Search results for "batch reactor"
showing 10 items of 50 documents
The metabolic versatility of PAOs as an opportunity to obtain a highly P-enriched stream for further P-recovery
2015
The effects of two sequencing batch reactor operation strategies for phosphorus stream enrichment over the biological phosphorus removal performance have been studied. The objective of both strategies is of performing an extraction cycle in order to obtain a new stream highly enriched with phosphorus. In the 1st strategy the amount of influent volatile fatty acids (VFAs) is the same in each cycle; while in the 2nd strategy the influent VFAs concentration is increased during phosphorus extraction experiments. Despite the strong decrease of the stored poly-P inside the cells in both strategies after the recovery cycles, the ability of the systems to remove phosphorus was not affected. The P-r…
Evaluation of activated sludge model no.2 at high phosphorus concentrations
2001
This paper presents laboratory scale experimentation carried out to study enhanced biological phosphorus removal at high phosphorus concentrations in a sequencing batch reactor. Four series of data obtained in a sequencing batch reactor are examined in light of the Activated Sludge Model No. 2. This model was calibrated using data from the first and second series working at low phosphorus concentrations. The Activated Sludge Model No. 2 successfully characterised the enhanced biological phosphorus removal performance of the sequencing batch reactor at low phosphorus concentrations. The calibrated model was then used to adjust experimental results of the other series working at high phosphor…
Effect of organic loading rate on the production of Polyhydroxyalkanoates from sewage sludge
2023
The aim of this work was to study the effect of organic loading rate on the production of Polyhydroxyalkanoates (PHA) from sewage sludge. Synthesis of PHA using sewage sludge as platform was achieved in this work. Three pilot-scale selection-sequencing batch reactors (S-SBR) were used for obtaining a culture able to accumulate PHA following a strategy of aerobic dynamic feeding (ADF) at different volumetric organic-loading-rate (vOLR): 1.3, 1.8 and 0.8 g COD L-1 d-1 for S-SBR 1, S-SBR 2 and S-SBR 3, respectively. Decreasing the vOLR enhanced the general performance of the process as for organic matter removal (from 99.2% ± 0.3% in S-SBR-3 to 92 ± 2 in S-SBR-2) while the opposite trend was r…
Spatio-temporal perturbation of the dynamics of the ferroin catalyzed Belousov-Zhabotinsky reaction in a batch reactor caused by sodium dodecyl sulfa…
2008
The effects of the anionic surfactant sodium dodecyl sulfate (SDS) on the spatio-temporal and temporal dynamics of the ferroin-catalyzed Belousov-Zhabotinsky (BZ) reaction have been studied over a wide surfactant concentration range. For the first time, investigations were performed also for unstirred systems. The presence of SDS in the reaction mixture influences the oscillatory parameters to an extent that significantly depends on the surfactant concentration. The trend of the wave speed v upon the increasing amount of SDS was found to have a maximum at [SDS] = 0.075 mol dm (-3) ( v = 0.071 mm s (-1)), after which the speed decreased to 0.043 mm s (-1) at [SDS] = 0.5 mol dm (-3), which is…
Interesterification of rapeseed oil catalysed by a low surface area tin (II) oxide heterogeneous catalyst
2018
Abstract The interesterification of rapeseed oil was performed in a batch reactor using for the first time low surface area massive tin(II) oxide as heterogeneous catalyst and methyl acetate as acyl acceptor. The effect of reaction temperature, methyl acetate to oil molar ratio and catalyst loading on the performances of the process were investigated. Yields in fatty acid methyl esters (FAMEs) and triacetin (TA) up to 90% and 70% respectively, were achieved after 4 h of reaction time at 483 K in the presence of 0.69 mol of SnO per mole of rapeseed oil using a methyl acetate to oil molar ratio of 40. Quite interestingly, the catalyst performances improved when water was added to the reaction…
Autohydrolysis pretreatment of Arundo donax: a comparison between microwave-assisted batch and fast heating rate flow-through reaction systems
2015
Background: Autohydrolysis of lignocellulosic biomass in liquid hot water has been widely studied owing to its high efficiency and relatively low cost. In the perspective of industrial applications, continuous or semi-continuous processes are more interesting than batch systems. Moreover, microwave heating of pretreatment systems has been proposed to intensify the kinetics of the process. In this study, the autohydrolysis of Arundo donax was performed in pure liquid hot water using a microwave-heated batch reactor and a semi-continuous flow-through reaction system with fast heating rate at the same operating conditions with the aim of performing a systematic comparison between the two diffe…
New time-dependent Monte Carlo algorithm designed to model three-phase batch reactor processes: applications on 2,4-dinitro-toluene hydrogenation on …
2003
Abstract The hydrogenation of 2,4-dinitro-toluene on a Pd/C catalyst was employed as a test reaction to simulate, by the time-dependent Monte Carlo method, processes occurring in a three-phase batch reactor working at isobar and isotherm conditions. A new time-dependent Monte Carlo algorithm, including an original subroutine useful to reduce the time of the simulations, was developed and implemented in Fortran language. The paper describes the flowchart of the code together with the main technical details and the involved physical and chemical models. Computational characteristics, such as the simulated time to reach surface steady state conditions and the effects of the catalyst morphology…
A Friendly-Biological Reactor SIMulator (BioReSIM) for studying biological processes in wastewater treatment processes
2014
Biological processes for wastewater treatments are inherently dynamic systems because of the large variations in the influent wastewater flow rate, concentration composition and the adaptive behavior of the involved microorganisms. Moreover, the sludge retention time (SRT) is a critical factor to understand the bioreactor performances when changes in the influent or in the operation conditions take place. Since SRT are usually in the range of 10-30 days, the performance of biological reactors needs a long time to be monitored in a regular laboratory demonstration, limiting the knowledge that can be obtained in the experimental lab practice. In order to overcome this lack, mathematical model…
Kinetics and characteristics of 70 °C, VFA-grown, UASB granular sludge
1999
We studied in batch reactors the kinetics and characterization of 70 °C, volatile fatty acids (VFAs)-grown, upflow anaerobic sludge blanket granular sludge with 55 and 35 °C sludge as reference. The half-saturation constant (Ks), the inhibition constant (Ki), the maximum specific methane production rate (μCH4max), and the inhibition response coefficient (n) of the 70 °C sludge were 6.15 mM, 48.2 mM, 0.132 h−1, and 2.48, respectively, while no inhibition occurred at 55 and 35 °C, where the Ks was 3.67 and 3.82 mM, respectively. At 70 °C, the highest initial specific methanogenic activity (ISMA, 0.311 gCH4-COD per gram volatile solids per day) on VFAs was about 12–15% lower than that on aceta…
Comparison of different predictive models for nutrient estimation in a sequencing batch reactor for wastewater treatment
2006
Abstract In this paper different predictive models for nutrient estimation in a sequencing batch reactor (SBR) for wastewater treatment are compared: principal component regression (PCR), partial least squares (PLS), and artificial neural networks (ANNs). Two unfolding procedures were used: batch-wise and variable-wise. For the latter unfolding method, X and Y matrix augmentation with lagged variables were used in some models to incorporate process dynamics. The results have shown that batch-wise unfolding PLS models outperform the other approaches. The ANN models are good predictive models, but in this particular case-study, they do not outperform those multivariate projection models that …