Search results for "absorptio"
showing 10 items of 2815 documents
Use of the red-edge excitation effect for investigation of dielectric interactions in biomembranes
1999
Dipole moments of the fluorescent probes 1-phenylnaphthylamine (1-AN) and 1-anilinonaphthalene-8-sulfonate (1,8-ANS) are measured using electro-optical absorption and emission methods. Dipole moments in the ground and excited states were measured in cyclohexane and dioxane. It is shown that the charge distributions in the 1-AN and 1,8-ANS molecules differ substantially. The spectral dependence of the electro-optical coefficients suggests that the absorption spectrum of 1,8-ANS is due to a superposition of (at least two) electronic transitions. It is found that spectra of 1-AN in erythocyte ghosts are inhomogeneously broadened. The above effect makes it possible to selectively excite probe m…
<title>Electro-optical and fluorescence lifetime studies of aminophthalimide probes in liquids</title>
1995
The modified electro-optical absorption and emission methods are described as well as their use for measurements of electrical dipole moments of five aminophthalimides in ground and excited states. It is found that there exists a principal difference between properties of 3- aminophthalimide (3AP) and 4-amino-N-methylphthalimide (4ANMP) in different solvents. The equilibrated dipole moment of 3AP in its excited state is practically independent on the solvent polarity, in comparison with 4ANMP. The possible mechanism of this effect is discussed.© (1995) COPYRIGHT SPIE--The International Society for Optical Engineering. Downloading of the abstract is permitted for personal use only.
Enhanced supercontinuum generation in tapered tellurite suspended core fiber
2015
Abstract We demonstrate 400-THz (0.6–3.3 µm) bandwidth infrared supercontinuum generation in a 10 cm-long tapered tellurite suspended core fiber pumped by nJ-level 200-fs pulses from an optical parametric oscillator. The increased nonlinearity and dispersion engineering extended by the moderate reduction of the fiber core size are exploited for supercontinuum optimization on both frequency edges (i.e., 155-THz overall gain), while keeping efficient power coupling into the untapered fiber input. The remaining limitation of supercontinuum bandwidth is related to the presence of the high absorption beyond 3 µm whereas spectral broadening is expected to fully cover the glass transmission window…
Tunable dual-wavelength thulium-doped fiber laser in the range from 2067 to 2073.5 nm
2017
A tunable dual-wavelength lineal cavity Tm-doped fiber laser is presented. The generation of the laser lines is based on the use of cascaded fiber Bragg gratings and a Hi-Bi fiber optic loop mirror.
4W continuous-wave narrow-linewidth tunable solid-state laser source at 546nm by externally frequency doubling a ytterbium-doped single-mode fiber la…
2009
A high-power continuous-wave coherent light source at 545.5nm is described. We use 8.3W from a solid-state ytterbium-doped single-mode fiber oscillator/amplifier system as input into an external frequency doubling stage. This system produces up to 4.1 W of stable green single-frequency laser radiation. We characterize the light source by performing absorption spectroscopy on iodine across the full tuning range of the fiber laser and saturation spectroscopy on one strong iodine line of the doppler-broadened spectrum.
Urbach absorption edge of silica: reduction of glassy disorder by fluorine doping
2004
Abstract The vacuum-ultraviolet fundamental absorption edge (‘Urbach edge’) of four types of synthetic silica glasses, ‘wet’, ‘dry’, and doped by 570 and 6010 ppm wt. fluorine, was studied in the absorption coefficient range (1 cm−1–500 cm−1) at room temperature. The absorption edge has exponential form in agreement with the Urbach’s rule. The well-documented increase of vacuum-ultraviolet transparency upon fluorine doping is due to a steeper absorption edge (shorter ‘Urbach tail’) as compared to undoped silicas. The increase of the edge slope in F-doped silica occurs already the lower dopant concentration (570 ppm), the slope does not increase further in the 6010 ppm doped glass. These fin…
Time‐resolved absorption and luminescence following electron‐hole pair creation in ZnO
2008
We report transient absorption induced by electron-hole excitation in undoped ZnO. A laser pump/continuum probe method covers 2–300 ps, and an electron pulse with lamp transmission covers 8–300 ns. The broad absorption spectrum increases monotonically with wavelength from 900 to 1600 nm. Following a reasonable hypothesis that the free-carrier-like induced infrared absorption is proportional to the total number of free carriers, excitons, and shallow-trapped carriers in the sample, these data allow setting an upper limit on the quantum efficiency of a specified lifetime component of luminescence. For the undoped commercial ZnO studied in this report, the quantum efficiency of room temperatur…
Dopant Clusterization and Oxygen Coordination in Ta-Doped Bismuth Oxide: A Structural and Computational Insight into the Mechanism of Anion Conduction
2015
Bi2O3 in its fluorite-like form can be obtained either at 730-824 °C, showing the highest oxide-ion conduction known so far, or by doping. We present a comprehensive appraisal of the local atomic structure of Ta-doped Bi2O3 investigating by X-ray absorption spectroscopy the aggregation motifs of Ta5+ and the interaction between dopants and oxygen vacancies. Using periodic density functional theory simulations, we show that the connection of Ta4O18 aggregates is energetically favorable. We find that the local coordination of Bi3+ and its electronic structure, as seen from the calculated density of states (DOS), are invariably determined by the Bi 6s2 lone pair in both doped and undoped Bi2O3…
Biowaiver Monographs for Immediate-Release Solid Oral Dosage Forms: Ketoprofen
2012
Literature and experimental data relevant to the decision to allow a waiver of in vivo bioequivalence (BE) testing for the approval of immediate-release (IR) solid oral dosage forms containing ketoprofen are reviewed. Ketoprofen's solubility and permeability, its therapeutic use and therapeutic index, pharmacokinetic properties, data related to the possibility of excipient interactions, and reported BE/bioavailability (BA)/dissolution data were taken into consideration. The available data suggest that according to the current Biopharmaceutics Classification System (BCS) and all current guidances, ketoprofen is a weak acid that would be assigned to BCS Class II. The extent of ketoprofen abso…
Evaluation of the pH effect of formulations on the skin permeability of drugs by biopartitioning micellar chromatography☆
2004
Dermal absorption of chemicals is an area of increasing interest for the pharmaceutical and cosmetic industries, as well as in dermal exposure and risk assessment processes. Biopartitioning micellar chromatography (BMC) is a mode of reversed phase micellar chromatography that has proved to be useful in the description and prediction of several pharmacological properties of xenobiotics including oral drug absorption, ocular and skin drug permeability. The present paper deals with the application of biopartitionig micellar chromatography to evaluate the pH effect on the skin permeability of twelve non-steroidal anti-inflammatory drugs and lidocaine. For this purpose the BMC retention of the w…