Search results for "X-ray"

showing 10 items of 4234 documents

Manganese(II) complexes of scorpiand-like azamacrocycles as MnSOD mimics.

2011

Mn(II) complexes of scorpiand-type azamacrocycles constituted by a tretrazapyridinophane core appended with an ethylamino tail including 2- or 4-quinoline functionalities show very appealing in vitro SOD activity. The observed behaviour is related to structural and electrochemical parameters.

Biomimetic materialsAza CompoundsManganeseMacrocyclic CompoundsStereochemistrySuperoxide DismutaseMetals and AlloysMolecular Conformationchemistry.chemical_elementGeneral ChemistryManganeseElectrochemistryCrystallography X-RayCatalysisMolecular conformationSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialschemistryBiomimetic MaterialsCoordination ComplexesMaterials ChemistryCeramics and CompositesQuinolinesAza CompoundsChemical communications (Cambridge, England)
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Possible functions of biomineralization of some Textulariid (Foraminifera) species of the Nw Iberian Margin

2016

The main goal of this work is to analyze the elemental composition of the test’s wall of some species/specimens of Textulariids (sub-class Subclass Textulariia), collected in surface sediments of the NW Iberian Margin. The elemental analyses was based on the Energy Dispersive Spectroscopy (EDS) on the Scanning Electron Microscope (SEM; Hitachi, S4100) of Textularia deltoidea, Textularia agglutinans, Sahulia conica, Karrerotextularia flintii, Siphotextularia heterostoma, Karreriella bradyi, Spiroplectammina sagittula and Arenoparrella mexicana . The elelemetal cocnentrations of the species wall were compared with the mineralogical composition (X-Ray diffraction) of the sediments of the stati…

Biomineralization010506 paleontologyElemental analysisEnergy-dispersive X-ray spectroscopyMineralogyTest (biology)010502 geochemistry & geophysics01 natural sciencesDeep seaSagittulaEDS[ SDE ] Environmental SciencesForaminiferaTextularialcsh:StratigraphyConica14. Life underwater0105 earth and related environmental scienceslcsh:QE640-699biologylcsh:QE1-996.5Wall compositionbiology.organism_classificationlcsh:GeologySEDIMENTOLOGIA MARINHAElemental analysisEnvironmental chemistrySEM[SDE]Environmental SciencesAgglutinated foraminifera
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Compartmentalization of gypsum and halite associated with cyanobacteria in saline soil crusts

2016

The interface between biological and geochemical components in surface crust of a saline soil was investigated using X-Ray Diffraction (XRD), and variable pressure scanning electron microscopy (SEM) in combination with Energy Dispersive X-ray Spectrometry (EDS). Mineral compounds such as halite and gypsum were identified crystallized around filaments of cyanobacteria. A total of 92 genera were identified from the bacterial community based on 16S gene pyrosequencing analysis. The occurrence of the gypsum crystals, their shapes and compartmentalization suggested that they separated NaCl from the immediate microenvironment of the cyanobacteria, and that some cyanobacteria and communities of su…

Biomineralization0301 basic medicineCyanobacteriaGypsumbiomineralisationSettore AGR/13 - Chimica Agraria030106 microbiologychemistry.chemical_elementMineralogySulfur bacteriaSodium ChlorideBiologyengineering.materialCyanobacteriaCalcium SulfateApplied Microbiology and BiotechnologyMicrobiologySoil03 medical and health sciencesX-Ray DiffractionSoil crustRNA Ribosomal 16SSoil MicrobiologyMineralSulfur CompoundsEcologyMedicine (all)biology.organism_classificationSulfurchemistrySettore AGR/14 - PedologiaMicroscopy Electron ScanningengineeringsulfobacteriaSoil crustHaliteSoil microbiologySaline soilBiomineralizationFEMS Microbiology Ecology
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Genesis of amorphous calcium carbonate containing alveolar plates in the ciliate Coleps hirtus (Ciliophora, Prostomatea).

2013

7 pages; International audience; In the protist world, the ciliate Coleps hirtus (phylum Ciliophora, class Prostomatea) synthesizes a peculiar biomineralized test made of alveolar plates, structures located within alveolar vesicles at the cell cortex. Alveolar plates are arranged by overlapping like an armor and they are thought to protect and/or stiffen the cell. Although their morphology is species-specific and of complex architecture, so far almost nothing is known about their genesis, their structure and their elemental and mineral composition. We investigated the genesis of new alveolar plates after cell division and examined cells and isolated alveolar plates by electron microscopy, e…

