Search results for "Yield"
showing 10 items of 1338 documents
Formation of the Cationic [(2‐Aminoethenyl)carbine]iron Complexes by Treatment of (2‐Methoxyethenyl)carbene Complexes with Primary Amines:Synthesis a…
1997
Cationic (2-methoxyethenyl)methoxycarbene iron complexes 2, [Cp(CO)2Fe(C(OMe)CHCR(OMe))+][PF6−], are obtained by the addition of methanol to the corresponding (alkynyl)-methoxycarbene complexes 1, [Cp(CO)2Fe(C(OMe)CCR)+][PF6−]. Primary amines, H2NR', react with these 1,3-dimethoxy-substituted (alkenyl)carbene complexes, 2, through an addition/elimination process to yield cationic (2-aminoethenyl)methoxycarbene iron complexes, 3, [Cp(CO)2Fe(C(OMe)CHCR(NHR'))+][PF6−] in an isolated yield of 71–90%. The complexes 3a–c were characterized by X-ray structural analyses. Thus, previously isolated products, from the reaction, of the (alkynyl)methoxycarbene complexes 1a and 1c, with aniline at room t…
New Insights into the Stoichiometric and Catalytic Reactivity of Unsaturated Pd 3 (dppm) 3 CO n + Clusters ( n = 0, 1) Towards Halocarbons – First Ev…
2005
The title clusters, Pd 3 (dppm) 3 (CO) + and Pd 3 (dppm) 3 (CO) 0 can be electrochemically generated from the 1- and 2-electron reductions, respectively, of the Pd 3 (dppm) 3 (CO) 2 + cluster [dppm = bis(diphenylphosphanyl)methane; Pd 3 2 + ]. Pd 3 + reacts in a stoichiometric ratio with methyl iodide, MeI, and benzyl bromide, BzBr, in THF to provide the corresponding Pd 3 (X) + adducts (X = I, Br respectively) as inorganic products. Other products are Bz 2 and PhMe for BzBr but, for MeI, no organic product was observed (since they are too volatile). In the presence of the same substrates, Pd 3 0 also reacts in a stoichiometric ratio to form the same organics and the Pd 3 -(X) + adducts (X …
A polyhedral oligomeric silsesquioxane-based catalyst for the efficient synthesis of cyclic carbonates
2015
Polyhedral oligomeric silsesquioxane functionalized with imidazolium chloride peripheries (POSS-Imi) was successfully synthesized through a novel synthesis protocol. The solid was extensively characterized via1H NMR, 13C NMR and IR spectroscopy as well as combustion chemical analysis, mass spectrometry and transmission electron microscopy. Moreover, an in-depth investigation through 29Si NMR was performed. POSS-Imi was used for the first time as a catalyst for the conversion of CO2 and epoxides into cyclic carbonates with excellent results in terms of both yield and selectivity. The catalyst displayed improved catalytic performance with respect to unsupported 1-butyl-3-methylimidazolium chl…
Decomposition studies of group 6 hexacarbonyl complexes. Part 1: Production and decomposition of Mo(CO)6 and W(CO)6
2015
Abstract Chemical studies of superheavy elements require fast and efficient techniques, due to short half-lives and low production rates of the investigated nuclides. Here, we advocate for using a tubular flow reactor for assessing the thermal stability of the Sg carbonyl complex – Sg(CO)6. The experimental setup was tested with Mo and W carbonyl complexes, as their properties are established and supported by theoretical predictions. The suggested approach proved to be effective in discriminating between the thermal stabilities of Mo(CO)6 and W(CO)6. Therefore, an experimental verification of the predicted Sg–CO bond dissociation energy seems to be feasible by applying this technique. By in…
Domestic vs. International correlations of interest rate maturities
2010
The association between long and short interest rates is traditionally envisaged from a purely domestic perspective, where it is believed an empirical regularity. Hence, the weakening of this relationship in the first half of the 2000s has represented a conundrum, calling for a reassessment of the term structure and the conduct of monetary policy. Some commentators have called for investigations into the international dimension of this puzzle. Hence, in this paper we employ recent advances in panel data econometrics to investigate the co-movement of interest rate maturities both at the domestic and international levels for a sample of industrial countries. Specifically, we use the Ng (2006)…
The Low-Lying Excited States of 2,2′-Bithiophene: A Theoretical Analysis
2004
The low-energy region of the singlet →singlet, singlet →triplet, and triplet→triplet electronic spectra of 2,2'-bithiophene are studied using multiconfigurational second-order perturbation theory (CASPT2) and extended atomic natural orbitals (ANO) basis sets. The computed vertical, adiabatic, and emission transition energies are in agreement with the available experimental data. The two lowest singlet excited states, 1 1 B u and 2'B u , are computed to be degenerate, a novel feature of the system to be borne in mind during the rationalization of its photophysics. As regards the observed high triplet quantum yield of the molecule, it is concluded that the triplet states 2 3 A g and 2 3 B u ,…
Hydraulic Design of the Center-Pivot Irrigation System for Gradually Decreasing Sprinkler Spacing
2021
Design strategies that enhance modern irrigation practices, reduce energy consumption, and improve water use efficiency and crop yields are fundamental for sustainability. Although microirrigation is currently a widely applied method, center-pivot irrigation systems have become very popular on large farms, thanks to their automation, wide-coverage, and reliability. Different design procedures have been proposed, even though some aspects have not been solved yet. This paper presents a simple design procedure for center-pivot systems using a gradually decreasing sprinkler spacing along with a pivot lateral, which makes it possible to set favorable and uniformly distributed water application r…
Using field measurements and FAO-56 model to assess the eco-physiological response of citrus orchards under regulated deficit irrigation
2017
[EN] Micro-irrigation is considered one of the most efficient water distribution systems and allows increasing water use efficiency if coupled with effective water-saving irrigation management strategies as regulated deficit irrigation (RDI) or partial root-zone drying (PRD) techniques. However, application of these strategies makes it crucial the real-time monitoring of soil and crop water status, in order to identify appropriate irrigation scheduling parameters (irrigation timing and doses) and to prevent irreversible damage of plant system and/or crop yield reductions. Even if midday stem water potential (MSWP) is considered one of the most affordable indicator for direct determinations …
Continuous determination of fruit tree water-status by plant-based sensors
2017
Recently, climate change has caused shortages of water worldwide, especially in semi-arid and arid regions. Several irrigation strategies have been studied with the aim of saving water overuse in agriculture. In the past most of the attention was directed towards soil water content, but recently the focus has moved to plant responses to water deficit. In recent years, crop evapotranspiration (ETc) obtained from reference evapotranspiration (ET0) and crop coefficients (Kc), has become common for irrigation scheduling in several crops, but it does not provide precise insights on the tree water status. Today an increasing focus is being given to plant-based sensors for the continuous monitorin…
Monitoring Soil Salinisation as a Strategy for Preventing Land Degradation: A Case Study in Sicily, Italy
2010
Water demand is increasing worldwide. In regions affected by water scarcity such as those located in the Mediterranean basin, water supplies are already degraded, or subjected to degradation processes, which worsen the water shortage. In Sicily, the increasing scarcity of good quality water is expanding irrigation with saline-sodic waters, thus enhancing the risk of secondary salinization and sodification. Adequate management practices are urgently needed for sustainable use of saline/sodic waters. This chapter illustrates how the Geonics EM-38 probe was used for monitoring salinization in a Sicilian area where irrigation with saline water is increasingly practiced, and the risk of salinisa…