Search results for "absorption."
showing 10 items of 2682 documents
Preparation and XAFS studies of organotin(IV) complexes with adenosine and related compounds and calf thymus DNA
2007
Complexes of adenosine and related compounds (adenosine-5’-monophosphate, adenosine-5’-triphosphate and pyridoxal-5-phosphate) with Bu2SnO and/or BuSnCl2 were prepared in the solid state. The compositions of the complexes were determined by standard analytical methods. It was found that the complexes contain the organotin(IV) moiety and the ligand in a ratio of 1:1. The FT-IR spectra demonstrated that Bu2SnO reacts with the D-ribose moiety of the ligands, while Bu2SnCl2 is coordinated to the deprotonated phosphate group. The basic part of the ligands does not participate directly in complex formation. Comparison of the experimental Mossbauer Δ (quadrupole splitting) values with those calcul…
Comparative Experimental and Theoretical Study of the Fe L-2,L-3-Edges X-ray Absorption Spectroscopy in Three Highly Popular, Low-Spin Organoiron Com…
2019
The occupied and unoccupied electronic structures of three highly popular, closed shell organoiron complexes ([Fe(CO)(5)], [(eta(5)-C5H5 )Fe(CO)(mu-CO)](2), and [(eta(5)-C5H5)(2)Fe]) have been theoretically investigated by taking advantage of density functional theory (DFT) calculations coupled to the isolobal analogy (Elian et al. Inorg. Chem. 1976, 15, 1148). The adopted approach allowed us to look into the relative role played by the ligand -> Fe donation and the Fe -> ligand back-donation in title molecules, as well as to investigate how CO- (terminal or bridging) and [(eta(5)-C5H5)](-)-based pi* orbitals compete when these two ligands are simultaneously present as in [(eta(5)-C5H…
Determination of Kerr and two-photon absorption coefficients of indandione derivatives
2017
This material is based upon work supported by the ERDF 1.1.1.1 activity project Nr. 1.1.1.1/16/A/046 “Application assessment of novel organic materials by prototyping of photonic devices” as well as by National Research Program “Multifunctional Materials and Composites, Photonics and Nanotechnology” (IMIS2) project “Photonics and materials for photonics”.
Optical diagnostic method for benzene detection in air
2014
In this paper we show our first results of research for creation a detector for benzene vapor and possibly other volatile organic compounds detection in air based on Zeeman atomic absorption technique. First the detailed study of benzene absorption spectra with high resolution spectrometer Jobin-Yvon 1000M was done. The absorption spectra of benzene were registered in the spectral range from 200-900 nm. More detailed analysis was done for the 240 – 260 nm spectral range to test a possibility to detect benzene by means of emission line of 254 nm of mercury.
Critical review of the atomic spectrometric analysis of arsenic in foods
1994
The literature on the determination of arsenic in foods by atomic spectroscopy involving hydride generation, platform furnace Zeeman and inductively coupled plasma has been critically reviewed. Hydride generation has been largely displaced as a powerful tool by platform furnace Zeeman, using the STPF (stabilized temperature platform furnace) concept for the control of interferences. Inductively coupled plasma with conventional pneumatic nebulization has been little used. An alternative is to employ hydride generation-ICP with extraction of the arsenic in an organic phase. This technique permits proper control of interferences together with an increase in sensitivity. Depending on the conten…
<title>Deconvolution of the mercury 253.7 nm spectral line shape for the use in absorption spectroscopy</title>
2008
In this work we present measurement and results of the deconvolution of the Hg 253.7 nm spectral line shapes, emitted from the mercury isotope high-frequency electrodeless discharge lamps, made at the Institute of Atomic Physics and Spectroscopy for the use in Zeeman Atomic Absorption Spectrometry. The emission line profiles of 254 nm Hg resonance line have been measured by means of a Zeeman scanning spectrometer at the mercury cold spot temperature value at 20 C. Then the deconvolution procedure or solving of this ill-posed inverse problem by means of the Tikhonov's regularization method [1] was performed to obtain the real spectral line shape.© (2008) COPYRIGHT SPIE--The International Soc…
<title>Advanced light sources for atomic absorption analysis</title>
2003
High-frequency electrodeless light sources (HF EDLS) are widely used as bright radiators of narrow and intensive atomic and ionic spectral lines, covering the spectrum from VUV to IR. Main characteristics of HF EDLS are high emitted spectral line intensity, long service life, and in general, narrow spectral line shapes because of low-pressure of filling elements. In this work we give a short overview of the use of HF EDLS, containing Hg, Te, Se, Zn, Pb, As, Sb, Bi, Tl, In, Cd, Sn, in Zeeman Atomic absorption devices for assaying natural, drinking, waste and technical water as well as air, soil, food products and biological samples. The first steps are made for optimization of Ge, Ga, P, S, …
Correction parameters in X-ray fluorescence analysis applying the limit dilution method (LDM)
1992
This paper is a study of the interelemental effect and its correction based on the mathematical model used to develop LDM in XRF analysis. A “compensation coefficient” is defined which is obtained from the quotient of the mass absorption coefficients of the problem and the standard (μs*/μp*). This coefficient compensates the effects produced by interactions between the analyt and the interferences and therefore acts as a correction factor for the interelemental effect within this theoretical model. The model itself establishes a simple relation of the “compensation coefficient” and the Y/H correction parameters for the unknown and the standard. An algorithm is proposed for calculating the “…
Shaken Snow Globes: Kinematic Tracers of the Multiphase Condensation Cascade in Massive Galaxies, Groups, and Clusters
2018
We propose a novel method to constrain turbulence and bulk motions in massive galaxies, groups and clusters, exploring both simulations and observations. As emerged in the recent picture of the top-down multiphase condensation, the hot gaseous halos are tightly linked to all other phases in terms of cospatiality and thermodynamics. While hot halos (10^7 K) are perturbed by subsonic turbulence, warm (10^4 K) ionized and neutral filaments condense out of the turbulent eddies. The peaks condense into cold molecular clouds (< 100 K) raining in the core via chaotic cold accretion (CCA). We show all phases are tightly linked via the ensemble (wide-aperture) velocity dispersion along the line o…
The 30 Year Search for the Compact Object in SN 1987A
2018
Despite more than 30 years of searches, the compact object in Supernova (SN) 1987A has not yet been detected. We present new limits on the compact object in SN 1987A using millimeter, near-infrared, optical, ultraviolet, and X-ray observations from ALMA, VLT, HST, and Chandra. The limits are approximately 0.1 mJy ($0.1\times 10^{-26}$ erg s$^{-1}$ cm$^{-2}$ Hz$^{-1}$) at 213 GHz, 1 Lsun ($6\times 10^{-29}$ erg s$^{-1}$ cm$^{-2}$ Hz$^{-1}$) in optical if our line-of-sight is free of ejecta dust, and $10^{36}$ erg s$^{-1}$ ($2\times 10^{-30}$ erg s$^{-1}$ cm$^{-2}$ Hz$^{-1}$) in 2-10 keV X-rays. Our X-ray limits are an order of magnitude less constraining than previous limits because we use a…