6533b82afe1ef96bd128c486
RESEARCH PRODUCT
Cs[Ag4Zn2(SCN)9].
Minna GünesJussi Valkonensubject
CrystallographyChemistryGroup (periodic table)CaesiumAtomchemistry.chemical_elementSpace groupMoleculeGeneral MedicineCrystal structureSpace (mathematics)Inversion (discrete mathematics)General Biochemistry Genetics and Molecular Biologydescription
Caesium tetrasilver dizinc nonathiocyanate, Cs[Ag4Zn2(SCN)9], forms a continuous structure, where the Ag atoms and the S atoms of the thiocyanate groups form chains which run along [101]. These chains are bonded together through the Cs and Zn atoms. It is not possible to distinguish between space groups P1 and P\overline 1, but, if the latter space group is correct, the structure contains a thiocyanate group disordered across a centre of inversion. The structure is described in space group P\overline 1, in which the Cs atom also lies on a centre of inversion.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2002-08-10 | Acta crystallographica. Section C, Crystal structure communications |