Search results for "carbon"
showing 10 items of 6057 documents
Highly cross-linked imidazolium salt entrapped magnetic particles – preparation and applications
2012
Magnetic particles entrapped into highly cross-linked imidazolium salts were synthesized using a straightforward approach by radical polymerization of bis-vinylimidazolium salts in the presence of superparamagnetic iron oxide particles. Potential applications for these new materials as (i) catalysts for conversion of propylene oxide to propylene carbonate, (ii) supports for organocatalysts, and (iii) scavenger materials for palladium removal are outlined.
Pressure-induced formation of diblock copolymer "micelles" in supercritical fluids. A combined study by small angle scattering experiments and mean-f…
2004
We developed a simple time-dependent mean-field theory to describe the phase separation kinetics of either homopolymers or AB-diblock copolymers in supercritical (SC) fluids. The model, previously used to describe the phase behavior of AB-block copolymers under the assumption of strong solvent selectivity for just one copolymer chain, has been extended to study the kinetics of the phase separation process. Time resolved small angle x-ray scattering (TR-SAXS) measurements have been performed on different AB-diblock copolymers containing a perfluorinated chain and dissolved in SC-CO2. The data obtained over a wide range of pressure and temperature confirm our theoretical predictions. Particul…
Nanowear on Polymer Films of Different Architecture
2007
In this paper, we describe atomic force microscope (AFM) friction experiments on different polymers. The aim was to analyze the influence of the physical architecture of the polymer on the degree and mode of wear and on the wear mode. Experiments were carried out with (1) linear polystyrene (PS) and cycloolefinic copolymers of ethylene and norbornene, which are stabilized by entanglements, (2) mechanically stretched PS, (3) polyisoprene-b-polystyrene diblock copolymers, with varying composition, (4) brush polymers consisting of a poly(methyl methacrylate) (PMMA) backbone and PS side chains, (5) PMMA and PS brushes grafted from a silicon wafer, (6) plasma-polymerized PS, and (7) chemically c…
The morphology of block copolymer micelles in supercritical carbon dioxide by small-angle neutron and x-ray scattering
1997
Above its critical point, carbon dioxide forms a super-critical fluid, which promises to be an environmentally responsible replacement for the organic solvents traditionally used in polymerizations. Many lipophilic polymers such as polystyrene (PS) are insoluble in CO2, though polymerizations may be accomplished via the use of PS-fluoropolymer stabilizers, which act as emulsifying agents. Small-angle neutron and X-ray scattering have been used to show that these molecules form micelles with a CO2-phobic PS core and a CO2-philic fluoropolymer corona. When the PS block was fixed in length and the fluorinated corona block was varied, the number of block copolymer molecules per micelle (six to …
Supercritical-fluid extraction of chlorofluoroalkanes from rigid polyurethane foams
1996
Abstract Preliminary results about a process for recovering expanding agents chlorofluoroalkanes (CFCs) both trapped in the cavities and dissolved in the polymer from rigid polyurethane foams are reported. The performances of liquid and supercritical carbon dioxide, and of CO2-propane supercritical mixtures were compared. Better results in terms of extraction time and amount of extracted CFCs were obtained with finely ground materials and supercritical propane-carbon dioxide fluids.
Industrial applications of the aggregation of block copolymers in supercritical CO 2 : a SANS study
2002
Industrial applications of supercritical carbon dioxide (scCO2) rely upon the rather selective and easily adjustable solvent ability of CO2. CO2 near the critical point is a poor solvent for high molecular weight (HMW) hydrocarbon polymers, while it is a very good solvent for amorphous fluorinated polymers. By increasing the pressure, CO2 becomes a good solvent even for HMW hydrogenated chains. Specially engineered amphiphilic di-block copolymers, with CO2-philic and CO2-phobic portions, are expected to undergo trough a monomer–aggregate transition when the solvent density of the scCO2 changes. Here small-angle neutron scattering (SANS) results are reported for a block copolymer dissolved i…
Diffusional enhancement of holograms: phenanthrenequinone in polycarbonate
2002
As a further development of the manufacture of holographic gratings by the diffusion of phenanthrenequinone in polymer glass, the traditionally employed poly(methyl methacrylate) is replaced by poly(bisphenol-A-carbonate). The post-exposure growth and decay of the gratings in the two materials are compared at different spatial periods and temperatures. The medium with polycarbonate demonstrates a fortunate combination of significantly improved stability of the gratings and their faster development. Our results indicate that the polycarbonate materials promise to be suitable media for holographic optical elements and data storage.
Carbon nitride as photocatalyst in organic selective transformations
2020
Abstract Graphitic carbon nitride (g-C3N4) is a metal-free conjugated polymer which has become a new research hotspot in photocatalysis. It can be used for solar energy exploitation like in solar energy organic synthesis, one of the most new and appealing green applications of heterogeneous photocatalysis. This chapter resumes the state-of-the-art and progresses in the application of heterogeneous visible light photocatalysis in organic selective transformations by using C3N4 as photocatalyst.
Economical device for measuring thickness of a thin polymer film
1994
An inexpensive device (about $2K) for thickness measurements of thin (<1 μm) polymer films has been constructed. The homogeneous film is placed on a bulk substrate and three semiconductor lasers of different wavelengths are used to measure the reflectances at normal incidence. The thickness can be deduced with typically 4–8 nm uncertainty.
Rapeseed oil-based rigid polyisocyanurate foams modified with nanoparticles of various type
2014
Polyisocyanurate foams have been developed using a polyol system partially derived from rapeseed oil (RO). The effect of nanofillers with iso-dimensional geometry (zinc oxide), nanofibers (carbon nanotubes), and nanoplatelets (organically modified montmorillonite) on stiffness and strength of the foams has been studied. It was demonstrated that the tensile properties of the filled foams are enhanced by roughly the same proportion as the stiffness and strength of monolithic filled polymers.