Search results for "ZIRCON"
showing 10 items of 693 documents
Low-lying levels of201Hg from the decay of201Au
1972
The decay of 26.4-min201Au has been investigated using chemically separated sources and Ge(Li), Si(Li), plastic and Nal(Tl) detectors in different singles and coincidence arrangements. The β-disintegration energy was measured to be 1.27 ± 0.10 MeV. Thirteen γ-rays were observed to belong to this decay and the new levels at 543, 549.2, 552.8, 559.1, 605.7, 645.4, 732 and 1188 keV were established in201Hg, in addition to the three previously known excited states below 200 keV.
Catalytic enantioselective Friedel–Crafts alkylation at the 2-position of indole with simple enones
2007
Abstract A procedure for the enantioselective alkylation of indole at the 2-position with simple non-chelating enones is described for the first time. Reaction between 4,7-dihydroindole and enones in the presence of zirconium(IV)–BINOL complexes, followed by a p -benzoquinone oxidation gives indoles alkylated at the 2-position with good yields and moderate enantioselectivities.
Pre-3000 Ma thermal history of the Archean Kaap Valley puton, South Africa
1992
The Kaap Valley pluton is one of several early Archean (3200-3500 Ma) tonalitetrondhjemite plutons that surround the Barberton Greenstone belt, southern Africa. Precise dating using single-grain 207 Pb/ 206 Pb evaporation of zircon and 40 Ar/ 39 Ar laser step-heating of hornblende and biotite indicates that, in its interior, the Kaap Valley pluton preserves a memory of its initial intrusion and cooling, which spanned a time from 3225 to 3142 Ma. The pluton also records the effect of a low-temperature thermal event at its margin as seen by a 40 Ar/ 39 Ar biotite age of 3035 Ma, which is perhaps related to hydrothermal activity and gold mineralization in the adjacent Barberton Greenstone belt…
LA-ICP-MS U–Pb dating of detrital rutile and zircon from the Reynolds Range: A window into the Palaeoproterozoic tectonosedimentary evolution of the …
2014
Abstract The Palaeoproterozoic Reynolds Range of the Arunta Region, central Australia, comprises a series of shallow marine clastic sediments (Reynolds Range Group) which overlies deeper water sequences of turbidites (Lander Rock Formation) and minor sandstones (“unnamed sandstone”). U–Pb age data collected from detrital rutile and zircon in these rocks indicates these sequences contain very similar age spectra, although with a notable and important shift to younger ages within the stratigraphically younger Reynolds Range Group. Detrital zircons from the “unnamed sandstone” directly underlying the unconformity with the Reynolds Range Group contain a major age component at ca. 1860 Ma, toget…
Total absorption γ -ray spectroscopy of niobium isomers
2019
15 pags. 17 figs., 5 tabs.
Exploring reactivity of a bis-sulfonium zirconocene-ate dimer: synthesis of various zwitterionic phosphonium anionic zirconocene complexes
2007
Abstract Formal [3+2] cycloaddition reactions between the bis-sulfonium zirconocene-ate dimer 1a and methylpropiolate, benzaldehyde and carbon disulfide afforded stable zwitterionic phosphonium zirconocene-ate complexes 2–4, respectively, with two orthocondensed five-membered heterocycles. X-ray crystal structure of 4 has been determined. Elemental chalcogens (S, Se, Te) gave rise also to a new variety of five-coordinate zirconium(IV) complexes (5–7) by a formal [3+1] cycloaddition reaction. In these bicyclic zirconates, sulfur is included in a five-membered ring while the second chalcogen is in a four-membered one.
Mechanical treatment of TiO2 and ZrO2 oxide mixtures
2010
The mixed ZrO2–TiO2 system (5–50 wt% of ZrO2) has been studied to investigate the influence of the mechanical treatment on its physicochemical properties depending on the composition, time of milling (5, 10 and 20 min, r.p.m. 82) and temperature (400, 550 and 700 C). Samples were characterized by Raman spectroscopy, X-ray powder diffraction, Scanning Electron Microscopy coupled with Energy Dispersion X-ray analyzer, High Resolution-Transmission Electron Microscopy and nitrogen adsorption porosimetry. Results show that srilankite (TiZrO4) phase has been produced. No influence of the milling time and temperature on the phase composition is observed. The presence of zirconia increases the ther…
Further evidence for an early Carboniferous (∼340 Ma) age of high-grade metamorphism in the Saxonian granulite complex
1998
U–Pb and Pb–Pb zircon ages for metamorphic zircons from granulites in the Saxonian granulite complex are reported, using the SHRIMP ion microprobe, conventional multigrain and single-gain techniques and the evaporation method. This is complemented by a Pb–Pb evaporation age for a post-granulite granite emplaced into the schist mantle around the granulites during uplift of the complex. We also demonstrate that zircon ages are not reset during high-grade metamorphism, as commonly argued, but have a very high closure temperature and usually preserve the isotopic composition reflecting the time of their formation. Multifaceted zircons from four granulite samples that probably grew close to the …
Single zircon U–Pb ages and geochemistry of granitoid gneisses from SW Poland: evidence for an Avalonian affinity of the Brunian microcontinent
2010
AbstractSeven granitoid gneisses from the contact zone between the eastern margin of the Variscan belt and the Brunian microcontinent in SW Poland have been dated by ion-microprobe and207Pb/206Pb single zircon evaporation methods. The zircons define two age groups for the gneiss protoliths: (1) late Neoproterozoicc.576–560 Ma and (2) early Palaeozoicc.488–503 Ma granites. The granitoid gneisses belonging to the basement of the Brunian microcontinent contain abundant Mesoproterozoic to latest Palaeoproterozoic inherited material in the range of 1200–1750 Ma. The gneisses of the Variscan crustal domain lack Mesoproterozoic inherited zircon cores. Trace element geochemistry of Proterozoic gnei…
Direct mass measurements of neutron-rich zirconium isotopes up toZr104
2004
Atomic masses of radioactive zirconium isotopes from {sup 96}Zr to {sup 104}Zr have been measured with a relative accuracy of {<=}5x10{sup -7} using a Penning trap coupled to the ion guide isotope separator on-line system. The obtained two-neutron separation energies show strong local correlation in relation to the shape change and shape coexistence between N=58 and 60.