0000000000585874
AUTHOR
Minna Günes
Potassium silver thiocyanate
The structure of K[Ag(SCN)2] forms a three-dimensional network consisting of seven-coordinated K atoms and four-coordinated Ag atoms connected together by bridging thiocyanate groups.
Dicaesium silver zinc thiocyanate, Cs2[AgZn(SCN)5]
The title compound, dicaesium(I)-μ-thiocyanato-κ2N:S-zinc(II)-tetra-μ-thiocyanato-κ2S:N-argentate(I), crystallizes in the orthorhombic space group Pmn21 and contains units of composition AgZn(SCN)3 lying on a mirror plane and bonded together through Cs+ ions and thiocyanate groups. The crystal studied contained equal numbers of inversion twins.
Cs[Ag4Zn2(SCN)9].
Caesium tetrasilver dizinc nonathiocyanate, Cs[Ag4Zn2(SCN)9], forms a continuous structure, where the Ag atoms and the S atoms of the thiocyanate groups form chains which run along [101]. These chains are bonded together through the Cs and Zn atoms. It is not possible to distinguish between space groups P1 and P\overline 1, but, if the latter space group is correct, the structure contains a thiocyanate group disordered across a centre of inversion. The structure is described in space group P\overline 1, in which the Cs atom also lies on a centre of inversion.
Calcium dicaesium silver thiocyanate dihydrate.
The title compound, CaCs2[Ag2(SCN)6]·2H2O, forms a continuous structure where the Ag atoms form chains with S atoms in the c-axis direction. The chains are bonded together through Cs and Ca atoms. The crystal water of the structure is bonded to the Ca atoms, which lie on centers of symmetry.
Powder X-ray diffraction data for potassium silver thiocyanate, AgK(SCN)2 and dipotassium silver thiocyanate, AgK2(SCN)3
Previously unpublished powder X-ray diffraction data for potassium silver thiocyanate, AgK(SCN)2 and dipotassium silver thiocyanate, AgK2(SCN)3 are presented. F30 values for AgK(SCN)2 and AgK2(SCN)3 are 80(0.0075, 50) and 53(0.0089, 63), respectively. The Rietveld refinement of the patterns is also performed. For AgK(SCN)2Rp=6.98, Rwp=11.84, and RBragg=2.9. For AgK2(SCN)3Rp=7.22, Rwp=10.79, and RBragg=5.0.