Search results for "cellulose"

showing 10 items of 318 documents

Characterization of a new natural fiber from Arundo donax L. as potential reinforcement of polymer composites.

2013

Abstract The aim of this paper is to study the possibility of using of Arundo donax L. fibers as reinforcement in polymer composites. The fibers are extracted from the outer part of the stem of the plant, which widely grows in Mediterranean area and is diffused all around the world. To use these lignocellulosic fibers as reinforcement in polymer composites, it is necessary to investigate their microstructure, chemical composition and mechanical properties. Therefore, the morphology of A. donax L. fibers was investigated through electron microscopy, the thermal behavior through thermogravimetric analysis and the real density through a helium pycnometer. The chemical composition of the natura…

Dietary FiberThermogravimetric analysisMaterials sciencePolymers and PlasticsPolymersPoaceaeLigninchemistry.chemical_compoundPolysaccharidesTensile StrengthUltimate tensile strengthMaterials TestingSpectroscopy Fourier Transform InfraredMaterials ChemistryHemicelluloseCelluloseComposite materialCelluloseNatural fiberbiologyOrganic ChemistryTemperatureArundo donaxMicrostructurebiology.organism_classificationCharacterization (materials science)Arundo donax fiber Mechanical property Infrared spectroscopy Thermogravimetric analysis Scanning electron microscopy Statistical analysisSettore ING-IND/22 - Scienza E Tecnologia Dei MaterialichemistryMicroscopy Electron ScanningCarbohydrate polymers
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Control of mesogen configuration in colloids of liquid crystalline polymers

2010

We report on a method to chemically predetermine the surface anchoring of mesogens in liquid crystalline colloids formed by different types of dispersion polymerization, and hence to achieve control over the mesogen configuration in such colloids. The surface anchoring is controlled by the chemical linkage of the polymers forming the colloids to the surfactants stabilizing the colloids towards the dispergent. We find that the hydroxypropyl cellulose used in conventional dispersion poylmerization induces parallel mesogen surface anchoring that in turn leads to bipolar director-field configurations, while a methacrylate terminated polysiloxane stabilizer, which is used in nonpolar dispersion …

Dispersion polymerizationchemistry.chemical_classificationMaterials scienceHydroxypropyl celluloseMesogenGeneral ChemistryPolymerCondensed Matter PhysicsMethacrylatechemistry.chemical_compoundColloidchemistryChemical engineeringPolymer chemistryCopolymerDispersion (chemistry)Soft Matter
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Evaluation of the original dose in irradiated dried fruit by EPR spectroscopy

2011

Abstract The electron paramagnetic resonance spectroscopy (EPR) is one of the physical methods, recommended by the European Committee for Standardization, for the identification of irradiated food containing cellulose, such as dried fruit. In this work the applicability of EPR as identification method of irradiated pistachios, hazelnuts, peanuts, chestnuts, pumpkin seeds is evaluated; the time stability of the radiation induced signal is studied and the single aliquot additive dose method is used to evaluate the dose in the product.

Electron paramagnetic resonance spectroscopyRadiationPumpkin seedDried fruitRadiochemistryAnalytical chemistryfood and beveragesRadiation inducedcelluloseSettore FIS/07 - Fisica Applicata(Beni Culturali Ambientali Biol.e Medicin)food.foodlaw.inventionchemistry.chemical_compoundfoodchemistrylawEPR irradiated food; celluloseEPR irradiated foodFood irradiationIrradiationCelluloseElectron paramagnetic resonanceInstrumentationRadiation Measurements
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Nachweis von fetalem H�moglobin in Blutspuren mit Hilfe der Celluloseacetatfolien- (CAF) -Elektrophorese

1977

Blutspuren von 160 Nabelvenenblutproben wurden elektrophoretisch nach der von Wraxall beschriebenen Technik aufgetrennt und konnten gut drei Monate lang nach Lagerung bei Zimmertemperatur von Erwachsenenblutspuren unterschieden werden. Unterschiedliche Spurentrager (Glas, Holz, Filterpapier und Leinen) hatten keinen nennenswerten Einflus auf die Darstellung.

