ray detector data acquisition
2007
Abstract Pile-up distortion is a major drawback in X-ray spectroscopy at high count rate. Pulse width narrowing with shaping techniques can lead to the reduction of the pile-up distortion, but a low shaping time reduces the noise filtration and leads to a poor energy resolution. Thus, only a best compromise solution between the pile-up and the noise requirements is achievable. The hardware manipulation needed to adjust the parameters of the traditional electronic shaping amplifiers makes it uneasy to tests various settings in different conditions. Digital techniques can help to overcome such difficulties. A digital signal processing and analysis system for X-ray spectroscopy is described in…
Coronal properties of G-type stars in different evolutionary phases
2005
We report on the analysis of XMM-Newton observations of three G-type stars in very different evolutionary phases: the weak-lined T Tauri star HD 283572, the Zero Age Main Sequence star EK Dra and the Hertzsprung-gap giant star 31 Com. They all have high X-ray luminosity (10^31 erg/s for HD 283572 and 31 Com and 10^30 erg/s for EK Dra). We compare the Emission Measure Distributions (EMDs) of these active coronal sources, derived from high-resolution XMM-Newton grating spectra, as well as the pattern of elemental abundances vs. First Ionization Potential (FIP). We also perform time-resolved spectroscopy of a flare detected by XMM from EK Dra. We interpret the observed $EMD$s as the result of …
X-ray spectroscopy of MXB 1728-34 with XMM-Newton
2011
We have analysed an XMM-Newton observation of the low mass X-ray binary and atoll source MXB 1728-34. The source was in a low luminosity state during the XMM-Newton observation, corresponding to a bolometric X-ray luminosity of 5*10E36 d^2 erg/s, where d is the distance in units of 5.1 kpc. The 1-11 keV X-ray spectrum of the source, obtained combining data from all the five instruments on-board XMM-Newton, is well fitted by a Comptonized continuum. Evident residuals are present at 6-7 keV which are ascribed to the presence of a broad iron emission line. This feature can be equally well fitted by a relativistically smeared line or by a self-consistent, relativistically smeared, reflection mo…
Interpretation of the U L3-edge EXAFS in uranium dioxide using molecular dynamics and density functional theory simulations
2016
X-ray absorption spectroscopy is employed to study the local structure of pure and Cr-doped UO2 at 300 K. The U L3-edge EXAFS spectrum is interpreted within the multiplescattering (MS) theory using the results of the classical and ab initio molecular dynamics simulations, allowing us to validate the accuracy of theoretical models. The Cr K-edge XANES is simulated within the full-multiple-scattering formalism considering a substitutional model (Cr at U site). It is shown that both unrelaxed and relaxed structures, produced by ab initio density functional theory (DFT) calculations, fail to describe the experiment.
Zn K-edge XANES in nanocrystalline ZnO
2007
Zn K-edge XANES in ZnO has been calculated within the full-multiple-scattering (FMS) and finite difference method (FDM) formalism using the ab initio FDMNES code. The influence of non-muffin-tin potential, bulk defects, surface termination and polarization effects on XANES has been analysed. The obtained theoretical results are compared with available experimental data for polycrystalline and nanocrystalline zinc oxide systems.
Nanoscale x-ray absorption spectroscopy using XEOL-SNOM detection mode
2007
The first results obtained with the prototype system at the synchrotron beamline ID03 at ESRF are presented and illustrate the possibility to detect an element-specific contrast and to perform nanoscale x-ray absorption spectroscopy experiments at the Zn K and W L 3 absorption edges in mixed zinc oxide-zinc tungstate thin films.
Microwave-induced electromigration in multicomponent metallic alloys
2010
The crystallization of amorphous FeCoCuZrAlSiB alloy ribbons during microwave heating was investigated in situ using time-resolved X-ray powder diffraction. The formation of the nanocrystalline α-(Fe,Co)(SiAl) phase during the primary crystallization stage is followed by the crystallization of the residual glassy matrix. Scanning electron microscopy analysis after microwave exposure reveals the formation of nanosized hillocks evenly distributed over the ribbon surfaces. Local chemical composition analysis by energy-dispersive spectroscopy shows that the surface clusters are enriched in Cu and Al. The occurrence of this typical electromigration effect imposes a strong restriction on the dura…
Analytical study of canvas painting collection from the Basilica de la Virgen de los Desamparados using SEM/EDX, FT-IR, GC and electrochemical techni…
2001
A new method, based on the combined use of scanning electron microscopy-x-ray microanalysis, Fourier transform infrared spectroscopy, gas chromatography and differential pulse voltammetry, is proposed which permits a parallel investigation of organic and inorganic materials and the characterization of the artistic technique employed in canvas painting. The proposed method has led to analyze succesfully the canvas painting collection exhibited in the Basílica de la Virgen de los Desamparados (Valencia, Spain) which includes art works from 17th to 20th century.