Search results for "cathode"
showing 10 items of 296 documents
Surface termination effects on the oxygen reduction reaction rate at fuel cell cathodes
2018
This research was partly funded by the Latvian project IMIS2 with the computer resources provided by the High Performance Computing Centre Stuttgart (HLRS) (Project DEFTD 12939). The authors thank D. Gryaznov for fruitful discussions and M. Sokolov for technical assistance. MMK is grateful to the Office of the Director of National Science Foundation for support under the Independent Research and Development program. The ndings, conclusions, and recommendations expressed in this material are those of the authors and do not necessarily reect the views of NSF and other funding agencies.
First Principles Modeling of Pd-doped (La,Sr)(Co,Fe)O3Complex Perovskites
2016
(La,Sr)(Co,Fe)O3 (LSCF) perovskites are well known promising materials for cathodes of solid oxide fuel cells. In order to reduce cathode operational temperature, doping on B-sublattice with different metals was suggested. Indeed, as it was shown recently experimentally, doping with low Pd content increases oxygen vacancy concentration which is one of factors controlling oxygen transport in fuel cells. In this Communication, we modeled this material using first principles DFT calculations combined with supercell model. The charge density redistribution, density of states, and local lattice distortion around palladium ions are analyzed and reduction of the vacancy formation energy confirmed.
Heat and mass transfer analysis in single cell of PEFC using different PEM and GDL at higher temperature
2019
Abstract According to the H2 and fuel cell road map in Japan, the target operating temperature of polymer electrolyte fuel cell (PEFC) should be 90 °C from 2020 to 2025. In this study, the impact of polymer electrolyte membrane (PEM) and gas diffusion layer (GDL)'s thickness on heat and mass transfer characteristics as well as power generation performance of PEFC is investigated at operating temperature of 90 °C. The in-plane temperature distributions on anode and cathode separator are also measured using thermograph. As a result, it is observed that the increase in power from 1 W to 5 W at the current density of 0.80 A/cm2 as well as even temperature distribution within 1 °C can be obtaine…
Graphene in lithium ion battery cathode materials: A review
2013
Abstract Graphene is a relatively new and promising material, displaying a unique array of physical and chemical properties. Although considered to be especially promising for the use in energy storage applications, graphene has only recently been implemented as an electron conducting additive for lithium ion battery cathode materials. In current studies graphene is found to significantly improve cathode electrochemical performance. As the charge capacity, rate capability and cyclability of lithium ion batteries are still in ever-remaining need of improvement, this article examines the prospects of graphene implementation into lithium ion battery cathodes to meet such demands. The existing …
Development of a 3D CZT Spectrometer System with Digital Readout for Hard X/Gamma-Ray Astronomy
2019
We report on the development and of a complete X/γ rays detection system (10-1000 keV) based on CZT spectrometers with spatial resolution in three dimensions (3D) and a digital electronics acquisition chain. The prototype is made by packing four linear modules, each composed of one 3D CZT sensors. Each sensors is realized using a single spectroscopic graded CZT crystal of about 20×20×5 mm3. An electrode structure consisting of 12 collecting anodes with a pitch of 1.6 mm and 3 drift strips between each pair of anodes for 48 strips (0.15 mm wide) on the anodic side was adopted. The cathode is made of 10 strips with a pitch of 2 mm and orthogonal to anode side strips. Since the reading of the …
Shape restoration effect in Ag-SiO2 core-shell nanowires.
2014
The combination of two different materials in a single composite core–shell heterostructure can lead to improved or even completely novel properties. In this work we demonstrate the enhancement of the mechanical properties of silver (Ag) nanowires (NW) achieved by coating them with a silica (SiO2) shell. In situ scanning electron microscope (SEM) nanomechanical tests of Ag–SiO2 core–shell nanowires reveal an improved fracture resistance and an electron-beam induced shape restoration effect. In addition, control experiments are conducted separately on uncoated Ag NWs and on empty SiO2 shells in order to gain deeper insight into the peculiar properties of Ag–SiO2. Test conditions are simulate…
The Structural Disorder and Lattice Stability of (Ba,Sr)(Co,Fe)O3 Complex Perovskites
2011
The structural disorder and lattice stability of complex perovskite (Ba,Sr)(Co,Fe)O3, a promising cathode material for solid oxide fuel cells and oxygen permeation membranes, is explored by means of first principles DFT calculations. It is predicted that Ba and Sr ions easily exchange their lattice positions (A-cation disorder) similarly to Co and Fe ions (B-cation disorder). The cation antisite defects (exchange of A- and B-type cations) also have the low formation energy. The BSCF is predicted to exist in an equilibrium mixture of several phases and can decompose exothermically into the Ba- and Co-rich hexagonal (Ba,Sr)CoO3 and Sr- and Fe-rich cubic (Ba,Sr)FeO3 perovskites.
Preparation of Heusler thin films: The quaternary alloy CO2Fe0.5Mn0.5Si
2008
In this work the basic strategies for the preparation of CO2Mn0.5Fe0.5Si as an example for Heusler alloy thin films will be described. Texture and magnetic properties of these films will be discussed, especially with regard to different buffer layers and annealing temperatures. Finally, we will show the integration of Heusler thin films into magnetic tunnel junctions (MTJs) and calculate the effective spin polarization. (c) 2008 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
Performance analysis of single cell solid oxide fuel cells
2017
Solid oxide fuel cells (SOFCs) are a class of fuel cells operating on high temperatures which have the potential to become one of the efficient and cost effective system for direct conversion of a wide variety of fuels to electricity. For proper operation of SOFCs, evaluation of cell stability and optimization of fuel utilization is of paramount importance. In this paper, we have performed experiments to obtain current-voltage (I–V) characteristics by using three different Hydrogen (H 2 ) flow rates(100 ml/min, 150 ml/min and 200 ml/min). Furthermore, we perform oxidation and reduction (redox) cycles to determine how many redox cycles a SOFC can withstand without cracking the cell which we …
New Results on High-Resolution 3-D CZT Drift Strip Detectors
2020
Intense research activities have been carry out in the development of room temperature gamma ray spectroscopic imagers, aiming to compete with the excellent energy resolution of high-purity germanium (HPGe) detectors (0.3 % FWHM at 662 keV) obtained after cryogenic cooling. Cadmium-zinc-telluride (CZT) detectors equipped with pixel, strip and virtual Frisch-grid electrode structures represented an appealing solution for room temperature measurements. In this work, we present the performance of new high-resolution CZT drift strip detectors (19.4 x 19.4 x 6 mm3), recently fabricated at IMEM-CNR of Parma (Italy) in collaboration with due2lab company (Reggio Emilia, Italy). The detectors, worki…