Electrophoresischemistry.chemical_compoundChromatographyChemistryAnatomyCellulose acetatePathology and Forensic MedicineZeitschrift f�r Rechtsmedizin
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A systematic literature review on less common natural fibres and their biocomposites

2018

Abstract Interest in utilization of renewable resources is increasing because of public's environmental awareness and economic considerations. Lignocellulosic fibres have already attracted growing attention as reinforcement of polymeric matrices instead of synthetic ones (mainly glass) from the academic and industrial fields. In addition to kenaf, hemp, sisal, flax and jute, which are the subject of extensive investigations for composite applications since the 1970s, in the last years several researchers suggested the use of less common natural fibres, due to their low cost and availability. This paper reviews the extraction methods, chemical, morphological, thermal and mechanical propertie…

Engineeringbiobased compositesStrategy and ManagementMechanical and thermal propertie02 engineering and technology010402 general chemistry01 natural sciencesIndustrial and Manufacturing EngineeringNatural (archaeology)Nanocelluloseagricultural residueschemical compositionmechanical and thermal propertiesnanocellulose extractionSISALGeneral Environmental Sciencecomputer.programming_languageLess common natural fibrebiologyRenewable Energy Sustainability and the Environmentbusiness.industryPolymeric matrixBiobased composite021001 nanoscience & nanotechnologybiology.organism_classificationEnvironmentally friendlyKenaf0104 chemical sciencesSettore ING-IND/22 - Scienza E Tecnologia Dei Materialiagricultural residues; biobased composites; chemical composition; less common natural fibres; mechanical and thermal properties; nanocellulose extractionExtraction methodsAgricultural residueBiochemical engineeringless common natural fibres0210 nano-technologybusinesscomputerRenewable resource
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Unveiling the distinctive role of titanium dioxide nanoparticles in aerobic sludge digestion.

2022

Abstract Aerobic digestion is considered to be a common process for the stabilization of waste activated sludge (WAS) in the small-sized wastewater treatment systems, while the broad application of titanium dioxide nanoparticles (TiO2 NPs) results in their unavoidable existence in WAS aerobic digestion, with its role in aerobic sludge digestion being never documented. This study set up a series of aerobic sludge digesters to evaluate the previously unknown role of TiO2 NPs on the performance of the digesters. The volatile solids (VS) degradation percentage increased from 21.9 ± 0.6% to 26.9 ± 0.1% − 30.0 ± 0.3% with the different contents of TiO2 NPs (0, 1, 20 and 50 mg/L). Similarly, the t…

Environmental Engineering0207 environmental engineering02 engineering and technology010501 environmental sciences01 natural sciencesWaste Disposal Fluidchemistry.chemical_compoundDigestion (alchemy)Environmental ChemistryHumic acidAerobic digestionAnaerobiosisCellulose020701 environmental engineeringWaste Management and Disposal0105 earth and related environmental scienceschemistry.chemical_classificationTitaniumSettore ICAR/03 - Ingegneria Sanitaria-AmbientaleSewageAerobic digestion Recalcitrant organics Sludge degradation Solubilization Titanium dioxide nanoparticles Anaerobiosis Digestion Titanium Waste Disposal Fluid Nanoparticles Sewagetechnology industry and agricultureBiodegradationPollution6. Clean waterAnaerobic digestionActivated sludgechemistryEnvironmental chemistryNanoparticlesSewage treatmentDigestionEnvironmental SciencesThe Science of the total environment
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Effective saccharification of lignocellulosic barley straw by mechanocatalytical pretreatment using potassium pyrosulfate as a catalyst

2017

The catalytic conversion of lignocellulosic biomass is attractive due to the feasible generation of valuable products such as reducing sugars which constitute the basic substrates for chemical and transportation fuel production, as well as the production of renewable hydrogen. This study shows the efficient conversion of lignocellulose, especially hemicellulose, into reducing sugars such as xylose and galactose, by mechanocatalysis using potassium pyrosulfate, K2S2O7, as an effective salt catalyst. Ball milling was performed, introducing a mechanical force which, combined with chemical pretreatment, leads to reducing sugar yields (40%) almost as high as when commonly used sulfuric acid was …

