6533b856fe1ef96bd12b1c29

RESEARCH PRODUCT

Reactivity of di-n-butyl-dicyclopentadienylzirconium towards amido stabilized stannylenes

Josef BarešPhilippe MeunierZdeňka PadělkováAleš RůžičkaNadine Pirio

subject

010405 organic chemistryoxidationOrganic Chemistry[ CHIM.COOR ] Chemical Sciences/Coordination chemistrychemistry.chemical_element010402 general chemistry01 natural sciencesBiochemistryOxygenMedicinal chemistryNMR0104 chemical sciences3. Good healthInorganic ChemistrychemistryzirconoceneMaterials ChemistryReactivity (chemistry)stannylene[CHIM.COOR]Chemical Sciences/Coordination chemistryPhysical and Theoretical ChemistryComputingMilieux_MISCELLANEOUS

description

Abstract Reaction of Sn[(N(C 6 H 3 i Pr 2 -2,6)(SiMe 3 )] 2 and [{Sn(N(C 6 H 3 i Pr 2 -2,6)(SiMe 3 )(μ-Cl) 2 ] with di- n -butyl-dicyclopentadienylzirconium yielded the trimetallic a carbene-like complex {[(N(C 6 H 3 i Pr 2 -2,6)(SiMe 3 )]( n -Bu)Sn} 2 Cp 2 Zr. The oxidation of {[(N(C 6 H 3 i Pr 2 -2,6)(SiMe 3 )]( n -Bu)Sn} 2 Cp 2 Zr by oxygen gives the five-membered dioxadistannazirconacyclic complex {[(N(C 6 H 3 i Pr 2 -2,6)(SiMe 3 )]( n -Bu)Sn} 2 O 2 Cp 2 Zr.

yearjournalcountryeditionlanguage
2009-01-30
10.1016/j.jorganchem.2009.01.041https://hal.archives-ouvertes.fr/hal-00458349