Search results for "carbon dioxide"

showing 10 items of 564 documents

Sterilization of macroscopic poly(l-lactic acid) porous scaffolds withdense carbon dioxide: Investigation of the spatial penetration of thetreatment …

2016

Abstract In this work the sterilization with dense carbon dioxide of poly( l -lactic acid) (PLLA) porous scaffolds intended for tissue engineering applications was investigated with the main objective of confirming the three-dimensional efficacy of the treatment and of analysing the scaffold properties after CO2 treatment. For this purpose the scaffold was contaminated with a conventional bacterium (Escherichia coli) and with spores (Streptomyces coelicolor), a species more fascinating and difficult to inactivate. Contamination was performed in such a way to soak the whole matrix with bacteria and spores. The effect of pressure and treatment time on the efficacy of the sterilization was eva…

0301 basic medicineScaffoldBiocompatibilityGeneral Chemical Engineering030106 microbiologyNanotechnology02 engineering and technology03 medical and health scienceschemistry.chemical_compoundTissue engineeringPhysical and Theoretical ChemistrySettore ING-IND/24 - Principi Di Ingegneria ChimicabiologyChemistryPenetration (firestop)Sterilization (microbiology)021001 nanoscience & nanotechnologyCondensed Matter Physicsbiology.organism_classificationDense carbon dioxide Sterilization PLLA scaffolds E. coli S. coelicolor BiocompatibilitySupercritical fluidLactic acidChemical engineering0210 nano-technologyBacteria
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CO2 flux emissions from the Earth's most actively degassing volcanoes, 2005-2015

2019

AbstractThe global carbon dioxide (CO2) flux from subaerial volcanoes remains poorly quantified, limiting our understanding of the deep carbon cycle during geologic time and in modern Earth. Past attempts to extrapolate the global volcanic CO2 flux have been biased by observations being available for a relatively small number of accessible volcanoes. Here, we propose that the strong, but yet unmeasured, CO2 emissions from several remote degassing volcanoes worldwide can be predicted using regional/global relationships between the CO2/ST ratio of volcanic gases and whole-rock trace element compositions (e.g., Ba/La). From these globally linked gas/rock compositions, we predict the CO2/ST gas…

0301 basic medicineVolcanologylcsh:MedicineAtmospheric sciencesCarbon cycleVolcanic Gases03 medical and health scienceschemistry.chemical_compound0302 clinical medicine[SDU.STU.VO]Sciences of the Universe [physics]/Earth Sciences/Volcanologyeventlcsh:Scienceevent.disaster_typeCarbon dioxide in Earth's atmospheregeographyMultidisciplinarygeography.geographical_feature_categoryAtmospheric carbon dioxidelcsh:RTrace elementFOS: Earth and related environmental sciencesVolcanologyGeochemistry030104 developmental biologyVolcanochemistry[SDU]Sciences of the Universe [physics]Carbon dioxideSubaerialEnvironmental scienceVolcanoeslcsh:Q030217 neurology & neurosurgeryvolcanic gas fluxes voclanoes
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The emissions reduction potential of substituting short-haul flights with non-high-speed rail (NHSR): The case of Finland

2021

Abstract Replacing short-haul flights with high-speed rail (HSR) has been widely discussed as one solution to mitigate the climate change impacts of aviation. However, although HSR can provide travel times similar to those provided by short-haul flights, and at lower emission levels, it also requires considerable investments in time and infrastructure to build. Instead, this study considers the feasibility of replacing short-haul flights with existing non-high-speed rail (NHSR). Our study is based in Finland, a country that has an extensive route network of short-haul flights but does not possess any HSR. We compared all 16 city pairs for which short-haul flights are offered with existing N…

050210 logistics & transportationAviationbusiness.industry05 social sciencesGeography Planning and Development0211 other engineering and technologiesCarbon dioxide equivalentClimate change021107 urban & regional planningTransportation02 engineering and technologyUrban StudiesReduction (complexity)Transport engineering0502 economics and businessEnvironmental sciencebusinessAir travelCase Studies on Transport Policy
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Thermomineral waters of Greece: geochemical characterization

