Search results for "biohiili"
showing 10 items of 12 documents
Conversion of furfural to 2-methylfuran over CuNi catalysts supported on biobased carbon foams
2021
In this study, carbon foams prepared from the by-products of the Finnish forest industry, such as tannic acid and pine bark extracts, were examined as supports for 5/5% Cu/Ni catalysts in the hydrotreatment of furfural to 2-methylfuran (MF). Experiments were conducted in a batch reactor at 503 K and 40 bar H2. Prior to metal impregnation, the carbon foam from tannic acid was activated with steam (S1), and the carbon foam from pine bark extracts was activated with ZnCl2 (S2) and washed with acids (HNO3 or H2SO4). For comparison, a spruce-based activated carbon (AC) catalyst and two commercial AC catalysts as references were investigated. Compressive strength of the foam S2 was 30 times great…
Preparation and Characterization of Pulp and Paper Mill Sludge-Activated Biochars Using Alkaline Activation : A Box–Behnken Design Approach
2022
This study utilized pulp and paper mill sludge as a carbon source to produce activated biochar adsorbents. The response surface methodology (RSM) application for predicting and optimizing the activated biochar preparation conditions was investigated. Biochars were prepared based on a Box–Behnken design (BBD) approach with three independent factors (i.e., pyrolysis temperature, holding time, and KOH:biomass ratio), and the responses evaluated were specific surface area (SSA), micropore area (Smicro), and mesopore area (Smeso). According to the RSM and BBD analysis, a pyrolysis temperature of 800 °C for 3 h of holding and an impregnation ratio of 1:1 (biomass:KOH) are the optimum conditions f…
How and why does willow biochar increase a clay soil water retention capacity?
2018
Addition of biochar into a soil changes its water retention properties by modifying soil textural and structural properties. In addition, internal micrometer-scale porosity that is able to directly store readily plant available water affects soil water retention properties. This study shows how precise knowledge of the internal micrometer-scale pore size distribution of biochar can deepen the understanding of the biochar-water interactions in soils. The micrometer-scale porosity of willow biochar was quantitatively and qualitatively characterized using X-ray tomography, 3D image analysis and Helium ion microscopy. The effect of biochar application on clay soil water retention was studied by…
Effects of biochar addition on anaerobic digestion and comparison of different biochar qualities
2017
Tässä pro gradu -työssä tutkittiin, voidaanko anaerobisen mädätyksen toimintaa parantaa lisäämällä mädätysprosessiin pieniä määriä biohiiltä. Anaerobista mädätystä tutkittiin laboratoriomittakaavan biokaasukokeilla, joissa biokaasureaktoreita käsiteltiin sekä pyrolyyttisesti että hydrodermaalisesti tuotetulla biohiilellä. Biohiilen mahdolliseen kykyyn lievittää ammoniakki-inhibitiota kiinnitettiin huomiota. Seitsemän pyrolyyttisen ja yhden hydrodermaalisen hiilen ominaisuuksia vertailtiin, jotta voitaisiin määrittää soveltuvia biohiiliä anaerobiseen mädätykseen. Biohiilistä analysoitiin ammonium-adsorptiokapasiteetti, irtoavan liukoisen orgaanisen kokonaishiilen (DOC) ja liukoisen kokonaist…
Effect of Tire-Char Ash on the Extent of Synergy during CO2 Cogasification with Hydrochar from Potassium-Rich Coconut Fiber
2020
The influence of inherent tire char ash during co-gasification with coconut hydrochar prepared at different intensities was investigated by thermogravimetric analysis to ascertain the extent to which synergistic interaction, reactivity, and activation energy reduction were altered. High-ash tire tread (TT) and low-ash sidewall (SW) both exhibited enhanced synergy, reactivity, and activation reduction upon co-gasification with hydrochars; however, the extent of promotion was more pronounced in SW-hydrochar blends. This difference was caused by the inhibiting nature of TT inherent ash, particularly the role of Si-containing compounds. Inhibition in TT-hydrochar blends was mainly due to the pr…
