Search results for "alum"
showing 10 items of 1303 documents
Counterintuitive Mechanisms of the Addition of Hydrogen and Simple Olefins to Heavy Group 13 Alkene Analogues
2013
The mechanism of the reaction of olefins and hydrogen with dimetallenes ArMMAr (Ar = aromatic group; M = Al or Ga) was studied by density functional theory calculations and experimental methods. The digallenes, for which the most experimental data are available, are extensively dissociated to gallanediyl monomers, :GaAr, in hydrocarbon solution, but the calculations and experimental data showed also that they react with simple olefins, such as ethylene, as intact ArGaGaAr dimers via stepwise [2 + 2 + 2] cycloadditions due to their considerably lower activation barriers vis-à-vis the gallanediyl monomers, :GaAr. This pathway was preferred over the [2 + 2] cycloaddition of olefin to monomeric…
Influence of temperature on the hydration products of low pH cements
2012
International audience; The chemical evolution of two hydrated "low pH" binders prepared from binary (60% Portland cement + 40% silica fume) or ternary (37.5% Portland cement +32.5% silica fume + 30% fly-ash) mixtures was characterized over one year at 20 degrees C. 50 degrees C, and 80 degrees C. The main hydrates were Al-substituted C-S-H. Raising the temperature from 20 to 80 degrees C caused a lengthening and cross-linking of their silicate chains. Ettringite that formed in pastes stored at 20 degrees C was destabilized. Only traces of calcium sulfate (gypsum and/or anhydrite) reprecipitated after one year in some materials cured at 50 degrees C and 80 degrees C. The sulfates released w…
Influence of three types of superplasticizers on tricalciumaluminate hydration in presence of gypsum.
2006
International audience; Different types of superplasticizers have been widely used over the past few decades in order to produce a more fluid or very high strength and durable concrete. These chemical admixtures interfere with the various physico-chemical processes occurring in early cement paste. In this paper we present results from a study on the influence of superplasticizers on pure tricalciumaluminate hydration in presence of gypsum. The suspensions hydration has been investigated by conductimetry, isothermal calorimetry and total organic carbon analysis of the liquid phase. The time taken for ettringite formation has been determined without superplasticizer and in presence of three d…
Tutorial multimèdia per al desenvolupament de treballs de fi de grau en Informació i Documentació
2013
La pàgina web i els materials creats formen part del projecte d'Innovació Educativa: Tutorial multimèdia per al desenvolupament de treballs de fi de grau en Informació i Documentació. La preparació i defensa d’un Treball de Fi de Grau constitueix una de les principals novetats derivades del procés de construcció de l’Espai Europeu d’Educació Superior (EEES). En aquest treball queden reflectides totes les habilitats adquirides pels estudiants en els anys previs a la finalització del Grau, atès que els estudiants han d’enfrontar-se en el mateix al procés de generació autònoma de coneixement i a les dificultats que comporta un treball de tipus pràctic. El present document recull l’experiència …
Multi-directional vs. mono-directional multi-step strategies for single point incremental forming of non-axisymmetric components
2020
Abstract Multi Stage approach is used in Single Point Incremental Forming (SPIF) to overcome one of the main forming limitations, namely the maximum wall angle, characterizing the single stage process. In this paper, different multi-path strategies for the production of parts with flat edges are considered in order to evaluate the best solution in terms of feasibility and geometrical accuracy of the final part: A) mono-directional incremental draw angle; B) mono-directional incremental draw angle with increasing part side; C) Multi-directional approach with non-horizontal path planes. Strain evaluation by means of CGA (Circular Grid Analysis) and defect analysis have been carried out in ord…
Key factors for industrial applicability of friction stir welded t-joints of different materials
2010
CDRX modelling in friction stir welding of AA7075-T6 aluminum alloy: analytical approaches
2007
Abstract Friction stir welding (FSW) is an energy efficient and environmentally “friendly” (no fumes, noise, or sparks) welding process, during which the workpiece are welded together in a solid-state joining process at a temperature below the melting point of the workpiece material under a combination of extruding and forging. Significant microstructural evolution takes place during FSW: in particular continuous dynamic recrystallization (CDRX) phenomena result in a highly refined grain structure in the weld nugget and strongly affect the final joint resistance. In the paper two different analytical models aimed to the determination of the average grain size due to continuous dynamic recry…
Enhancing formability of aluminium alloys by superimposing hydrostatic pressure
2003
Publisher Summary One of the strategic topics in manufacturing engineering is represented by the reduction of components weight. This aim is pursued by utilizing accurate and effective design tools and using lightweight metals such as aluminum, magnesium, and titanium alloys. Unfortunately, such materials often show a poor ductility, and thus enhancing formability is nowadays one of the most relevant research focus, as well as the development of effective and reliable predictive models of defects insurgence during forming processes. In this scenario, forming by means of superimposed hydrostatic pressure represents a promising alternative manufacturing technique. The chapter discusses the si…
Comparison between FSW and bonded lap joints - A preliminary investigation
2017
Difficult to weld aluminium alloys can be effectively joined by different alternative processes. Friction Stir Welding (FSW), among the solid-state processes and adhesive bonding represent two very attractive techniques. They allow the production of highly resistant joints avoiding the formation of the typical fusion weld defects. The aim of this work is to identify, analyse and compare the mechanical properties of AA6016 aluminium alloy joints made out of 1 mm thick sheets. FSW lap joints were and epoxy bonded joints were produced. Using the FSW results as benchmark, the overlap required in the bonded joint was identified to ensure the same static strength. Once the geometric configuration…