2020

75 °C). In terms of pH most results vary from 5.5 to 823 °C) ii) warm (23 40 °C) iii) thermal (40 75 °C) and iv) hyperthermal (&gtfew springs show either very low pH (&lt10) proposing serpentinization processes. Regarding TDS concentrations collected waters can be subdivided into low salinity (up to 1.5 g/L) brackish (up to 20 g/L) and saline (up to 43 g/L). The medium high salinities can be justified by mixing with sea water and/or strong waterrock interaction processes. Isotope composition of O and H ranges from 12.7 to +2.7 ‰ SMOW and from 91 to +12 ‰ SMOW respectively and is generally comprised between the Global Meteoric Water Line and the East Mediterranean Meteoric Water Line. Only few water samples show a positive shift for δ18O possibly related to high temperature waterrock interaction processes. Carbon dioxide (18 997000 μmol/mol) or N2 (1100 989000 μmol/mol) or CH4 (&ltMany geothermal areas of Greece are located in regions affected by Miocene or Quaternary volcanism and in continental basins characterised by elevated heat flow. Moreover the majority of them is found along the coast as well as in islands of the Aegean Sea and thus thermal water is often brackish to saline due to marine intrusion into costal aquifer. In the present study almost 300 thermal and cold mineral water samples were collected along the Hellenic territory with their physicochemical parameters (temperature pH electrical conductivity and Eh) and the amount of bicarbonates (titration with 0.1N HCl) being determined in situ. Additionally gases found either in free or dissolved phase were sampled. Both water and gas samples were analysed at the INGVPa laboratories for major ions (Ion Chromatography) silica (Inductively Coupled Plasma Optical Emission Spectrometry) chemical composition of free and dissolved gases (Gas Chromatography) water isotopes (O and H) and carbon and helium isotopes of free and dissolved gases (Mass Spectrometry). The temperature of the investigated waters ranges from 6.5 to 98°C pH from 1.96 to 11.98 whilst Total Dissolved Solids (TDS) from 0.06 to 43 g/L. Based on the temperature parameter waters can be divided into four groups: i) cold (&lt0.5 913000 μmol/mol) are the prevailing gas species found in the studied sites. The δ13CCO2 values ranged from 20.1 to +8.5 ‰ whilst the isotope ratio of He from 0.21 to 6.71 R/RA.4) suggesting interaction with H2Srich gases or very high pH values (&gtSettore GEO/08 - Geochimica E Vulcanologia
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Utilization of impedance spectroscopy to investigate the self-assembly behavior of amphiphiles soluble in supercritical carbon dioxide: Preliminary r…

2007

Abstract A mixture of CO 2 , water, methyl orange (MO) and Dynol 604 surfactant was analyzed at 309 K and 20 MPa simultaneously by impedance and UV–vis spectroscopy. A plot of the static dielectric constant as a function of the surfactant concentration was obtained using a suitable equivalent circuit to elaborate impedance data. Experimental points can be fitted by two different straight lines whose intersection occurs at about 0.13% (w/w) concentration of Dynol. When the surfactant concentration crossed the aforementioned value, a peak was detectable in the UV–vis spectrum at a wavelength range corresponding to the absorption of MO; absorbance of the peak increased with the surfactant conc…

AbsorbanceSupercritical carbon dioxidePulmonary surfactantChemistryGeneral Chemical EngineeringCritical micelle concentrationAnalytical chemistryMicroemulsionPhysical and Theoretical ChemistryCondensed Matter PhysicsSpectroscopySupercritical fluidDielectric spectroscopyThe Journal of Supercritical Fluids
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Upgrading landfill gas using a high pressure water absorption process

2014

Abstract The upgrading of landfill gas (methane 54.2 ± 2.0%, carbon dioxide 42.1 ± 2.4% and nitrogen 3.7 ± 1.2%) was studied with a pilot-scale high pressure water absorption system consisting of absorption, desorption and gas drying units. The gas was upgraded in two phases and with two absorption columns operating in sequence in pressures up to 180 bar, and with initial pressures of 8 and 10 bar. This type of high pressure process, where water is used for increasing the gas pressure, does not need a separate compression unit to produce the gas pressure required by gas vehicles. Product gas with a methane contents ranging from 83.0% to 92.1% was achieved with differing process parameters, …

Absorption of waterbusiness.industryGeneral Chemical Engineeringta1172Organic ChemistryEnergy Engineering and Power TechnologyWater gasPulp and paper industryMethanePressure swing adsorptionchemistry.chemical_compoundFuel TechnologyLandfill gaschemistryNatural gasCarbon dioxideta219Absorption (chemistry)businessFuel
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A broader model for C 4 photosynthesis evolution in plants inferred from the goosefoot family (Chenopodiaceae s.s.)