Facile synthesis of sustainable activated biochars with different pore structures as efficient additive-carbon-free anodes for lithium- and sodium-io…
2022
The present work elucidates facile one-pot synthesis from biomass forestry waste (Norway spruce bark) and its chemical activation yielding high specific surface area (SBET) biochars as efficient lithium- and sodium-ion storage anodes. The chemically activated biochar using ZnCl2 (Biochar-1) produced a highly mesoporous carbon containing 96.1% mesopores in its structure as compared to only 56.1% mesoporosity from KOH-activated biochars (Biochar-2). The latter exhibited a lower degree of graphitization with disordered and defective carbon structures, while the former presented more formation of ordered graphite sheets in its structure as analyzed from Raman spectra. In addition, both biochars…
Current state and future perspectives of biochar applications in Finland
2018
Kiinnostus biohiiltä kohtaan lisääntyy jatkuvasti, sillä biohiili tarjoaa taloudellisia ja ympäristön kannalta kestäviä ratkaisuja. Biohiiltä on tutkittu Suomessa noin kymmenen vuotta, mutta vasta viime aikoina sen taloudellinen kannattavuus on tunnistettu. Aikaisemmat biohiileen liittyvät tutkimukset ovat keskittyneet lähinnä pyrolyysiprosessiin, biohiilen ominaisuuksiin sekä biohiilen potentiaalisten käyttökohteiden tutkimiseen. Biohiilen markkinatilannetta ei ole vielä Suomessa tutkittu, lukuun ottamatta biohiilen käyttöä energiantuotannossa (biohiilen poltto), mikä on kuitenkin rajattu tästä tutkimuksesta. Tämän työn tarkoitus on tutkia biohiilen käytön nykyistä tilannetta ja sen tuleva…
Bisphenol A removal from water by biomass-based carbon : Isotherms, kinetics and thermodynamics studies
2020
Biomass-based carbon was modified and used as an efficient bisphenol A (BPA) sorbent. The simple and environmentally friendly modification method produced sorbent with a capacity of 41.5 mg/g. The raw material was modified with FeCl3 (Fe-CR), treated with hydrochloric acid (H-CR) or modified with CaCl2 (Ca-CR). Batch sorption experiments were performed to evaluate the effects of the initial pH, sorbent dosage, temperature, and contact time on BPA removal. BPA removal with modified carbons was notably higher than that with unmodified carbon. All sorbent materials exhibited very high sorption capacities and compared favourably to materials reported in the literature. Several isotherms were ap…
Enhanced nitrogen removal of low carbon wastewater in denitrification bioreactors by utilizing industrial waste toward circular economy
2020
Aquaculture needs practical solutions for nutrient removal to achieve sustainable fish production. Passive denitrifying bioreactors may provide an ecological, low-cost and low-maintenance approach for wastewater nitrogen removal. However, innovative organic materials are needed to enhance nitrate removal from the low carbon effluents in intensive recirculating aquaculture systems (RAS). In this study, we tested three additional carbon sources, including biochar, dried Sphagnum sp. moss and industrial potato residues, to enhance the performance of woodchip bioreactors treating the low carbon RAS wastewater. We assessed nitrate (NO3−) removal and microbial community composition during a one-y…
Effects of pyrolysis temperature on the hydrologically relevant porosity of willow biochar
2018
Biochar pore space consists of porosity of multiple length scales. In direct water holding applications like water storage for plant water uptake, the main interest is in micrometre-range porosity since these pores are able to store water that is easily available for plants. Gas adsorption measurements which are commonly used to characterize the physical pore structure of biochars are not able to quantify this pore-size range. While pyrogenetic porosity (i.e. pores formed during pyrolysis process) tends to increase with elevated process temperature, it is uncertain whether this change affects the pore space capable to store plant available water. In this study, we characterized biochar poro…