Search results for "Zeeman effect"
showing 10 items of 85 documents
A Luminescent Thermometer Exhibiting Slow Relaxation of the Magnetization: Toward Self-Monitored Building Blocks for Next-Generation Optomagnetic Dev…
2019
The development and integration of Single-Molecule Magnets (SMMs) into molecular electronic devices continue to be an exciting challenge. In such potential devices, heat generation due to the electric current is a critical issue that has to be considered upon device fabrication. To read out accurately the temperature at the submicrometer spatial range, new multifunctional SMMs need to be developed. Herein, we present the first self-calibrated molecular thermometer with SMM properties, which provides an elegant avenue to address these issues. The employment of 2,2′-bipyrimidine and 1,1,1-trifluoroacetylacetonate ligands results in a dinuclear compound, [Dy2(bpm)(tfaa)6], which exhibits slow …
Study of As and Tl high-frequency electrodeless lamps for Zeeman absorption spectroscopy
2020
High-frequency electrodeless light sources are known as bright radiators with the line spectrum, characterized by high intensities and narrow line shapes. The lamp balloons are mostly made of quartz and filled with a metal and buffer gas. These light sources must be optimized for each application in accordance with the specific requirements of radiation quality, lifetime, and stability. This work is devoted to the diagnostic of high-frequency electrodeless light sources for their use in high precision atomic absorption analyzers and other applications like disinfection. The spectral line intensities and profiles were studied in discharges with arsenic and thallium fillings. Special attentio…
Axialisation, cooling and quenching of $\mathsf{Ba^+}$ ions in a Penning trap
1998
Collisions of ions, stored in a Penning trap, with neutral background molecules usually lead to rapid ion loss from the trap unless the ions are excited by the sum of the frequencies of the reduced cyclotron and magnetron motion. Then the ions are cooled by collisions and are driven to the trap centre leading to substantial increase of the storage time. Furthermore in a three level system including a long living metastable state collisions deexcite this metastable state and increase the population density in the ionic ground state. In a laser spectroscopic experiment we demonstrate the advantages of collisions on Ba+ ions stored in a Penning trap. The combined action of metastable state que…
High-Spatial-Resolution Monitoring of Strong Magnetic Field using Rb vapor Nanometric-Thin Cell
2011
We have implemented the so-called $\lambda$-Zeeman technique (LZT) to investigate individual hyperfine transitions between Zeeman sublevels of the Rb atoms in a strong external magnetic field $B$ in the range of $2500 - 5000$ G (recently it was established that LZT is very convenient for the range of $10 - 2500$ G). Atoms are confined in a nanometric thin cell (NTC) with the thickness $L = \lambda$, where $\lambda$ is the resonant wavelength 794 nm for Rb $D_1$ line. Narrow velocity selective optical pumping (VSOP) resonances in the transmission spectrum of the NTC are split into several components in a magnetic field with the frequency positions and transition probabilities depending on th…
Zeeman effect in sulfur monoxide: A tool to probe magnetic fields in star forming regions
2017
[Context] Magnetic fields play a fundamental role in star formation processes and the best method to evaluate their intensity is to measure the Zeeman effect of atomic and molecular lines. However, a direct measurement of the Zeeman spectral pattern from interstellar molecular species is challenging due to the high sensitivity and high spectral resolution required. So far, the Zeeman effect has been detected unambiguously in star forming regions for very few non-masing species, such as OH and CN.
ENDOR Spectroscopic and Molecular Orbital Study of the Dynamical Properties of the Side Chain in Radical Anions of Ubiquinones Q-1, Q-2, Q-6, and Q-10
2000
Abstract The dynamics of the side chain of the radical anions of ubiquinones Q-1 (2,3-dimethoxy-5-methyl-6-[3-methyl-2-butenyl]-1,4-benzoquinone), Q-2, Q-6, and Q-10 have been investigated using electron nuclear double-resonance (ENDOR) spectroscopy. When radicals are produced in the liquid phase, secondary radicals are also formed. The EPR spectra of these additional radicals overlap with the radical of interest. ENDOR spectroscopy was found to be capable for studying the dynamical properties of such conditions. The temperature dependence of the isotropic hyperfine coupling constants of the β- and γ-protons of the side chain was measured. The activation energy of the rotation and other dyn…
Demonstration of sensitivity increase in mercury free-spin-precession magnetometers due to laser-based readout for neutron electric dipole moment sea…
2018
International audience; We report on a laser based $^{199}$Hg co-magnetometer deployed in an experiment searching for a permanent electric dipole moment of the neutron. We demonstrate a more than five times increased signal to-noise-ratio in a direct comparison measurement with its $^{204}$Hg discharge bulb-based predecessor. An improved data model for the extraction of important system parameters such as the degrees of absorption and polarization is derived. Laser- and lamp-based data-sets can be consistently described by the improved model which permits to compare measurements using the two different light sources and to explain the increase in magnetometer performance. The laser-based ma…
Evidence for anI=1 isomeric state in96Rb
1981
Aβ-RADOP (β-Radiation Detected Optical Pumping) experiment on the short lived (T1/2=203 ms)96Rb isotope has been performed at the on line mass separator for fission produced alkali isotopes at the TRIGA reactor in Mainz. Irradiation of r.f. onto the polarized sample to induce Zeeman transitions resulted in two signals for nuclear spinsI=2 andI=1. The previously undetermined component withI=1 is interpreted as evidence for an isomeric state in96Rb.
Evaluation of the magnetic moments of radium isotopes
1990
Using the relativistic linked cluster many-body perturbation procedure we have obtained the hyperfine field at the nucleus of the Ra+ ion in the2S1/2 ground state. There is good agreement between the calculated magnetic moment of213Ra and the results of a recent Zeeman measurement by the collinear laser beam technique. Detailed comparison is carried out between our result and earlier ones.
Hydrogen-related radiation defects in SiO2-based glasses
2008
Abstract Spectroscopic properties of hydrogen atom trapped in an oxygen vacancy in SiO2 glass were studied. Samples were loaded with D2 and H2 gases to convert O vacancies to pairs of Si–D and Si–H groups, and subsequently irradiated by F2 laser in order to destroy some of these groups. Electron paramagnetic resonance, infrared absorption and visible/UV absorption spectra were measured. Proton hyperfine doublet with splitting of 1.05 mT was found in all H2-treated/irradiated samples. UV-bleaching treatment showed that this signal is independent of the other, well-known hydrogen-related signals in silica. The size of the hyperfine splitting corresponds to twice the 1H nuclear Zeeman splittin…