Biomineralization570Morphology (linguistics)MineralogyColeps hirtus02 engineering and technologyCalcium Carbonatelaw.invention03 medical and health scienceschemistry.chemical_compoundX-Ray DiffractionStructural BiologylawSpectroscopy Fourier Transform InfraredCell cortexCiliophora[SDV.IB.BIO]Life Sciences [q-bio]/Bioengineering/BiomaterialsAlveolar plates030304 developmental biologyCiliate0303 health sciencesProstomateabiologyVesicleCiliateSpectrometry X-Ray Emission500respiratory system021001 nanoscience & nanotechnologybiology.organism_classification[ SDV.IB.BIO ] Life Sciences [q-bio]/Bioengineering/BiomaterialsAmorphous calcium carbonateMicroscopy ElectronchemistryProtozoanBiophysicsAmorphous calcium carbonateElectron microscope0210 nano-technologyBiomineralization
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Climate variation during the Holocene influenced the skeletal properties of Chamelea gallina shells in the North Adriatic Sea (Italy)

2021

Understanding how marine taxa will respond to near-future climate changes is one of the main challenges for management of coastal ecosystem services. Ecological studies that investigate relationships between the environment and shell properties of commercially important marine species are commonly restricted to latitudinal gradients or small-scale laboratory experiments. This paper aimed to explore the variations in shell features and growth of the edible bivalve Chamelea gallina from the Holocene sedimentary succession to present-day thanatocoenosis of the Po Plain-Adriatic Sea system (Italy). Comparing the Holocene sub-fossil record to modern thanatocoenoses allowed obtaining an insight o…

BiomineralizationAtmospheric ScienceRecrystallization (geology)010504 meteorology & atmospheric sciencesPhysiologyOceans and Sea01 natural sciencesAnimal ShellX-Ray DiffractionSpectroscopy Fourier Transform InfraredHoloceneClimatologySedimentary GeologyMineralsMultidisciplinaryQuaternary PeriodbiologyGeographyFossilsQREukaryotaFossilGeologyMineralogyDiagenesisOceanographyItalyTaphonomyPhysical SciencesMedicineChamelea gallina[SDU.STU.PG]Sciences of the Universe [physics]/Earth Sciences/PaleontologyPorosityGeologyResearch Article010506 paleontologyBivalvesScienceClimate ChangeOceans and SeasMaterials ScienceMaterial PropertiesClimate changeengineering.materialCalcium CarbonateCalcification PhysiologicAnimal ShellsAnimals14. Life underwaterPaleoclimatologyEcosystem0105 earth and related environmental sciencesPetrologyHolocene EpochAnimalAragoniteRadiometric DatingOrganismsBiology and Life SciencesPaleontologyGeologic TimeMolluscsbiology.organism_classificationInvertebratesBivalviaSea surface temperatureAragonite13. Climate actionengineeringEarth SciencesCenozoic EraSedimentary rockSedimentPaleobiologyPhysiological ProcessesZoologyPloS One
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Ferroelectric polysiloxane liquid crystals with ‘de Vries’-type smectic A*–smectic C* transitions

2004

We report preliminary results of optical and small angle X-ray scattering (SAXS) experiments on the smectic A*−smectic C* transition in two ferroelectric liquid crystalline polysiloxanes. Although the optical tilt angle in the SmC* phases reaches values up to 30°, temperature-dependent SAXS measurements clearly reveal that the smectic layer spacing is basically conserved during the A*–C* transition as well as in the subsequent C* phase. Connected with the A*–C* transition we further observed a significant increase in birefringence, hence reflecting an increase of orientational order. The practical absence of layer shrinkage and the enhanced orientational ordering are consistent with the de …

BirefringenceMaterials scienceCondensed matter physicsSmall-angle X-ray scatteringbusiness.industryScatteringLiquid crystallineGeneral ChemistryCondensed Matter PhysicsFerroelectricityTilt (optics)OpticsLiquid crystalPhase (matter)General Materials SciencebusinessLiquid Crystals
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INTEGRAL/RXTE Observations of Cygnus X-1

2003

We present first results from contemporaneous observations of Cygnus X-1 with INTEGRAL and RXTE, made during INTEGRAL's performance verification phase in 2002 November and December. Consistent with earlier results, the 3-250 keV data are well described by Comptonization spectra from a Compton corona with a temperature of kT~50-90 keV and an optical depth of tau~1.0-1.3 plus reflection from a cold or mildly ionized slab with a covering factor of Omega/2pi~0.2-0.3. A soft excess below 10 keV, interpreted as emission from the accretion disk, is seen to decrease during the 1.5 months spanned by our observations. Our results indicate a remarkable consistency among the independently calibrated de…

