Search results for "Zen"
showing 10 items of 3479 documents
Resisting Immigration Detention
2016
The aim of this article is to provide a normative analysis of the ways in which immigrants resist immigration detention. After having outlined (in Section 2) some general features that make immigration detention a rather abnormal condition for human beings to be kept in, I distinguish three main forms of resistance to it: institutionalized, non-institutionalized, and anti-institutional. I first spell out, in Section 3, some individual characteristics of these forms of resistance. Then (in Sections 4 and 5), using Italy as my test case, I suggest, for each of these forms, an interpretation of their normative meaning (that is, their meaning according to both the relevant legal rules and their…
The Understanding of Human Rights and Rule of Law from the Perspective of Kohlberg’s Theory
2015
Human rights, democracy and the rule of law are considered to be the foundations of the normative order of modern societies (Habermas, 1996). Even though the universal validity of human rights is often criticized, they represent an ethical minimum consensus of the global society as conventions on human rights have been ratified by more than 150 states.
Educazione alla cittadinanza : significati, linee di ricerca, finalità e pratiche didattiche
2016
Resumen basado en el de la publicación Título, resumen y palabras clave en italiano e inglés Monográfico con el título: Educación para la ciudadanía : significado y experiencias La globalización económica, política y comunicativa es uno de los principales problemas de la realidad histórica actual que socava las identidades sociales basadas en la pertenencia a comunidades locales y bien definidas. Las transformaciones de índole social, cultural y económica vinculadas a la globalización corresponden a una complejidad y la multidimensionalidad del concepto de ciudadanía. Hoy en día el término ciudadanía ya no se refiere exclusivamente a la participación en la vida pública y membresía en un est…
7-[(3-Chloro-6-methyl-6,11-dihydrodibenzo[c,f][1,2]thiazepin-11-yl)amino]heptanoic acidS,S-dioxide hydrochloride
2012
In the title compound, C(21)H(26)ClN(2)O(4)S(.)Cl, also known as tianeptine hydro-chloride, the seven-membered ring adopts a boat conformation. The dihedral angle between the mean planes of the benzene rings is 44.44 (7)°. There is an intra-molecular hydrogen bond formed via S= O⋯H-N. In the crystal, mol-ecules are connected via pairs of N-H.·O, N-H⋯Cl and O-H⋯Cl hydrogen bonds, forming inversion dimers, which are consolidated by C-H⋯O inter-actions. The dimers are linked by C-H⋯O and C-H⋯Cl inter-actions, forming a two-dimensional network lying parallel to (011).
(Z)-Amino(2-methyl-3-oxoisoindolin-1-ylidene)acetonitrile
2009
The asymmetric unit of the title compound, C11H9N3O, contains two independent and nearly identical molecules (A and B). Molecule A can be transformed to B using a rotation of approximately 85° around the [111] direction. Each A molecule is connected to three B molecules via N—H...N and N—H...O hydrogen bonds and vice versa. Centrosymmetrically related molecules of the same residue form π–π interactions with centroid–centroid distances of 4.326 (1) and 3.826 (1) Å for the benzene rings of molecules A and B, respectively.
4-Nitro-phenyl 2-bromo-2-methyl-propano-ate.
2011
In the title compound, C(10)H(10)BrNO(4), the planes of the carboxyl-ate and nitro groups are rotated by 60.53 (13) and 6.4 (3)°, respectively, to the benzene ring. In the crystal, inter-molecular C-H⋯O hydrogen bonds link the mol-ecules into zigzag chains parallel to the c axis.
N-(4-Acetyl-3-methyl-1-phenyl-1H-pyrazol-5-yl)-N-methyl-2-(2-methyl-4-oxo-3,4-dihydroquinazolin-3-yl)benzamide
2013
In the title compound, C29H25N5O3, the dihedral angle between the benzene ring and the pendant quinazoline ring system (r.m.s. deviation = 0.036Å) is 87.60 (17)°. The equivalent angle between the pyrazole ring and the phenyl group is 70.0 (2)°. The dihedral angle between the benzene and pyrazole rings is 30.7 (2)° and overall, the molecular conformation approximates to a Z shape. A short intramolecular C—H...O contact occurs. In the crystal, the molecules are linked by Cπ—H...O-type hydrogen bonds and aromatic π–π stacking interactions [centroid–centroid distance = 3.860 (3) Å], generating a three-…
Ab initio study of the internal rotation potential of p-disilanylbenzene and p-(1,1′,2,2′-tetramethyldisilanyl)benzene
1996
Abstract We present a detailed ab initio study of the geometrical structure and torsional potential of p -disilanylbenzene and its methyl derivative p -(1,1′,2,2′-tetramethyldisilanyl)benzene. The geometries of the different conformers have been fully optimized at the Hartree-Fock 3-21G ∗ and 6-31G ∗ levels. In all cases, the most stable conformation corresponds to the conformer in which the phenylene group lies in a plane perpendicular to the four silicon atoms. The torsional potential curves calculated using the 3-21G ∗ and 6-31G ∗ basis sets show similar features. In the case of p -(1,1′,2,2′-tetramethyldisilanyl)benzene the interactions between the hydrogen atoms of phenylene and the me…
Synthesis and COX inhibition of 7-R1-8-R2-1-ethyl-3,4-dimethyl-, 4,10-dihydro-1H-pyrazolo[3,4-c][1,5]benzodiazocine-5,11-diones
2008
The title compounds were easily synthesized by reacting the 4-aminopyrazole hydrochloride 2 and the substituted 2-nitrobenzoyl chlorides 3a-d. The obtained 2-nitrobenzamides 4a-d were methylated and then reduced to give the corresponding amines 6a-d. These were hydrolyzed then directly converted into 4,10-dihydro-1H-pyrazolo[3,4-c][1,5]benzodiazocine-5,11-diones 1a-d by the action of SOCl2 in benzene. These were tested for their COX inhibitory activity, showing an inhibitory profile against both COX-1 and COX-2, being slightly more selective against COX-2 with a percentage of inhibition, at the concentration of 10 μM, in the range 42.0 – 55.0.
Capturing Hydrophobic Trifluoroiodomethane in Water into an M 4 L 6 Cage
2016
Synthetically important trifluoroiodomethane (CF3I) was trapped in water by using a metal–organic supramolecular anionic cage. Under ambient conditions, nearly 1:1 encapsulation of the hydrophobic, gaseous CF3I substrate with the cage was observed, and its binding constant was calculated by relative comparison with benzene encapsulation.