Search results for "angle"

showing 10 items of 1921 documents

Influence of metal–support interaction on the surface structure of gold nanoclusters deposited on native SiOx/Si substrates

2014

The structure of small gold nanoclusters (R ~ 2.5 nm) deposited on different silica on silicon substrates is investigated using several characterization techniques (AFM, XRD, EXAFS and GISAXS). The grain morphology and the surface roughness of the deposited gold clusters are determined by AFM. The in-plane GISAXS intensity is modelled in order to obtain information about the cluster size and the characteristic length scale of the surface roughness. AFM and GISAXS results are in excellent agreement and show that the surface morphology of the deposited clusters depends on whether defect-rich (native) or defect-free (thermal) silica is used as a substrate. Gold clusters show a strong tendency …

Gold clusterMaterials scienceExtended X-ray absorption fine structureGeneral Physics and AstronomyNanoparticleNanotechnologySubstrate (electronics)Thermal treatmentgoldNanoclustersEXAFSsurfaces nanoparticles GISAXS AFMChemical engineeringSurface roughnessGrazing-incidence small-angle scatteringPhysical and Theoretical ChemistryGISAXSmetal-support interactionPhysical Chemistry Chemical Physics
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Palladium Supported on Cross-Linked Imidazolium Network on Silica as Highly Sustainable Catalysts for the Suzuki Reaction under Flow Conditions

2013

Highly cross-linked imidazolium-based materials, obtained by radical oligomerization of bis-vinylimidazolium salts in the presence of 3-mercaptopropyl-modified silica gel, were used as supports for palladium catalysts. Thanks to the high imidazolium loading these materials were able to support a high amount of the metal (10 wt%). Such materials were characterized by several techniques (13C magic angle spinning nuclear magnetic resonance, the Brunauer-Emmett-Teller technique, X-ray photoelectron spectroscopy, and transmission electron microscopy). The palladium catalysts displayed good activity allowing the synthesis of several biphenyl compounds in high yields working with only 0.1 mol% of …

Green chemistryflow chemistryInorganic chemistrychemistry.chemical_elementCatalysisMetalchemistry.chemical_compoundSuzuki reactionMagic angle spinningsustainable chemistry; catalysis flow chemistrysustainable chemistryC C couplingSuzuki-Miyaura reactioncatalyst recyclingBiphenylcatalysisSilica gelSettore CHIM/06 - Chimica OrganicaGeneral ChemistrypalladiumSuzuki–Miyaura reactionchemistryvisual_artvisual_art.visual_art_mediumC-C couplingPalladiumAdvanced Synthesis & Catalysis
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An Integral on a Complete Metric Measure Space

2015

We study a Henstock-Kurzweil type integral defined on a complete metric measure space \(X\) endowed with a Radon measure \(\mu\) and with a family of “cells” \(\mathcal{F}\) that satisfies the Vitali covering theorem with respect to \(\mu\). This integral encloses, in particular, the classical Henstock-Kurzweil integral on the real line, the dyadic Henstock-Kurzweil integral, the Mawhin’s integral [19], and the \(s\)-HK integral [4]. The main result of this paper is the extension of the usual descriptive characterizations of the Henstock-Kurzweil integral on the real line, in terms of \(ACG^*\) functions (Main Theorem 1) and in terms of variational measures (Main Theorem 2).

HK-integralMeasure (physics)Space (mathematics)26A39Settore MAT/05 - Analisi MatematicaMetric (mathematics)CalculusGeometry and Topology28A12HK-integral ACG4 function critical variationAnalysis\(ACG^\bigtriangleup\) functionMathematicscritical variation
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Crystal structure and theoretical study of (2E)-1-[4-hydroxy-3-(morpholin-4-ylmethyl)phenyl]-3-(thiophen-2-yl)prop-2-en-1-one

2018

WOS: 000437492100018

HOMOLUMOCyclohexane conformationThio-Crystal structureDihedral angleRing (chemistry)01 natural sciencesResearch CommunicationsMannich Baseschemistry.chemical_compoundquantum-Chemical CalculationChalconesMorpholineGeneral Materials ScienceBenzeneCrystallographyMathematics::Commutative Algebra010405 organic chemistryHydrogen bondGeneral ChemistryCondensed Matter PhysicsCondensed Matter::Mesoscopic Systems and Quantum Hall EffectTheoretical Study0104 chemical sciences010404 medicinal & biomolecular chemistryCrystallographychemistryQD901-999Crystal Structure
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3d mesh denoising using normal based myriad filter

2011

We propose a new filtering scheme for denoising of 3D objects which are represented by a triangular mesh. This scheme consists on applying myriad filter to face normals and then updating the vertices positions in order to preserve the original shape of the object. The choice of the Myriad is justified by the assumption of Cauchy distributed angles between surface normals. This filter improves the performance of a normal-based method which is adapted to the underlying mesh structure. To evaluate these methods of filtering, we use three error metrics. The first is based on the vertices, the second is based on the normals and the third is based on Hausdorff distance. Experimental results demon…

Hausdorff distanceNoise reductionFace (geometry)Triangle meshMedian filterCauchy distributionPolygon meshFilter (signal processing)TopologyAlgorithmComputingMethodologies_COMPUTERGRAPHICSMathematics2011 Seventh International Conference on Signal Image Technology & Internet-Based Systems
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Heat Capacity and entanglement

2012

Starting from a recent result on thermodynamic equilibrium of quantum systems, a connection between thermal properties, originating from Gibbs state probabilistic structure, and quantum correlations is discussed as a consequence of entanglement monogamy. As an example, a simple two-qubit system is analyzed, allowing for an expression of such a connection as an explicit function linking heat capacity to a measure of bipartite entanglement.