Environmental EngineeringCarbohydratesLignocellulosic biomassBioengineeringXylose010402 general chemistry01 natural sciencesPotassium pyrosulfateCatalysischemistry.chemical_compoundHydrolysisHemicelluloseBiomassWaste Management and Disposalchemistry.chemical_classificationXyloseWaste management010405 organic chemistryRenewable Energy Sustainability and the EnvironmentHydrolysisHordeumSulfuric acidGeneral MedicinePulp and paper industry0104 chemical sciencesReducing sugarchemistryPotassiumBioresource Technology
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Concentrations of monosaccharides in humic substances in the early stages of humification.

2001

Deteriorated liquid packaging board (LPB) and biowaste compost are matrices, mainly consisting of cellulose, in the early stages of humification. Degradative studies on these matrices allow an examination of the role of carbohydrates in the synthesis of humic substances. Samples of different age were collected and divided by extraction into hot water extract (HWE), bitumen, humic acid (HA), fulvic acid (FA) and humin or residual fibre fractions. The following monosaccharides were identified in these fractions: L-arabinose, D-ribose, D-xylose, L-fucose, D-mannose, D-fructose, D-galactose, D-glucose, L-rhamnose and xylitol. The main component in all fractions was glucose. The concentrations o…

Environmental EngineeringHealth Toxicology and Mutagenesisengineering.materialcomplex mixturesLiquid packaging boardProduct PackagingEnvironmental ChemistryHumic acidMonosaccharideOrganic matterFood scienceCelluloseHumic Substanceschemistry.chemical_classificationChromatographyChemistryCompostMonosaccharidesPublic Health Environmental and Occupational HealthTemperatureWaterGeneral MedicineGeneral ChemistryBiodegradationPollutionHumusRefuse DisposalengineeringHuminChemosphere
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2018

Reactivity is an important parameter when considering the chemical modification or dissolution of cellulose. Different pretreatment methods affect cellulose reactivity by decreasing its degree of polymerization (DP) and crystallinity. In this study, the molar mass of cellulose was decreased via enzymatic pretreatment. Three commercial endoglucanase-rich products were tested. The target was to reduce the viscosity of the pulp to below 200 mL/g and, thus, increase the reactivity of the cellulose. For comparison, cellulose was also pretreated with ozone, and the effects of each pretreatment method on crystallinity and monosaccharide composition of the resulting pulps were investigated. Both en…

Environmental EngineeringMolar massPulp (paper)Chemical modificationBioengineeringengineering.materialchemistry.chemical_compoundHydrolysisCrystallinitychemistryengineeringReactivity (chemistry)CelluloseDerivatizationWaste Management and DisposalNuclear chemistryBioResources
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Trimeprazine is enantioselectively degraded by an activated sludge in ready biodegradability test conditions

2018

[EN] A great number of available pharmaceuticals are chiral compounds. Although they are usually manufactured as racemic mixtures, they can be enantioselectively biodegraded as a result of microbial processes. In this paper, a biodegradability assay in similar conditions to those recommended in OECD tests of enantiomers of trimeprazine (a phenothiazine employed as a racemate) is carried out. Experiments were performed in batch mode using a minimal salts medium inoculated with an activated sludge (collected from a Valencian Waste Water Treatment Plant, WWTP) and supplemented with the racemate. The concentration of the enantiomers of trimeprazine were monitored by means of a chiral HPLC metho…

Environmental EngineeringTrimeprazineEnantioselectivity010501 environmental sciences01 natural scienceschemistry.chemical_compoundMonod equationCurve fittingCelluloseWaste Management and DisposalChromatography High Pressure Liquid0105 earth and related environmental sciencesWater Science and TechnologyCivil and Structural EngineeringChromatographySewageEcological ModelingBatch experiment010401 analytical chemistryBiodegradability testEnantioselective synthesisStereoisomerismAntipruriticsTrimeprazinePrecisionBiodegradationPollution0104 chemical sciencesChiral column chromatographyBiodegradation EnvironmentalActivated sludgechemistryEnantiomerWater Pollutants ChemicalWater Research
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