Search results for "ZINC"
showing 10 items of 1081 documents
Enhanced electron-transfer properties of cofacial porphyrin dimers through pi-pi interactions
2009
pi-pi assisted: Photoinduced electron transfer from cofacial porphyrin dimers to electron acceptors is prominently accelerated, whereas the back electron transfer is decelerated, relative to the corresponding porphyrin monomer (see figure).The radical cation of zinc tetrapentylporphyrin is dimerized with an excess of the neutral counterpart to form the dimer radical cation in which the unpaired electron is delocalized over both porphyrin rings. The dimeric radical cation exhibits an NIR absorption spectrum characteristic of weak pi-bond formation between the porphyrin rings. When cofacial porphyrin dimers, linked by different spacers, are oxidized such pi-bond formation between the porphyri…
Development of quadrupole collectivity in the neutron-rich Ni, Zn, Ge, and Se isotopes
2003
An experiment was performed to study the collective properties of neutron-rich Ni, Zn, Ge, and Se isotopes. Of particular interest is the vicinity of the N = 50 and Z = 28 shell closures. For most neutron-rich nuclei in this region of the chart of nuclei the B(E2) values of the transitions from the ground to the first excited 2+ states are unknown. This information would give valuable insight into the changes in nuclear structure when going to more neutron-rich nuclei.
Coulomb Excitation of Neutron-Rich Zn Isotopes: First Observation of the21+State inZn80
2007
Neutron-rich, radioactive Zn isotopes were investigated at the Radioactive Ion Beam facility REX-ISOLDE (CERN) using low-energy Coulomb excitation. The energy of the 2(1)+ state in 78Zn could be firmly established and for the first time the 2+ --> 0(1)+ transition in 80Zn was observed at 1492(1) keV. B(E2,2(1)+ --> 0(1)+) values were extracted for (74,76,78,80)Zn and compared to large scale shell model calculations. With only two protons outside the Z=28 proton core, 80Zn is the lightest N=50 isotone for which spectroscopic information has been obtained to date. Two sets of advanced shell model calculations reproduce the observed B(E2) systematics. The results for N=50 isotones indicate a g…
Potentialities of High-Resolution 3-D CZT Drift Strip Detectors for Prompt Gamma-Ray Measurements in BNCT
2022
Recently, new high-resolution cadmium–zinc–telluride (CZT) drift strip detectors for room temperature gamma-ray spectroscopic imaging were developed by our group. The CZT detectors equipped with orthogonal anode/cathode collecting strips, drift strips and dedicated pulse processing allow a detection area of 6 × 20 mm2 and excellent room temperature spectroscopic performance (0.82% FWHM at 661.7 keV). In this work, we investigated the potentialities of these detectors for prompt gamma-ray spectroscopy (PGS) in boron neutron capture therapy (BNCT). The detectors, exploiting the measurement of the 478 keV prompt gamma rays emitted by 94% 7Li nuclides from the 10B(n, α)7…
Unravelling the modus operandi of phytosiderophores during zinc uptake in rice: the importance of geochemical gradients and accurate stability consta…
2020
Abstract Micronutrient deficiencies threaten global food production. Attempts to biofortify crops rely on a clear understanding of micronutrient uptake processes. Zinc deficiency in rice is a serious problem. One of the pathways proposed for the transfer of zinc from soils into rice plants involves deoxymugineic acid (DMA), a phytosiderophore. The idea that phytosiderophores play a wider role in nutrition of Poaceae beyond iron is well established. However, key mechanistic details of the DMA-assisted zinc uptake pathway in rice remain uncertain. In particular, questions surround the form in which zinc from DMA is taken up [i.e. as free aqueous Zn(II) or as Zn(II)–DMA complexes] and the role…
Urinary Arsenic Species and Methylation Efficiency During Pregnancy: Concentrations and Associated Factors in Spanish Pregnant Women
2021
Background: Arsenic (As) is considered to be toxic for humans, the main routes of exposure being through drinking water and the diet. Once ingested, inorganic arsenic can be methylated sequentially to monomethyl and dimethyl arsenicals. Several factors can affect both As exposure and methylation efficiency. Objectives: To describe the urinary concentrations of the different As species and evaluate the methylation effi-ciency during pregnancy, as well as their associated factors in a birth cohort of pregnant Spanish women. Methods: Participants in this cross-sectional study were 1017 pregnant women from two areas of Spain who had taken part in the INMA (Environment and Childhood) project (20…
Más allá del acero: Otros metales y sus usos en la arquitectura del siglo XXI
2009
[ES] El protagonismo que ostentan los metales como compuestos básicos para el desenvolvimiento cotidiano de la vida humana resulta evidente e irrefutable. Del mismo modo que una mayoría de las actividades diarias que realizamos serían imposibles sin el apoyo que nos brinda el metal, un amplio porcentaje de la arquitectura de la última centuria también hace descansar sus fundamentos en la solidez de una estructura metálica. Más allá del hierro como predecesor y del acero como digno sucesor, la constructiva recurre asimismo con asiduidad a otros metales para conformar con ellos la imagen final del edificio, redundando en ésta componentes tanto técnicos como expresivos de los que son responsab…
Bioavailability and assessment of heavy metal pollution in sediment cores off the Mejerda River Delta (Gulf of Tunis): How useful is a multiproxy app…
2016
International audience; Three core samples were taken from zones offshore from the Mejerda River Delta (Tunisia) and analyzed formajor and trace elements to assess their relationships with organic matter, monosulfides and carbonates, aswell as for pollution and bioavailability. Chemical speciation,ΣSEM/AVS, the enrichment factor (EF) and thegeo-accumulation index (I-geo) were used. Iron, cadmium, lead and zinc – the most frequently mined metalsin the Mejerda catchment – were found as contaminants in the offshore areas. Estimations of trace elementaccumulation using the EF and the I-geo index show that lead, and to a lesser extent zinc, are the most pollutingmetals off the Mejerda outlet. Ac…
Impact of 70 years urban growth associated with heavy metal pollution
2014
Historical trends in trace element deposition were analyzed using herbaria specimens. We determined Al, Fe, Mg, Mn, Ca, Na, P, K, S, As, Cd, Cr, Cu, Ni, Pb and Zn contents in leaves of eight specimens collected in 1941. To assess changes, we collected the same plants from a botanical garden in 2012. The concentrations of major elements showed large species variability. However, temporal trends were predominately detected for heavy metals. The Cd, Ni and Cr contents in the 2012 leaves were 10, 13 and 16 times higher, respectively, than in 1941. Urban activities have substantially raised the levels of these metals in urban atmospheres due to changes in human activities over 70 years of urban …
Drug release from calcium and zinc pectinate beads: Impact of dissolution medium composition
2011
The aim of this study was to investigate drug release from calcium and zinc pectinate beads and to understand the impact of medium electrolytes during drug transfer. A potential drug carrier for colonic drug delivery (rutin) was prepared with calcium and zinc pectinate beads and was tested in three different simulated intestinal fluids (pH 7.3) with phosphates (Sorensen’s and Mc Ilvaine’s buffers) and without phosphates (Tris-buffer). According to swelling studies and zinc ions release, it was showed that zinc ions keep adhering to the bead surface. Drug release and swelling behaviour from the two dosage forms depend not only on pH and ionic strength but also on the electrolytes there were …