Heat capacity entanglement concurrence thermal equilibrium
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A possible jet precession in the periodic quasar B0605-085

2010

The quasar B0605-085 (OH 010) shows a hint for probable periodical variability in the radio total flux-density light curves. We study the possible periodicity of B0605-085 in the total flux-density, spectra and opacity changes in order to compare it with jet kinematics on parsec scales. We have analyzed archival total flux-density variability at ten frequencies (408 MHz, 4.8 GHz, 6.7 GHz, 8 GHz, 10.7 GHz, 14.5 GHz, 22 GHz, 37 GHz, 90 GHz, and 230 GHz) together with the archival high-resolution very long baseline interferometry data at 15 GHz from the MOJAVE monitoring campaign. Using the Fourier transform and discrete autocorrelation methods we have searched for periods in the total flux-de…

High Energy Astrophysical Phenomena (astro-ph.HE)PhysicsActive galactic nucleusOpacityAstrophysics::High Energy Astrophysical PhenomenaFOS: Physical sciencesAstronomy and AstrophysicsQuasarAstrophysicsAstrophysics::Cosmology and Extragalactic AstrophysicsViewing angleLight curveAstrophysics - Astrophysics of GalaxiesSpectral lineInterferometrySpace and Planetary ScienceAstrophysics of Galaxies (astro-ph.GA)Very-long-baseline interferometryAstrophysics - High Energy Astrophysical PhenomenaAstrophysics::Galaxy Astrophysics
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NuSTARandXMM–Newtonbroad-band spectrum of SAX J1808.4–3658 during its latest outburst in 2015

2018

The first discovered accreting millisecond pulsar, SAX J1808.4-3658, went into X-ray outburst in April 2015. We triggered a 100 ks XMM-Newton ToO, taken at the peak of the outburst, and a 55 ks NuSTAR ToO, performed four days apart. We report here the results of a detailed spectral analysis of both the XMM-Newton and NuSTAR spectra. While the XMM-Newton spectrum appears much softer than in previous observations, the NuSTAR spectrum confirms the results obtained with XMM-Newton during the 2008 outburst. We find clear evidence of a broad iron line that we interpret as produced by reflection from the inner accretion disk. For the first time, we use a self-consistent reflection model to fit the…

High Energy Astrophysical Phenomena (astro-ph.HE)line: formation line: identification stars: individual: SAX J1808.4-3658 stars: magnetic fields stars: neutron X-rays: binaries X-rays: generalPhysics010308 nuclear & particles physicsAstrophysics::High Energy Astrophysical PhenomenaFOS: Physical sciencesBroad bandAstronomy and AstrophysicsAstrophysics01 natural sciencesSpectral lineRadial velocityNeutron starSettore FIS/05 - Astronomia E AstrofisicaSpace and Planetary ScienceMillisecond pulsarInclination angle0103 physical sciencesSpectral analysisAstrophysics - High Energy Astrophysical Phenomena010303 astronomy & astrophysicsLine (formation)Monthly Notices of the Royal Astronomical Society
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Hierarchies of geometric entanglement

2007

We introduce a class of generalized geometric measures of entanglement. For pure quantum states of $N$ elementary subsystems, they are defined as the distances from the sets of $K$-separable states ($K=2,...,N$). The entire set of generalized geometric measures provides a quantification and hierarchical ordering of the different bipartite and multipartite components of the global geometric entanglement, and allows to discriminate among the different contributions. The extended measures are applied to the study of entanglement in different classes of $N$-qubit pure states. These classes include $W$ and $GHZ$ states, and their symmetric superpositions; symmetric multi-magnon states; cluster s…

High Energy Physics - TheoryFOS: Physical sciencesMONOTONESQuantum entanglementSquashed entanglementMultipartite entanglementCombinatoricsSYSTEMSQuantum mechanicsMathematical PhysicsPhysicsQuantum PhysicsQUANTUM-MECHANICSCluster stateCURRENT SITUATIONQUANTUM-MECHANICS CURRENT SITUATION STATES SYSTEMS MONOTONESMathematical Physics (math-ph)Quantum PhysicsAtomic and Molecular Physics and OpticsCondensed Matter - Other Condensed MatterMultipartiteHigh Energy Physics - Theory (hep-th)STATESQubitBipartite graphW stateQuantum Physics (quant-ph)Other Condensed Matter (cond-mat.other)Physical Review A
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Strong monogamy of bipartite and genuine multipartite entanglement: The Gaussian case

2007

We demonstrate the existence of general constraints on distributed quantum correlations, which impose a trade-off on bipartite and multipartite entanglement at once. For all N-mode Gaussian states under permutation invariance, we establish exactly a monogamy inequality, stronger than the traditional one, that by recursion defines a proper measure of genuine N-partite entanglement. Strong monogamy holds as well for subsystems of arbitrary size, and the emerging multipartite entanglement measure is found to be scale invariant. We unveil its operational connection with the optimal fidelity of continuous variable teleportation networks.

High Energy Physics - TheoryINFORMATIONGaussianGeneral Physics and AstronomyFOS: Physical sciencesQuantum entanglementSquashed entanglementTeleportationMultipartite entanglementMeasure (mathematics)symbols.namesakeQuantum mechanicsCondensed Matter - Statistical MechanicsMathematical PhysicsMathematicsDiscrete mathematicsQuantum PhysicsStatistical Mechanics (cond-mat.stat-mech)Mathematical Physics (math-ph)Quantum PhysicsHigh Energy Physics - Theory (hep-th)symbolsBipartite graphCONTINUOUS-VARIABLE SYSTEMSW stateQuantum Physics (quant-ph)
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