Search results for "caesium"
showing 10 items of 63 documents
CsPbCl3 nanocrystals dispersed in the Rb0,8Cs0,2Cl matrix studied by far-infrared spectroscopy
2009
Abstract The comparative far-infrared spectroscopy studies of Rb0.8Cs0.2Cl and Rb0.8Cs0.2Cl containing CsPbCl3 nanocrystals between 170 and 320 K are reported. The effect of cesium lead chloride nanocrystals on the phonon modes of the host matrix, particularly manifested in different temperature behavior of LO–TO splitting and the temperature dependence of high frequency dielectric constant, are demonstrated.
Thermodynamic characterisation of novel solutions for closed-loop reverse electrodialysis
2018
Closed-loop reverse electrodialysis is a novel technology to convert low-grade heat directly into electricity. It consists of a reverse electrodialysis unit coupled with a regeneration unit in which the waste-heat is used to restore the initial conditions of the two solutions. One of the most impor- tant advantages of closed-loop system is the possibility to select an ad-hoc salt solution to obtain high efficiency. In this regard, it is important to assess how the salt solution properties affect the performance of the energy generation and solution regeneration processes. The aim of this study is to analyse the effect of thermodynamic properties of non-conventional salt solutions within a R…
Quantum transport of single neutral atoms
2007
The state-selective (quantum) transport of single neutral atoms stored in a one dimensional optical lattice is a promising technique to implement controlled atomic interaction using coherent cold collisions. This is required in several schemes of quantum information processing. Here, we present a technical implementation of the quantum transport scheme for one, two and more caesium atoms, as well as the manipulation and detection of their internal states.
Controlled insertion and retrieval of atoms coupled to a high-finesse optical resonator
2008
We experimentally investigate the interaction between one and two atoms and the field of a high-finesse optical resonator. Laser-cooled caesium atoms are transported into the cavity using an optical dipole trap. We monitor the interaction dynamics of a single atom strongly coupled to the resonator mode for several hundred milliseconds by observing the cavity transmission. Moreover, we investigate the position-dependent coupling of one and two atoms by shuttling them through the cavity mode. We demonstrate an alternative method, which suppresses heating effects, to analyze the atom-field interaction by retrieving the atom from the cavity and by measuring its final state.
Interacting Rubidium and Caesium Atoms
2007
Binary mixtures of ultracold atoms are of great interest in the research field of quantum optics and are studied by several groups aiming at different applications. This paper works with rubidium and caesium, which are simultaneously stored in a magnetic trap. Species-selective microwave cooling is used on the rubidium groundstate hyperfine transition. Caesium is sympathetically cooled via elastic collisions with rubidium. When cooling down the mixture to temperatures below 1 muK, below 4 muK we observe strong losses of caesium. Analysing the dynamics of sympathetic cooling, lower limit for the modulus of the rubidium-caesium triplet s-wave scattering length is estimated.
Cs[Ag4Zn2(SCN)9].
2002
Caesium tetrasilver dizinc nonathiocyanate, Cs[Ag4Zn2(SCN)9], forms a continuous structure, where the Ag atoms and the S atoms of the thiocyanate groups form chains which run along [101]. These chains are bonded together through the Cs and Zn atoms. It is not possible to distinguish between space groups P1 and P\overline 1, but, if the latter space group is correct, the structure contains a thiocyanate group disordered across a centre of inversion. The structure is described in space group P\overline 1, in which the Cs atom also lies on a centre of inversion.
Recent advances in synthesis, surface chemistry of cesium lead-free halide perovskite nanocrystals and their potential applications
2020
Abstract Cesium lead halide perovskite nanocrystals (NCs) have emerged as a key material for optoelectronic applications owing to their outstanding optical properties and easy synthesis in solution. Nowadays, the scientific community is facing a daring challenge toward the synthesis of lead-free perovskite NCs with high stability and excellent optical properties for the fabrication of optoelectronic devices with enhanced performance. In this sense, cesium lead-free halide perovskites (CsLFHPs) are demonstrated as extremely less susceptible toward oxygen and moisture and suitable candidates for long-term device applications. Thus, synthesis and identification of CsLFHP NCs essentially need u…
Efficient microwave-assisted direct radiosynthesis of [(18)F]PR04.MZ and [(18)F]LBT999: selective dopamine transporter ligands for quantitative molec…
2009
Abstract PR04.MZ 8-(4-fluoro-but-2-ynyl)-3- p -tolyl-8-aza-bicyclo[3.2.1]octane-2-carboxylic acid methyl ester ( 1 ) and LBT999 8-(( E )-4-fluoro-but-2-enyl)-3b- p -tolyl-8-aza-bicyclo[3.2.1]octane-2β-carboxylic acid methyl ester ( 2 ) are selective dopamine reuptake inhibitors, derived from cocaine. Compounds 1 and 2 were labelled with fluorine-18 at their terminally fluorinated N-substituents employing microwave enhanced direct nucleophilic fluorination. K[ 18 F]F − Kryptofix ® 222 cryptate, tetrabutyl ammonium [ 18 F]fluoride and caesium [ 18 F]fluoride were compared as fluoride sources under conventional and microwave enhanced conditions. Fluorination yields were remarkably increased un…
Interaction of sodium, lithium, caesium, and potassium ions with ascorbyl radicals.
1987
Abstract The influence of the concentration of sodium, lithium , caesium, and potassium ions as well as of the ionic strength of the solutions used on the dismutation rate of ascorbyl radicals has been investigated. While the dismutation rate was not influenced by Li+, it decreased, however, with increasing concentrations of the other ions investigated. The largest effect was obtained with Na+. This change in dismutation rate indicates a stabilizing effect on ascorbyl radical by these ions.
High-contrast dark resonances on the D1 line in cesium nanocell: the advantages compared with the other alkali D lines
2015
Electromagnetically induced transparency (EIT) effect in a -system formed by Cs atoms line, enclosed in nanometric-thin cells, is studied both experimentally and theoretically for the first time. T...