Search results for "Yle"

showing 10 items of 5917 documents

CCDC 2090119: Experimental Crystal Structure Determination

2021

Related Article: Chris Gendy, J. Mikko Rautiainen, Aaron Mailman, Heikki M. Tuononen|2021|Chem.-Eur.J.|27|14405|doi:10.1002/chem.202102804

5-{chloro[111333-hexamethyl-2-(trimethylsilyl)trisilan-2-yl]germylene}-1-[26-di-isopropylphenyl]-2244-tetramethylpyrrolidineSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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Polymeric Nanoparticles with Neglectable Protein Corona

2020

Small : nano micro 16(18), 1907574 (2020). doi:10.1002/smll.201907574

540 Chemistry and allied sciencesDispersity610 Medizinmicellar structuresNanoparticleProtein Corona02 engineering and technology010402 general chemistry01 natural sciencesPolyethylene GlycolsBiomaterialschemistry.chemical_compoundAdsorption610 Medical sciencesHumansGeneral Materials ScienceParticle SizeGel electrophoresisChemistryasymmetrical flow field-flow fractionationSarcosineGeneral Chemistry021001 nanoscience & nanotechnology0104 chemical sciencesChemical engineering540 Chemiedrug deliveryNanoparticlesParticleProtein CoronaParticle sizePeptides0210 nano-technologyHydrophobic and Hydrophilic InteractionsEthylene glycolBiotechnologySmall
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Acid‐Cleavable Poly(ethylene glycol) Hydrogels Displaying Protein Release at pH 5

2020

Abstract PEG is the gold standard polymer for pharmaceutical applications, however it lacks degradability. Degradation under physiologically relevant pH as present in endolysosomes, cancerous and inflammatory tissues is crucial for many areas. The authors present anionic ring‐opening copolymerization of ethylene oxide with 3,4‐epoxy‐1‐butene (EPB) and subsequent modification to introduce acid‐degradable vinyl ether groups as well as methacrylate (MA) units, enabling radical cross‐linking. Copolymers with different molar ratios of EPB, molecular weights (M n) up to 10 000 g mol−1 and narrow dispersities (Đ<1.05) were prepared. Both the P(EG‐co‐isoEPB)MA copolymer and the hydrogels showed pH‐…

540 Chemistry and allied sciencesVinyl CompoundsBiocompatible MaterialsDegree of polymerization010402 general chemistry01 natural sciencesCatalysisPolyethylene GlycolsPolymerizationchemistry.chemical_compoundHydrolysisPolymer chemistryPEG ratioCopolymermedicinehydrogelsPolymer Technologieschemistry.chemical_classificationFull PaperEthylene oxide010405 organic chemistryHydrolysisOrganic ChemistryBiochemistry and Molecular BiologyProteinsprotein releaseHydrogelsGeneral ChemistryPolymerFull PapersHydrogen-Ion ConcentrationVinyl etherPolymerteknologiPEG0104 chemical sciencescopolymerizationchemistry540 Chemiedrug deliverySelf-healing hydrogelsMethacrylatesBiokemi och molekylärbiologimedicine.drugChemistry – A European Journal
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Unexpected Behavior of Enaminones: Interesting New Routes to 1,6-Naphthyridines, 2-Oxopyrrolidines and Pyrano[4,3,2-de][1,6]naphthyridines

2012

Reaction of enaminones 1a&amp;#8211;d with 2-aminoprop-1-ene-1,1,3-tricarbonitrile (2) in the presence of AcOH/NH4OAc afforded 7-amino-5-oxo-5,6-dihydro-1,6-naphthyridine-8-carbonitrile derivatives 9a&amp;#8211;d. On the other hand, 2-aminopyrano[4,3,2-de] [1,6]naphthyridine-3-carbonitriles 20a&amp;#8211;c,e were the only obtained products from the reactions of 1a&amp;#8211;d with 2 in the presence of AcOH/NaOAc, while 1d afforded [3,5-bis-(4-chloro-benzoyl)-phenyl]-(4-chloro-phenyl)-methanone 21 under the same condition. The reaction of 2 with diethyl acetylenedicarboxylate in the presence of AcOH/NH4OAc afforded (4-cyano-5-dicyanomethylene-2-oxo-2,5-dihydro-1H-pyrrol-3-yl)-acetic acid eth…

