Search results for "YIELD"
showing 10 items of 1338 documents
Chromatographic Efficiency in Micellar Liquid Chromatography: Should it Be Still a Topic of Concern?
2013
Micellar liquid chromatography (MLC) was first proposed as an attractive alternative to avoid the use of organic solvents. It was soon apparent that pure micellar solutions yield poor efficiencies. This problem was remediated by the addition of a small amount of an organic solvent. However, the general opinion of the poor peak shape has prevailed as a handicap for MLC, in spite of the fact that the hybrid mode often offers similar or even improved efficiencies (for basic compounds) relative to that attained in the hydro-organic mode. Only the efficiencies for apolar non-ionizable compounds are still clearly inferior. This work describes the type of interactions and polarity changes with org…
Analysis of tricyclic antidepressants in pharmaceuticals by microemulsion liquid chromatography
2021
Abstract Basic compounds yield long retention times and broad and asymmetric peaks in reversed-phase liquid chromatography, due to interaction with residual silanols in the columns. The addition of the surfactant sodium dodecyl sulphate in the so called micellar liquid chromatography enhances the efficiency, but long retention is achieved, due to electrostatic interaction between the cationic species of basic compounds and the anionic sulphate group of the surfactant. This forces the addition of a strong organic solvent to get appropriate times. An alternative is the use of a microemulsion (ME), formed by mixing surfactant, oil and an alcohol as co-surfactant. Association of hydrophobic com…
Silica Entrapment for Significantly Stabilized, Energy-Conducting Light-Harvesting Complex (LHCII)
2014
The major light-harvesting chlorophyll a/b complex (LHCII) of the photosynthetic apparatus in green plants consists of a membrane protein and numerous noncovalently bound pigments that make up about one-third of the molecular mass of the pigment-protein complex. Due to this high pigment density, LHCII is potentially interesting as a light-harvesting component in synthetic constructs. However, for such applications its stability needs to be significantly improved. In this work, LHCII was dramatically stabilized by enclosing it within polymerizing colloidal silica. The entrapped LHCII stayed functional at 50 °C for up to 24 h instead of a few minutes in detergent solution and clearly showed e…
Influence of the Liquefied Starch Composition and pH on the Saccharification at the Obtaining of Maltose Syrup
1970
In this paper the influence of the composition of the liquefied starch and of pH on the quality of saccharification at the obtaining of maltose syrup is investigated. A large number of experiments (68) in various liquefaction conditions show that Dextrose Equivalent (DE) and the composition in hydrolysis products with Degree of Polymerisation higher as four (DP ≥4) in the liquefied starch have a strong influence on the saccharification products, mainly on the maltose content in the maltose syrups. The liquefied starch with DE lower as 25 has smaller amounts of DP ≥4 (40 to 60%), whereas the liquefied starch with DE between 25 and 27 has high amounts of DP ≥4 (60 to 80%). For the production …
Effects of stubble height and cutting frequency on regrowth of berseem clover in a Mediterranean semiarid environment
2011
Defoliation management of forage crops affects endogenous reserves (in the root and in the stubble), the residual leaf area, and, consequently, the regrowth and biomass yield. The aim of this study was to evaluate the effect of cutting frequency (28-d vs. 35-d intervals) and stubble height (3 vs. 6 cm) on forage yield, regrowth, and persistence of berseem clover (Trifolium alexandrinum L.). Neither cutting interval nor cutting height affected plant survival during the crop cycle. Frequent clipping reduced crop yield. Residual biomass and leaf area were less when plants were cut at a height of 3 cm compared with 6 cm, but stubble height did not affect the total amount of dry matter (DM) remo…
Mass-asymmetric fission in the 40ca+142Nd reaction
2016
Shell effects play a major role in fission. Mass-asymmetric fission observed in the spontaneous and low energy fission of actinide nuclei was explained by incorporating the fragment shell properties in liquid drop model. Asymmetric fission has also been observed in the low energy fission of neutron-deficient 180 Hg nuclei in recent β -delayed fission experiments. This low-energy β -delayed fission has been explained in terms of strong shell effects in pre-scission configurations associated with the system after capture. Calculations predicted asymmetric fission for heavier Hg isotopes as well, at compound nuclear excitation energy as high as 40 MeV. To explore the evolution of fission fragm…
Effect of Nitrogen Fertilization on the Quality of Swiss Chard at Harvest and during Storage as Minimally Processed Produce
2014
The effects of different levels of nitrogen fertilization (0–50–100–150–200 kg/ha), minimal processing and cold storage (14 days at 4C) on yield and quality of fresh-cut Swiss chard (Beta vulgaris L. var. cicla L.) were evaluated. Increasing the level of nitrogen fertilization over 100 kg N/ha, plants had a higher fresh weight, reduced their dry matter content and resulted taller and leafier. Total and marketable yield increased linearly with increasing nitrogen level. Both nitrate and ascorbic acid content at harvest increased with increasing nitrogen supply. Nitrogen fertilization negatively affected the yield of minimal processing. No effect on appearance and quality loss during cold sto…
Spectroscopic parameters related to non bridging oxygen hole centers in amorphous-SiO2
2005
The relationship between the luminescence at 1.9 eV and the absorption bands at 2.0 eV and at 4.8 eV were investigated in a wide variety of synthetic silica samples exposed to different gamma- and beta-ray irradiation doses. We found that the intensities of these optical bands are linearly correlated in agreement with the model in which they are assigned to a single defect. This finding allows to determine spectroscopic parameters related to optical transitions efficiency: the oscillator strength of the 4.8 eV results ~200 times higher than that of the 2.0 eV; the 1.9 eV luminescence quantum yield under 4.8 eV excitation is lower (by a factor ~3) than that under 2.0 eV excitation. These res…
Enhanced structural correlations accelerate diffusion in charge-stabilized colloidal suspensions
1999
Theoretical calculations for colloidal charge-stabilized and hard sphere suspensions show that hydrodynamic interactions yield a qualitatively different particle concentration dependence of the short-time self-diffusion coefficient. The effect, however, is numerically small and hardly accessible by conventional light scattering experiments. Applying multiple-scattering decorrelation equipment and a careful data analysis we show that the theoretical prediction for charged particles is in agreement with our experimental results from aqueous polystyrene latex suspensions.
Role of Mobile Interstitial Oxygen Atoms in Defect Processes in Oxides: Interconversion between Oxygen-Associated Defects inSiO2Glass
2004
The role of mobile interstitial oxygen atoms (${\mathrm{O}}^{0}$) in defect processes in oxides is demonstrated by interconversion between the oxygen dangling bond and the peroxy radical (POR) in ${\mathrm{S}\mathrm{i}\mathrm{O}}_{2}$ glass. Superstoichiometric ${\mathrm{O}}^{0}$ was created by ${\mathrm{F}}_{2}$ laser photolysis of the interstitial ${\mathrm{O}}_{2}$. On annealing above $300\text{ }\ifmmode^\circ\else\textdegree\fi{}\mathrm{C}$, ${\mathrm{O}}^{0}$ migrated and converted the oxygen dangling bond to POR. Exposure to 5.0 eV light converted POR back to a pair of the oxygen dangling bond and ${\mathrm{O}}^{0}$ (quantum yield: $\ensuremath{\sim}0.1$). These findings suggest that…