Search results for "calor"
showing 10 items of 866 documents
Heat-capacity anomaly due to spin reorientation and thermodynamic functions of ErFeO3 and TmFeO3
2001
Abstract Heat capacities of orthoferrites, ErFeO 3 and TmFeO 3 , have been measured below room temperature by adiabatic calorimetry. A broad but definite anomaly due to the spin reorientation phenomenon was successfully detected in the expected temperature range (ca. 90 K). The results are compared with a vast anomaly reported for YbFeO 3 . The temperature dependence of the electric quadrupole splitting of the Fe nuclear levels was determined by Mossbauer spectroscopy through the spin reorientation. A heat capacity anomaly centered at 3.60 K due to the magnetic ordering of Er 3+ ions was clearly detected. Some Schottky anomalies were resolved and energy splittings involved were roughly esti…
Halloysite nanotubes/pluronic nanocomposites for waterlogged archeological wood: thermal stability and X-ray microtomography
2020
Filling a polymer with halloysite nanotubes is considered a promising strategy to generate nanocomposites with tailored physicochemical properties. We have focused our attention on pluronic block copolymer/halloysite nanocomposites prepared by melt blending. The effect of composition on thermal stability and polymer crystallinity was investigated by thermogravimetry and differential scanning calorimetry. Electron microscopy was used to monitor the nanoparticle distribution in the polymeric matrix. The pluronic thermal stability is reduced by the clay nanoparticles. Concerning the polymer crystallinity, it is slightly decreased even if the melting temperature is lowered by halloysite. Furthe…
Structure-dependent tuning of electro-optic and thermoplastic properties in triphenyl groups containing molecular glasses
2015
Abstract The series of seven molecular compounds composed of D–π–A chromophores and triphenylmethyl auxiliary groups were characterized by UV–Vis spectroscopy, differential scanning calorimetry and quantum chemical calculations. Nonlinear optical (NLO) properties of compounds were determined by second harmonic generation measurements in corona poled thin glassy films. The results show that triphenylmethyl auxiliary groups are effective at shielding undesirable dipole interactions in solid phase thus increasing NLO efficiency of materials. Thermal stability up to 108 °C was achieved for a polar order in poled samples.
Corundum type indium oxide nanostructures: ambient pressure synthesis from InOOH, and optical and photocatalytic properties
2016
A simple, cost effective, surfactant free and scalable synthesis of rhombohedral In2O3 (rh-In2O3) nanostructures with controllable size and shape has been developed under ambient pressure by thermal dehydration of InOOH nanostructures. The InOOH nanostructures have been prepared by solvothermal reaction between indium nitrate hydrate with tetramethylammonium hydroxide (TMAH) in anhydrous methanol at 140 °C without any surfactant. The structure and morphology of the nanostructures have been characterized in detail by X-ray powder diffraction (XRD), Raman spectroscopy, and high-resolution transmission electron microscopy (HRTEM). The studies reveal that highly crystalline nanostructures of In…
The effect of the composition on the properties of?-irradiated ethylenevinyl alcohol copolymers
1983
Two ethylene-vinyl alcohol copolymers (Eval E and Eval F with about 45% and 25% of ethylene respectively) have been irradiated in air in the dose range 0–200 Mrad. The irradiated samples show both crosslinking and degradation; the former effect is more relevant in the copolymer with a larger content of polyethylene. Calorimetric results show that both the crystalline and the amorphous phases are involved in the reactions initiated by the irradiation.
Planar Array Technology for the Fabrication of Germanium X-Ray Microcalorimeters
2008
Several technologies are presently competing for measuring the temperature increase in cryogenic micro-calorimeters used as high resolution energy-dispersive X-ray detectors. Doped germanium, whose resistivity depends on temperature, is a promising material for this purpose, because of its comparatively low specific heat and the possibility of making wafers with high doping uniformity by neutron transmutation. Presently, Ge-based microcalorimeters are still micro-machined and manually assembled. Here we present a planar approach to the fabrication of 2-D arrays of microcalorimeters and show the preliminary technological results.
Electroplated bismuth absorbers for planar NTD-Ge sensor arrays applied to hard x-ray detection in astrophysics
2018
Single sensors or small arrays of manually assembled neutron transmutation doped germanium (NTD-Ge) based microcalorimeters have been widely used as high energy-resolution detectors from infrared to hard X-rays. Several planar technological processes were developed in the last years aimed at the fabrication of NTD-Ge arrays, specifically designed to produce soft X-ray detectors. One of these processes consists in the fabrication of the absorbers. In order to absorb efficiently hard X-ray photons, the absorber has to be properly designed and a suitable material has to be employed. Bismuth offers interesting properties in terms of absorbing capability, of low heat capacity (needed to obtain h…
Compensating isothermal calorimeter to investigate the vulcanization of factice
1990
Abstract Sulphur factice is produced from a mixture of a vegetable oil and sulphur for linkage. To start vulcanization, the mixture is heated to temperatures betueen 130 and 150 °C. Within hours or days the temperature increases to about 160 °C and the product solidifies. To investigate the production process and to optimize the reaction, the temperature development was simulated in laboratory-scale experiments and the heat released was measured. In order to investigate the reaction kinetics of the entire vulcanization process, the calorimeter must a11ow the measurement of the mixture in liquid and solid state. The developed compensating calorimeter consists of a hot plate equipped with thi…
Effect of Poly(Titanium Oxide) on the Viscoelastic and Thermophysical Properties of Interpenetrating Polymer Networks
2021
The authors thank V. Serga for many useful discussions. The research was (partly) performed in the Institute of Solid State Physics, University of Latvia ISSP UL. ISSP UL as the Center of Excellence is supported through the Framework Program for European universities Union Horizon 2020, H2020-WIDESPREAD-01–2016–2017-Teaming Phase 2 under Grant Agreement No. 739508, CAMART2 project.
Influence of orthophosphate ions on the dissolution of tricalcium silicate
2008
International audience; Tricalcium silicate dissolution in the presence of orthophosphate ions was monitored by measuring the concentrations of calcium and silicate ions in dilute suspensions using a special dissolution cell coupled to an optical emission spectrometer. Results show that increasing adsorption of orthophosphate ions slows down the dissolution of Ca3SiO5 and that a calcium-phosphate precipitate may form at certain orthophosphate concentrations. These observations are correlated with results of calorimetric experiments carried out during the hydration of silica-rich cement pastes in the presence of the same salts.