Black hole physics ; Individual stars ; Cyg X-1 ; Gamma rays ; X-rays observations ; BinariesAstrophysics::High Energy Astrophysical PhenomenaPhase (waves)FOS: Physical sciencesFlux02 engineering and technologyAstrophysicsUNESCO::ASTRONOMÍA Y ASTROFÍSICAAstrophysicsCyg X-101 natural sciencesOmegaSpectral lineIonizationIndividual stars0103 physical sciencesOptical depth (astrophysics)0202 electrical engineering electronic engineering information engineeringCalibration010303 astronomy & astrophysicsOptical depthPhysics010308 nuclear & particles physicsGamma raysBinariesAstrophysics (astro-ph)X-rays observationsGamma rayAstronomyAstronomy and Astrophysics020206 networking & telecommunicationsBlack hole physics:ASTRONOMÍA Y ASTROFÍSICA::Cosmología y cosmogonia [UNESCO]CoronaSpace and Planetary ScienceReflection (physics)020201 artificial intelligence & image processingUNESCO::ASTRONOMÍA Y ASTROFÍSICA::Cosmología y cosmogonia:ASTRONOMÍA Y ASTROFÍSICA [UNESCO]AIP Conference Proceedings
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Can gravity perturbations explain QPOs?

2007

We show the results of some numerical simulations trying to reproduce the QPO behavior in black hole and neutron star sources. Our simulations are based on the idea that a nearly periodic luminosity oscillation can be obtained from a perturbation of the source gravitational field with a sinusoidal time behavior. We find that some specific features of the QPO phenomenon can be described by this simple model, but the required amplitude of the gravity perturbation is more than 1% of the unperturbed gravitational field. If the hypothesis is formed that such a perturbation is due to a density fluctuation (of the accretion disk or the source itself, in the case of the neutron star) going around t…

Black holePhysicsGravitationNeutron starAmplitudeX-ray bursterGravitational fieldAstrophysics::High Energy Astrophysical PhenomenaX-ray binaryStellar black holeAstrophysics
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The NHXM observatory

2011

Exploration of the X-ray sky has established X-ray astronomy as a fundamental astrophysical discipline. While our knowledge of the sky below 10 keV has increased dramatically (∼8 orders of magnitude) by use of grazing incidence optics, we still await a similar improvement above 10 keV, where to date only collimated instruments have been used. Also ripe for exploration is the field of X-ray polarimetry, an unused fundamental tool to understand the physics and morphology of X-ray sources. Here we present a novel mission, the New Hard X-ray Mission (NHXM) that brings together for the first time simultaneous high-sensitivity, hard-X-ray imaging, broadband spectroscopy and polarimetry. NHXM will…

Black-holesAcceleration mechanismCosmic Visionmedia_common.quotation_subjectPolarimetry7. Clean energy01 natural sciencesMissionsCosmologyPhysical cosmologyNon-thermal emissionAcceleration mechanism; Accretion physics; Black-holes; Compact objects; Cosmology; Missions; Non-thermal emission; X-ray imaging; X-ray polarimetry; Astronomy and Astrophysics; Space and Planetary ScienceObservatory0103 physical sciencesBroadbandX-ray polarimetry010303 astronomy & astrophysicsCompact objectsmedia_commonPhysics010308 nuclear & particles physicsX-ray imagingVegaAstronomyAstronomy and AstrophysicsAccretion physicsCosmologySkySpace and Planetary ScienceExperimental Astronomy
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Structural and functional characterization of enamel pigmentation in shrews.

2013

Pigmented tooth enamel occurs in several vertebrate clades, ranging from mammals to fish. Although an iron compound is associated with this orange to red colored pigmentation, its chemical and structural organization within the enamel is unknown. To determine the nature of the iron compound, we investigated heavily pigmented teeth of the northern short-tailed shrew Blarina brevicauda using combined characterization techniques such as scanning and transmission electron microscopy and synchrotron X-ray diffraction. We found that the pigmentation of the enamel with an iron content of around 8wt% results from a close to amorphous magnetite phase deposited around the nm-sized enamel crystals. Fu…

Blarina brevicaudaMineralogychemistry.chemical_compoundstomatognathic systemMicroscopy Electron TransmissionX-Ray DiffractionStructural BiologyHardnessbiology.animalElastic ModulusmedicineAnimalsDental EnamelMagnetiteEnamel paintbiologyChemistryPigmentationPhotoelectron SpectroscopyShrewsShrewNanoindentationTooth enamelbiology.organism_classificationFerrosoferric Oxidestomatognathic diseasesmedicine.anatomical_structureTransmission electron microscopyvisual_artIron contentDentinvisual_art.visual_art_mediumBiophysicsJournal of structural biology
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