Search results for "characterization"

Direct experimental observation of mesoscopic fluorous domains in fluorinated room temperature ionic liquids

2017

Fluorinated room temperature ionic liquids (FRTILs) represent a class of solvent media that are attracting great attention due to their IL-specific properties as well as features stemming from their fluorous nature. Medium-to-long fluorous tails constitute a well-defined apolar moiety in the otherwise polar environment. Similarly to the case of alkyl tails, such chains are expected to result in the formation of self-assembled fluorous domains. So far, however, no direct experimental observation has been made of the existence of such structural heterogeneities on the nm scale. We report here the first experimental evidence of the existence of mesoscopic spatial segregation of fluorinated dom…

On the fractional probabilistic Taylor's and mean value theorems

2016

In order to develop certain fractional probabilistic analogues of Taylor's theorem and mean value theorem, we introduce the nth-order fractional equilibrium distribution in terms of the Weyl fractional integral and investigate its main properties. Specifically, we show a characterization result by which the nth-order fractional equilibrium distribution is identical to the starting distribution if and only if it is exponential. The nth-order fractional equilibrium density is then used to prove a fractional probabilistic Taylor's theorem based on derivatives of Riemann-Liouville type. A fractional analogue of the probabilistic mean value theorem is thus developed for pairs of nonnegative rand…

The Girgentana Goat Breed: A Zootechnical Overview on Genetics, Nutrition and Dairy Production Aspects

2017

In recent years, there has been a great interest in recovering and preserving local livestock breeds. An interesting situation is represented by the Girgentana goat, an ancient local breed reared in Sicily. Over recent years, this breed has become almost extinct, in part as a consequence of the marked decrease in fresh goat milk consumption. On the basis of these considerations, several studies on its genetic structure and management aspects have been conducted in order to protect the Girgentana goat from the risk of extinction and recover its genetic and economic value. In this context, information on genetics, nutrition and dairy production aspects may have a crucial role in the improveme…

Characterization and differentiation of rock varnish types from different environments by microanalytical techniques

2017

© 2017 Elsevier B.V. We investigated rock varnishes collected from several locations and environments worldwide by a broad range of microanalytical techniques. These techniques were selected to address the challenges posed by the chemical and structural complexity within the micrometer- to nanometer-sized structures in these geological materials. Femtosecond laser ablation-inductively coupled plasma-mass spectrometry (fs LA-ICP-MS), scanning transmission X-ray microscopy-near edge X-ray adsorption fine structure spectroscopy (STXM-NEXAFS) in combination with scanning electron microscopy (SEM) of focused ion beam (FIB) ultra-thin (100–200 nm) sections, conventional and polarization microscop…

The effect of body shape and gender on wireless Body Area Network on-body channels

2010

Technological advancements have made possible the emergence of Body Area Networks (BANs). There are numerous on-body channel characterizations in the literature performed on a phantom or a single human subject. In this paper, using multiple subjects, we consider the effect of body shape and gender on the on-body channel. A characterization of a narrowband on-body to on-body channel among different subjects is presented. The paper investigates the relationship between the propagation and the subject's physical characteristics. The investigation is performed at 2360 MHz; the new medical band undergoing FCC approval. Our results show that the path loss in women is less than that in men and the…

Strong Bonding of Single C60 Molecules to (1 × 2)-Pt(110): an STM/DFT Investigation.

2007

International audience; The interaction of single C60 molecules with the (1 × 2)-Pt(110) surface has been studied by scanning tunneling microscopy and density functional theory (DFT) calculations on slab models. Molecules are observed to be frozen at room temperature and are found to be almost exclusively in the same configuration. Extensive DFT calculations show that this configuration is the global energy minimum, suggesting that adsorbed molecules have enough rototranslational freedom to escape from the numerous local minima. The adsorption energy (3.81 eV) is the strongest ever found for C60, and it is roughly proportional to the number of the Pt and C atoms at contact distance. Analysi…

Bond characterization of monolithic and layered glass panels and ultrasonic tests to control glued surfaces

2019

Abstract An experimental investigation is presented regarding the compressive and shear strength of monolithic and PVB laminated glass elements connected by acrylic glue. Ultrasonic tests were also used to control the efficiency of glued surfaces of glass panels. Twenty-four triplets composed of three float glass elements glued with acrylic adhesive were prepared to perform bond tests. Of these twelve triplets were made with monolithic glass elements with a nominal thickness of 20 mm, while twelve were made with layered glass elements 20 mm thick. Three single elements of monolithic glass and three of layered glass were tested for compressive strength. Ultrasonic tests were performed on a s…

The Odd Sibling: Features ofβ3-Adrenoceptor Pharmacology

2014

beta(3)-Adrenoceptor agonists have recently been introduced for the treatment of overactive urinary bladder syndrome. Their target, the beta(3)-adrenoceptor, was discovered much later than beta(1)- and beta(2)-adrenoceptors and exhibits unique properties which make extrapolation of findings from the other two subtypes difficult and the beta(3)-adrenoceptor a less-understood subtype. This article discusses three aspects of beta(3)-adrenoceptor pharmacology. First, the ligand-recognition profile of beta(3)-adrenoceptors differs considerably from that of the other two subtypes, i.e., many antagonists considered as nonselective actually are beta(3)-sparing, including propranolol or nadolol. Man…

Genomics and Proteomics Analyses Revealed Novel Candidate Pesticidal Proteins in a Lepidopteran-Toxic Bacillus thuringiensis Strain

2020

Discovery and identification of novel insecticidal proteins in Bacillus thuringiensis (Bt) strains are of crucial importance for efficient biological control of pests and better management of insect resistance. In this study, the Bt strain KhF, toxic for Plodia interpunctella and Grapholita molesta larvae, underwent genomics and proteomics analyses to achieve a better understanding of the bases of its pathogenicity. The whole-genome sequencing results revealed that the KhF strain contained nine coding sequences with homologies to Bt insecticidal genes. The lepidopteran toxic mixture of spores and crystals of this Bt strain was subjected to liquid chromatography and tandem mass spectrometry …

Il miglioramento energetico nel recupero degli edifici storici. Applicazione al patrimonio architettonico palermitano

L'architettura storica può assumere un ruolo rilevante nel raggiungimento degli obiettivi europei di efficienza energetica per il settore edile, obiettivi che, tuttavia, devono essere compatibili con la conservazione del patrimonio storico e del suo valore culturale. A tal fine è necessario far riferimento ai caratteri specifici dell'architettura storica e alla sua dimensione locale. La presente tesi, sulla base di tale assunto, esamina le prestazioni energetiche degli edifici storici e il loro potenziale miglioramento, concentrandosi sul patrimonio architettonico di Palermo, caso di studio significativo per l'area mediterranea. La ricerca, condotta con riferimento sia alla scala urbana sia…