Search results for "c60"

LIQUIDI IONICI E FULLERENI: PIATTAFORME PER NUOVI MATERIALI

The synthesis of innovative catalysts based on different carbon nanoforms (CNFs), namely fullerene C60 and carbon nanotubes (CNTs), and their application in Suzuki and Heck C-C coupling reactions, constitutes the common thread of the first part (Chapter 1 and 2) of this thesis. C60 and CNTs were functionalized with ionic liquids (ILs) and poly-amidoamine (PAMAM) dendrimers, respectively, and used as supports for palladium nanoparticles (PdNPs). Moreover, additional supported catalytic systems based on one of the synthesized C60-IL hybrids were prepared and successfully employed in the title coupling reactions. The final part (Chapter 3) of the thesis deals on the microwave-mediated synthesi…

Understanding the Experiences of Heavy Smokers after Exercise

2015

There is now strong evidence that exercise has an acute effect on the urge to smoke and the accompanying withdrawal symptoms. However, the perceptions by heavy smokers of exercise and its relationship to the urge to smoke have not been well documented. The aim of the present study is to understand the experiences of heavy smokers with regard to exercise and its effect on their urge to smoke. Five physically inactive, heavy smokers are asked to abstain from smoking the night before exercising on a cycle ergometer under two conditions (one at medium and one at vigorous intensity done a week apart). Semi-structured, in-depth interviews are conducted after the second exercise session. Thematic …

CCDC 949723: Experimental Crystal Structure Determination

2014

Related Article: Alexander Giovannitti, Stefan M. Seifermann, Angela Bihlmeier, Thierry Muller, Filip Topic, Kari Rissanen, Martin Nieger, Wim Klopper, and Stefan Bräse|2013|Eur.J.Org.Chem.|2013|7907|doi:10.1002/ejoc.201301146

Multivariate GARCH estimation via a Bregman-proximal trust-region method

2011

The estimation of multivariate GARCH time series models is a difficult task mainly due to the significant overparameterization exhibited by the problem and usually referred to as the "curse of dimensionality". For example, in the case of the VEC family, the number of parameters involved in the model grows as a polynomial of order four on the dimensionality of the problem. Moreover, these parameters are subjected to convoluted nonlinear constraints necessary to ensure, for instance, the existence of stationary solutions and the positive semidefinite character of the conditional covariance matrices used in the model design. So far, this problem has been addressed in the literature only in low…

Restoring Harmony in the Lifeworld? : Identity, Learning, and Leaving Preelite Sport

2020

Sport provides many youth participants with a central life project, and yet very few eventually fulfill their athletic dreams, which may lead them to disengage from sport entirely. Many studies have explored the processes of athletic retirement, but little is known about how youth athletes actually reconstruct their relationship with sport and embodiment postretirement. The authors explored these issues in the story of “Pilvi,” a Finnish alpine skier who disengaged from sport in her late adolescence. Employing an existential-phenomenological approach, they conducted six low-structured interviews with Pilvi, combined with visual methods, and identified key themes relating to the body, space,…

About Vertex Mappings

2019

Summary In [6] partial graph mappings were formalized in the Mizar system [3]. Such mappings map some vertices and edges of a graph to another while preserving adjacency. While this general approach is appropriate for the general form of (multidi)graphs as introduced in [7], a more specialized version for graphs without parallel edges seems convenient. As such, partial vertex mappings preserving adjacency between the mapped verticed are formalized here.

Beyond life-skills: talented athletes, existential learning and (Un)learning the life of an athlete

2022

Following developments in educational discourse more broadly, learning discourses in youth sport have been shaped by outcome-based and instrumental goals of developing useful life-skills for ‘successful’ lives. There is, however, a need to expand such traditional understandings of sport-based youth development, which we undertook by exploring existential learning in sport through encountering discontinuity. We conducted in-depth qualitative research with 16 Finnish athletes (seven men/nine women, aged 19–20), five of whom had recently disengaged from the athlete development pathway. In the interviews, we used creative non-fiction vignettes to invite reflections on learning experiences in sp…

Global Dynamics and Imbalance Effects in the Lucas-Uzawa Model: Further Results

2007

In this paper we use a new analytical approach to the Lucas-Uzawa model (Boucekkine and Ruiz Tamarit, 2007) to extend the existing results on the dynamics, and notably on the imbalance effects arising in the model. The approach does not only allow to extend the traditional analysis to any initial conditions and for all variables in level, but it also permits a more general investigation of imbalance effects.

[60]Fullerene l -Amino Acids and Peptides: Synthesis under Phase-Transfer Catalysis Using a Phosphine–Borane Linker. Electrochemical Behavior

2017

International audience; A new method to link amino acid and peptide derivatives to [60]fullerene is described. It uses hydrophosphination with a secondary phosphine borane. First, the stereoselective synthesis of secondary phosphine borane amino acid derivatives was achieved by alkylation of phenylphosphine borane with gamma-iodo-alpha-amino ester reagents under phase transfer catalysis (PTC). Second, a sec-phosphine borane amino ester was saponified and coupled with alpha,gamma-diamino esters to afford the corresponding dipeptide derivatives in good yields. Finally, the hydrophosphination reaction of [60]fullerene by the sec-phosphine borane compounds was performed under PTC to obtain C-60…