Search results for "absorptio"

High-contrast sub-Doppler absorption spikes in a hot atomic vapor cell exposed to a dual-frequency laser field

2017

International audience; The saturated absorption technique is an elegant method widely used in atomic and molecular physics for high-resolution spectroscopy, laser frequency standards and metrology purposes. We have recently discovered that a saturated absorption scheme with a dual-frequency laser can lead to a significant sign reversal of the usual Doppler-free dip, yielding a deep enhanced-absorption spike. In this paper, we report detailed experimental investigations of this phenomenon, together with a full in-depth theoretical description. It is shown that several physical effects can support or oppose the formation of the high-contrast central spike in the absorption profile. The physi…

Search for Cosmic Neutrino Point Sources with Four Year Data of the ANTARES Telescope

2012

In this paper, a time-integrated search for point sources of cosmic neutrinos is presented using the data collected from 2007 to 2010 by the ANTARES neutrino telescope. No statistically significant signal has been found and upper limits on the neutrino flux have been obtained. Assuming an E ¿2 n; spectrum, these flux limits are at 1-10 ¿10¿8 GeV cm¿2 s¿1 for declinations ranging from ¿90° to 40°. Limits for specific models of RX J1713.7¿3946 and Vela X, which include information on the source morphology and spectrum, are also given.

Multi-resolution investigations of the methane IR spectrum. At the borderline between modelling state of the art and astrophysical needs

2009

International audience; Remote sensing of the atmosphere of astrophysical objects relies essentially on molecular spectroscopy. Astrophysical investigations generally need both complete and accurate spectroscopic databases. Despite continuous efforts in experimental and theoretical spectroscopic investigations, the lack of data in specific spectral regions of interest is one of the principal limitation of the presently available spectroscopic databases. Extrapolations to relevant experimental conditions like high temperature is also a major issue for astrophysical applications. Among other molecules, methane is present in the atmosphere of many astrophysical objects. The modeling of its abs…

Experimental study of $^{100}$Tc $\beta$ decay with total absorption $\gamma$-ray spectroscopy

2017

International audience; The β decay of Tc100 has been studied by using the total absorption γ-ray spectroscopy technique at the Ion Guide Isotope Separator On-Line facility in Jyväskylä. In this work the new Decay Total Absorption γ-ray Spectrometer in coincidence with a cylindrical plastic β detector has been employed. The β intensity to the ground state obtained from the analysis is in good agreement with previous high-resolution measurements. However, differences in the feeding to the first-excited state as well as weak feeding to a new level at high excitation energy have been deduced from this experiment. Theoretical calculations performed in the quasiparticle random-phase approximatio…

Topical anti-inflammatory potential of quercetin in lipid-based nanosystems: In vivo and in vitro evaluation

2013

Purpose: To develop quercetin-loaded phospholipid vesicles, namely liposomes and PEVs (Penetration Enhancer-containing Vesicles), and to investigate their efficacy on TPA-induced skin inflammation. Methods: Vesicles were made from a mixture of phospholipids, quercetin and polyethylene glycol 400 (PEG), specifically added to increase drug solubility and penetration through the skin. Vesicle morphology and self-assembly were probed by Cryo-Transmission Electron Microscopy and Small/Wide Angle X-ray Scattering, as well as the main physico-chemical features by Light Scattering. The anti-inflammatory efficacy of quercetin nanovesicles was assessed in vivo on TPA-treated mice dorsal skin by the d…

Non-linear optical, electrochemical and spectroelectrochemical properties of amphiphilic inner salt porphyrinic systems

2016

Three zwitterionic meso-substituted A3B- and AB2C-porphyrins containing one sulfonato alkylpyridinium substituent and three or two alkoxy-substituted phenyl groups were synthesized in good yield and fully characterized as to their physicochemical properties by a variety of techniques. This new series of inner salt donor-acceptor meso-substituted porphyrin derivatives were prepared for possible application as amphiphilic probes for membrane insertion in the area of combined second-harmonic and two-photon fluorescence cellular microscopy. To this end, the linear and nonlinear optical properties of the compounds were characterized, together with their electrochemical and spectroelectrochemica…

HEALTHCARE RESILIENCE: A DYNAMIC CAPABILITIES VIEW FOR EXPLORING THE ROLE OF DIGITAL TECHNOLOGIES AND KNOWLEDGE ABSORPTION IN MANAGING OPERATIONAL FA…

2020

THE EUROPEAN RURAL DEVELOPMENT POLICY DURING 2014 - 2020

2014

The common agricultural policy has generated contradictory discussions between Member States. Several successive reforms, due to the continuous changing of funding instruments within the common agricultural policy have lead to several changes within the policy. Since the 2000s, the reform policy was reorganized into two complementary pillars, funded through entirely different funds. Thus, the rural development policy becomes separate and specific, rather than common. The current reform, in place starting since 2013 is to bring new several new challenges: maintaining competitiveness of European agriculture within global markets and the promotion of organic farming and creating new jobs. The …

High-resolution spectroscopy of difference and combination bands of SF6 to elucidate the ν3 + ν1 − ν1 and ν3 + ν2 − ν2 hot band structures in the ν3 …

2014

The strong infrared absorption in the ν3 S–F stretching region of sulphur hexafluoride (SF6) near 948 cm−1 makes it a powerful greenhouse gas. Although its present concentration in the atmosphere is very low, it is increasing rapidly, due to industrial pollution. The ground state population of this heavy species is only 32% at room temperature and thus many hot bands are present. Consequently, a reliable remote-sensing spectroscopic detection and monitoring of this species require an accurate modelling of these hot bands. We used two experimental set-ups at the SOLEIL French synchrotron facility to record some difference and combination bands of SF6: (1) a new cryogenic multiple pass cell w…

Optical investigation of spin-crossover in cobalt(II) bis-terpy complexes

2007

Abstract The spin transition of the [Co(terpy) 2 ] 2+ complex (terpy = 2,2′:6′,2″-terpyridine) is analysed based on experimental data from optical spectroscopy and magnetic susceptibility measurements. The single crystal absorption spectrum of [Co(terpy) 2 ](ClO 4 ) 2 shows an asymmetric absorption band at 14 400 cm −1 with an intensity typical for a spin-allowed d–d transition and a temperature behaviour typical for a thermal spin transition. The single crystal absorption spectra of suggest that in this compound, the complex is essentially in the high-spin state at all temperatures. However, the increase in intensity observed in the region of the low-spin MLCT transition with increasing te…