2012

C 4 photosynthesis is a fascinating example of parallel evolution of a complex trait involving multiple genetic, biochemical and anatomical changes. It is seen as an adaptation to deleteriously high levels of photorespiration. The current scenario for C 4 evolution inferred from grasses is that it originated subsequent to the Oligocene decline in CO 2 levels, is promoted in open habitats, acts as a pre-adaptation to drought resistance, and, once gained, is not subsequently lost. We test the generality of these hypotheses using a dated phylogeny of Amaranthaceae s.l. (including Chenopodiaceae), which includes the largest number of C 4 lineages in eudicots. The oldest chenopod C 4 lineage da…

AcclimatizationLineage (evolution)Drought toleranceChenopodiaceaePoaceaeGeneral Biochemistry Genetics and Molecular BiologyCarbon CycleSpecies SpecificityBotanyPoaceaePhotosynthesisMolecular clockChenopodiaceaeEudicotsResearch ArticlesPhylogenyGeneral Environmental ScienceAmaranthaceaeGeneral Immunology and MicrobiologybiologyEcologyfood and beveragesGeneral MedicineCarbon Dioxidebiology.organism_classificationBiological EvolutionCarbonDroughtsSaltsAdaptationParallel evolutionGeneral Agricultural and Biological SciencesProceedings of the Royal Society B: Biological Sciences
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Dependence of plasma pH on oxygen saturation

1969

Abstract The influence of haemoglobin oxygenation on the pH value of the blood plasma of healthy adolescents was investigated at 38°C by varying the parameters CO2 pressure, Hb concentration and buffer bases. A total of 5000 measurements gave the following results: 1. 1. The pHs difference between oxygenated and deoxygenated blood increases with diminishing CO2 pressure and with increasing Hb concentration. There is a linear relation between the pHs changes and the O2 saturation of the haemoglobin. 2. 2. Quantitatively these relationships can be expressed by the following equation: δpHs = (8 − pH ox − log 0.03 Pco 2 ) · [Hb] 225 · (100 − So 2 100 where ΔpHs is the pHs difference between par…

Acid-Base EquilibriumPulmonary and Respiratory MedicineAdolescentPhysiologyChemistryPartial PressureAnalytical chemistryOxygenationVenous bloodPlasmaBuffersCarbon DioxideHydrogen-Ion ConcentrationOxygenBicarbonatesHemoglobinsBloodBiochemistryBlood plasmaLinear relationHumansBase excessOxygen saturationBlood phRespiration Physiology
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Design of nonionic surfactants for supercritical carbon dioxide

1996

Interfacially active block copolymer amphiphiles have been synthesized and their self-assembly into micelles in supercritical carbon dioxide (CO 2 ) has been demonstrated with small-angle neutron scattering (SANS). These materials establish the design criteria for molecularly engineered surfactants that can stabilize and disperse otherwise insoluble matter into a CO 2 continuous phase. Polystyrene- b -poly(1,1-dihydroperfluorooctyl acrylate) copolymers self-assembled into polydisperse core-shell-type micelles as a result of the disparate solubility characteristics of the different block segments in CO 2 . These nonionic surfactants for CO 2 were shown by SANS to be capable of emulsifying u…

AcrylateMultidisciplinarySupercritical carbon dioxideSANSMicelleSupercritical fluidSolventchemistry.chemical_compoundchemistrysupercritical-CO2AmphiphilemicelleCopolymerOrganic chemistrySolubility
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A New Evaluation of Emergency Methods for Artificial Ventilation

1968

SUMMARY The effect of artificial ventilation by the exhaled-air methods (mouth-to-nose and mouth-to-mouth) and chest-pressure-arm-lift methods (Ho-ward-Thomsen, Silvester-Brosch, Holger Nielsen) was investigated in 11 anaesthetised apnoeic volunteers. The efficiency of these methods was assessed by the changes in arterial PO2, O2 saturation, PCO2 and pH. It could be shown that the exhaled-air methods ensured normal PO2 and O2 saturation in all cases, while the ventilation by the manual methods was insufficient. Even though normal oxygenation was achieved by the manual methods in some cases, others were extremely hypoventilated, with critically low O2 tensions. pH and CO2 tensions did not ch…

AdultArtificial ventilationmedicine.medical_treatmentpCO2law.inventionElectrocardiographylawMethodsVentilation-Perfusion RatioHumansMedicinebusiness.industryHypoventilationGeneral MedicineOxygenationCarbon DioxideHydrogen-Ion ConcentrationHypoventilatedRespiration ArtificialRespiratory Function TestsOxygenBloodAnesthesiology and Pain MedicineAnesthesiaVentilation (architecture)Arterial pO2EmergenciesbusinessMathematicsNormal po2Acta Anaesthesiologica Scandinavica
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