7-amino-5-oxo-56-dihydro-16-naphthyridine-8-carbonitrileMagnetic Resonance Spectroscopy2-aminoprop-1-ene-113-tricarbonitrileMolecular StructureChemistryOrganic ChemistryPharmaceutical ScienceEthyl esterMedicinal chemistryArticleAnalytical Chemistrylcsh:QD241-441Diethyl acetylenedicarboxylate3-amino-2-cyanopent-2-enedinitrilelcsh:Organic chemistryChemistry (miscellaneous)enaminonesNitrilesDrug DiscoveryTransition TemperatureMolecular Medicineenaminones; 3-amino-2-cyanopent-2-enedinitrile; 7-amino-5-oxo-56-dihydro-16-naphthyridine-8-carbonitrile; 2-aminoprop-1-ene-113-tricarbonitrileNaphthyridinesPhysical and Theoretical ChemistryMolecules
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CCDC 749971: Experimental Crystal Structure Determination

2010

Related Article: Y.Rousselin, N.Sok, F.Boschetti, R.Guilard, F.Denat|2010|Eur.J.Org.Chem.|2010|1688|doi:10.1002/ejoc.200901183

8b8c-Dimethyldecahydro-2a4a6a8a-tetraazacyclopenta[fg]acenaphthylene-1-carbonitrileSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1452354: Experimental Crystal Structure Determination

2016

Related Article: Negera Abdissa, Fangfang Pan, Amra Gruhonjic, Jürgen Gräfenstein, Paul A. Fitzpatrick, Göran Landberg, Kari Rissanen, Abiy Yenesew, Máté Erdélyi|2016|J.Nat.Prod.|79|2181|doi:10.1021/acs.jnatprod.6b00178

9-hydroxy-212-dimethoxy-35a-dimethyl-233a455a12c12d-octahydro-16-dioxabenzo[l]acephenanthrylene-10-carboxylic acidSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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Las obras musicales en las radios universitarias

2018

The Spanish General Audiovisual Communication Law does not relate to Campus Radio Stations. In this context, Copyright Collection Societies do not cover them in their catalogues of general fees. For this reason, the holders of these radios are forced to negotiate them. Althoug the Intellectual Property Law and the Order ECD/2574/2015, of 2 December, contain obligations for Copyright Collection Societies, on this matter its enforcement are far from being achieved

:CIENCIAS JURÍDICAS [UNESCO]on this matter its enforcement are far from being achieved Obras musicales2386-4567 22661 Actualidad jurídica iberoamericana 502169 2018 9 6653323 Las obras musicales en las radios universitarias López Sánchezcopyrightlicencias copyleftComputingMilieux_LEGALASPECTSOFCOMPUTINGtarifascopyleft licensescopyright collection societies. 136 175ComputingMilieux_GENERALMusical worksradios universitariasUNESCO::CIENCIAS JURÍDICASthe holders of these radios are forced to negotiate them. Althoug the Intellectual Property Law and the Order ECD/2574/2015campus radio stationspropiedad intelectualfeesCristina The Spanish General Audiovisual Communication Law does not relate to Campus Radio Stations. In this contextCopyright Collection Societies do not cover them in their catalogues of general fees. For this reasonof 2 Decembercontain obligations for Copyright Collection Societiesentidades de gestión colectiva
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Usurarian contracts. Current jurisprudencial perspective

