Search results for "Zero field"
showing 10 items of 48 documents
Spin transition in iron complexes induced by heat, pressure, light and nuclear decay
1988
The phenomenon of temperature-dependent spin transition will be introduced and the numerous chemical and physical influences affecting the spin transition characteristics will be discussed. We shall mainly concentrate on the spin crossover system [Fe(2-pic)3]X2·Sol (2-pic=2-aminomethylpyridine; X=Cl, Br; Sol=C2H5OH, CH3OH) and demonstrate how the behaviour of the spin transition5T2g(Oh)⇌1A1g(Oh) is influenced by substituting the metalion, the non-coordinating anions X, the crystal solvent molecules Sol and by isotopic exchange with H/D and14N/15N. It will also be shown that the spin transition is very susceptible to pressure. A quantitative spin state conversion from low spin to high spin c…
Two-dimensional single- and multiple-quantum correlation spectroscopy in zero-field nuclear magnetic resonance.
2020
We present single- and multiple-quantum correlation $J$-spectroscopy detected in zero ($<\!\!1$~$\mu$G) magnetic field using a \Rb vapor-cell magnetometer. At zero field the spectrum of ethanol appears as a mixture of \carbon isotopomers, and correlation spectroscopy is useful in separating the two composite spectra. We also identify and observe the zero-field equivalent of a double-quantum transition in ${}^{13}$C$_2$-acetic acid, and show that such transitions are of use in spectral assignment. Two-dimensional spectroscopy further improves the high resolution attained in zero-field NMR since selection rules on the coherence-transfer pathways allow for the separation of otherwise overlappi…
Zero-field nuclear magnetic resonance spectroscopy of viscous liquids
2014
Abstract We report zero-field NMR measurements of a viscous organic liquid, ethylene glycol. Zero-field spectra were taken showing resolved scalar spin–spin coupling (J-coupling) for ethylene glycol at different temperatures and water contents. Molecular dynamics strongly affects the resonance linewidth, which closely follows viscosity. Quantum chemical calculations have been used to obtain the relative stability and coupling constants of all ethylene glycol conformers. The results show the potential of zero-field NMR as a probe of molecular structure and dynamics in a wide range of environments, including viscous fluids.
Detekcia vektora spinovej polarizácie vo viackanálovej spinovo rozlýšenej fotoemissie za použitia spinového filtra založeného na Ir(001)
2016
Physical review / B 95(10), 104423 (2017). doi:10.1103/PhysRevB.95.104423
Field Dependence of the Electron Spin Relaxation in Quantum Dots
2005
Interaction of the electron spin with local elastic twists due to transverse phonons has been studied. Universal dependence of the spin relaxation rate on the strength and direction of the magnetic field has been obtained in terms of the electron gyromagnetic tensor and macroscopic elastic constants of the solid. The theory contains no unknown parameters and it can be easily tested in experiment. At high magnetic field it provides parameter-free lower bound on the electron spin relaxation in quantum dots.
High precision measurement of the11Li and9Li quadrupole moment ratio using zero-fieldβ-NQR
2013
The ratio of electric quadrupole moments of 11 Li and 9 Li was measured using the zero-field β-detected nuclear quadrupole resonance technique at TRIUMFISAC. The precision on the ratio Q11/Q9 = 1.0775(12) was improved by more than one order of magnitude and an absolute value for the quadrupole moment of 11 Li was inferred. Systematic effects, as argued here, are not expected to contribute to the ratio on this scale. The zero-field spin-lattice relaxation time for 8 Li implanted within SrTiO3 at 295K in zero-field was found to be T1 = 1.73(2)s. A comparison of the quadrupole moments of 9,11 Li and their ratio is made with the latest models, however, no conclusion may yet be drawn owing to th…
Nuclear magnetic resonance at millitesla fields using a zero-field spectrometer
2016
We describe new analytical capabilities for nuclear magnetic resonance (NMR) experiments in which signal detection is performed with chemical resolution (via spin-spin J couplings) in the zero to ultra-low magnetic field region, below 1μT. Using magnetic fields in the 100μT to 1mT range, we demonstrate the implementation of conventional NMR pulse sequences with spin-species selectivity.
The magnetic moment anomaly of the electron bound in hydrogen-like oxygen16O7
2003
The measurement of the g-factor of the electron bound in a hydrogen-like ion is a high-accuracy test of the theory of quantum electrodynamics (QED) in strong fields. Here we report on the measurement of the g-factor of the bound electron in hydrogen-like oxygen (16O7+). In our experiment a single highly charged ion is stored in a Penning trap. The electronic spin state of the ion is monitored via the continuous Stern?Gerlach effect in a quantum non-demolition measurement. Quantum jumps between the two spin states (spin up and spin down) are induced by a microwave field at the spin precession frequency of the bound electron. The g-factor of the bound electron is obtained by varying the micro…
A Heterobimetallic Anionic 3,6-Connected 2D Coordination Polymer Based on Nitranilate as Ligand
2016
In order to synthesize new coordination polymers with original architectures and interesting magnetic properties, we used the nitranilate ligand (C₆O₄(NO₂)₂2- = C₆N₂O₈2-), derived from the dianionic ligand dhbq2- (2,5-dihydroxy-1,4-benzoquinone = H₂C₆O₄2-). The use of this bis-bidentate bridging ligand led to [(DAMS)₂{FeNa(C₆N₂O₈)₃}·CH₃CN]n (1) (DAMS⁺ = C16H17N₂⁺ = 4-[4-(dimethylamino)-α-styryl]-1-methylpyridinium), a 2D heterometallic coordination polymer presenting an unprecedented structure for any anilato-based compound. This structural type is a 3,6-connected 2D coordination polymer derived from the well-known honeycomb hexagonal structure, where Fe(III) ions alternate with Na⁺ dimers …
Quantitative evaluation of the preferential orientation ofpara-phenylene vinylene pentamers in polystyrene films by optically detected magnetic reson…
2007
The morphology of drop-casted and spin-coated films of blends ofpara-phenylene vinylenederived pentamers with polystyrene is investigated by means of X-band optically detected magnetic resonance (ODMR) of the triplet excited states. Adapting an electron spin resonance simulation program to ODMR, the orientation distribution function of the oligomers in the films could be quantified. After drop casting or spin coating the pentamers from a solution, the oligomers tend to lie with their backbones in the plane of the film. The parameters of film preparation and the type of pentamer strongly influence the orientation distribution function. Also, the study of preferentially oriented films allows …