2018

El objetivo de este trabajo es destacar las novedades presentadas por la Jurisprudencia sobre contratos usurarios celebrados entre las empresas bancarias y sus clientes. La coexistencia de la Ley de Usura con las regulaciones para la protección de los consumidores contra cláusulas abusivas no ha menoscabado la vigencia de ley, pero sus diferencias en cuanto a la declaración de nulidad generan incertidumbre, por lo que sería conveniente una mayor armonización. The objective of this work is to highlight the novelties presented by the Jurisprudence on usurious contracts concluded between banking companies and their clients. The coexistence of the Usury Law with the regulations for the protecti…

:CIENCIAS JURÍDICAS [UNESCO]usura¸intereses remuneratoriousuryPerspectiva jurisprudencial actual Sabater Bayle [2386-4567 22661 Actualidad jurídica iberoamericana 502169 2018 9 6653322 Contratos usurarios]proteccion de consumidoresUsurapero sus diferencias en cuanto a la declaración de nulidad generan incertidumbre2386-4567 22661 Actualidad jurídica iberoamericana 502169 2018 9 6653322 Contratos usurarios: Perspectiva jurisprudencial actual Sabater BayleBanking contractsConsumer protectionUNESCO::CIENCIAS JURÍDICASElsa El objetivo de este trabajo es destacar las novedades presentadas por la Jurisprudencia sobre contratos usurarios celebrados entre las empresas bancarias y sus clientes. La coexistencia de la Ley de Usura con las regulaciones para la protección de los consumidores contra cláusulas abusivas no ha menoscabado la vigencia de leypor lo que sería conveniente una mayor armonización. Contratos bancariosintereses oratoriosconsumer protection 106 135moratory interestsContratos bancariosIntereses remuneratorio|Intereses oratoriosremuneration interests
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Culturas de escola e excelência: entre a integração de todos e a distinção dos melhores

2018

Sem perder de vista a multidimensionalidade inerente aos percursos escolares, este texto procura refletir sobre a importância dos fatores organizacionais na construção dos resultados académicos. O enfoque incide sobre as dimensões intra-escolares, designadamente os efeitos da cultura de escola (nas suas diferentes facetas) e dos processos de liderança sobre a socialização dos estudantes. Optando por uma linha de pesquisa reflexiva, procura-se compreender os processos de construção de habitus (no sentido de Bourdieu) e os sistemas de disposições (na ótica de Lahire) estruturadores da cultura organizacional de escola. Do ponto de vista metodológico recorre-se a dados recolhidos no âmbito de u…

:Ciências da Educação [Ciências Sociais]School culture4. EducationEstilos de liderançaCultura de escolaGeneral Medicine:SOCIOLOGÍA [UNESCO]Ciências Sociais::Ciências da EducaçãoCiências Sociais::SociologiaExcelência académica:Sociologia [Ciências Sociais]UNESCO::SOCIOLOGÍALeadership styleAcademic excellence
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Influence de la symétrie et de la taille de la molécule adsorbée sur le processus d'adsorption des composés éthyléniques sur une zéolithe de topologi…

2005

This manuscript lies within the scope of the understanding of the stepped isotherm observed during adsorption, on MFI zeolites, of some organic compounds which have a similar size to that of the pore opening of zeolite. During this work, the process of adsorption of ethylene and tetramethylethylene is initially studied by gravimetry and then by in situ infrared spectroscopy. This last technique enables to follow simultaneously the modifications of the adsorbent and the adsorbate. The analysis of these data lets suppose that the step in adsorption isotherm can be explained by taking account simultaneously of the symmetry and the size of the admolecule. In addition to the infrared bands chara…

<br />tétraméthyléthylène[CHIM.MATE] Chemical Sciences/Material chemistrytetramethylethylenespectroscopie infrarouge (FTIR)[ CHIM.MATE ] Chemical Sciences/Material chemistryethylenezéolithe ZSM-5Adsorptionthermogravimetrythermogravimétrieinfrared spectroscopy (FTIR)ZSM-5 zeolite
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