Search results for "chiral"
showing 10 items of 752 documents
Deeply bound levels in kaonic atoms
2000
Using a microscopic antikaon-nucleus optical potential recently developed by Ramos and Oset (nucl-th/9906016, in print in Nuclear Physics A) from a chiral model, we calculate strong interaction shifts and widths for $K^-$ atoms. This purely theoretical potential gives an acceptable description of the measured data ($\chi^2/{\rm num.data}= 3.8$), though it turns out to be less attractive than what can be inferred from the existing kaon atomic data. We also use a modified potential, obtained by adding to the latter theoretical one a s-wave term which is fitted to known experimental kaonic data ($\chi^2/{\rm degree of freedom}= 1.6$), to predict deeply bound $K^-$ atomic levels, not detected y…
Novel deoxycholic acid alkylamide-phenylurea-derived organogelators
2010
Abstract Three monomeric and three dimeric deoxycholic acid (DCA) alkylamido-phenylurea derivatives are designed based on known gelators and are synthesized and characterized by 1 H and 13 C NMR spectroscopy, ESI-TOF mass spectrometry, and elemental analyses. Among them, a monomeric derivative forms supramolecular gels in CHCl 3 and chlorobenzene, whereas a dimeric derivative gels THF and higher 1-alkanols containing 7–10 carbons. The morphologies of their xerogels are studied by scanning electron microscopy (SEM). No signature of macroscopic chirality of the gels is visible.
Stereoselective cathodic synthesis of 8-substituted (1R,3R,4S)-menthylamines.
2015
The electrochemical generation of menthylamines from the corresponding menthone oximes equipped with an additional substituent in position 8 is described. Due to 1,3-diaxial interactions a pronounced diastereoselectivity for the menthylamines is found.
Sensitivity of EDM experiments in paramagnetic atoms and molecules to hadronic CP violation
2020
Experiments searching for the electric dipole moment (EDM) of the electron $d_e$ utilise atomic/molecular states with one or more uncompensated electron spins, and these paramagnetic systems have recently achieved remarkable sensitivity to $d_e$. If the source of $CP$ violation resides entirely in the hadronic sector, the two-photon exchange processes between electrons and the nucleus induce $CP$-odd semileptonic interactions, parametrised by the Wilson coefficient $C_{SP}$, and provide the dominant source of EDMs in paramagnetic systems instead of $d_e$. We evaluate the $C_{SP}$ coefficients induced by the leading hadronic sources of $CP$ violation, namely nucleon EDMs and $CP$-odd pion-nu…
Measurement of the Charged-Pion Polarizability
2015
The COMPASS collaboration at CERN has investigated pion Compton scattering, $\pi^-\gamma\rightarrow \pi^-\gamma$, at centre-of-mass energy below 3.5 pion masses. The process is embedded in the reaction $\pi^-\mathrm{Ni}\rightarrow\pi^-\gamma\;\mathrm{Ni}$, which is initiated by 190\,GeV pions impinging on a nickel target. The exchange of quasi-real photons is selected by isolating the sharp Coulomb peak observed at smallest momentum transfers, $Q^2<0.0015$\,(GeV/$c$)$^2$. From a sample of 63\,000 events the pion electric polarisability is determined to be $\alpha_\pi\ =\ (\,2.0\ \pm\ 0.6_{\mbox{\scriptsize stat}}\ \pm\ 0.7_{\mbox{\scriptsize syst}}\,) \times 10^{-4}\,\mbox{fm}^3$ under the …
How to discover QCD Instantons at the LHC
2020
Topological Effects in the Standard Model: Instantons, Sphalerons and Beyond at LHC, Geneva, Switzerland, 16 Dec 2020 - 18 Dec 2020; The European physical journal / C 81(7), 624 (2021). doi:10.1140/epjc/s10052-021-09412-1
Strange meson production at high density and temperature
2010
The properties of strange mesons ($K$, $\bar K$ and $\bar K^*$) in dense matter are studied using a unitary approach in coupled channels for meson-baryon scattering. The kaon-nucleon interaction incorporates $s$- and $p$-wave contributions within a chiral model whereas the interaction of $\bar K^*$ with nucleons is obtained in the framework of the local hidden gauge formalism. The in-medium solution for the scattering amplitude accounts for Pauli blocking effects, mean-field binding on baryons, and meson self-energies. We obtain the $K$, $\bar K$ and $\bar K^*$ (off-shell) spectral functions in the nuclear medium and study their behaviour at finite density, temperature and momentum. We also…
Chiral diphosphine derivatives of alkylidyne tricobalt carbonyl clusters – A comparative study of different cobalt carbonyl (pre)catalysts for (asymm…
2016
Reaction of the tricobalt carbyne cluster [Co-3(mu(3)-CH)(CO)(9)] with chiral diphosphines of the Josiphos and Walphos families affords the new clusters [Co-3(mu(3)-CH)(CO)(7)(P-P*)] in good yield (P-P* = J004 (1), J005 (2), J007 (3), W001 (4), W003 (5)). The new alkylidyne tricobalt clusters, and the previously known [Co-3(mu(3)-CH)(CO)(7)(mu-J003)], have been tested as catalysts/catalyst precursors for intermolecular Pauson-Khand cyclization, using norbornene and phenylacetylene as substrate. The diphosphine-substituted tricobalt carbonyl clusters proved to be viable catalysts/catalyst precursors that gave products in moderate to good yields, but the enantiomeric excesses were low. When t…
Tetramethyl-Bis(ethylenedithio)-Tetrathiafulvalene (TM-BEDT-TTF) Revisited: Crystal Structures, Chiroptical Properties, Theoretical Calculations, and…
2013
The (S,S,S,S) and (R,R,R,R) enantiomers of tetramethyl-bis(ethylenedithio)-tetrathiafulvalene (TM-BEDT-TTF) show equatorial conformation for the four methyl groups in the solid state, according to the single-crystal X-ray analyses. Theoretical calculations at the Density Functional Theory (DFT) and time-dependent (TD) DFT levels indicate higher gas phase stability for the axial conformer than the equatorial one by 1.25kcal center dot mole-1 and allow the assignment of the UV-vis and circular dichroism transitions. A complete series of radical cation salts of 1:1 stoichiometry with the triiodide anion I3- was obtained by electrocrystallization of both enantiopure and racemic forms of the don…
Organic carbonates as alternative solvents for asymmetric hydrogenation
2009
Organic carbonates like propylene carbonate (PC) or butylene carbonate (BC) belong to the class of aprotic, highly dipolar solvents (AHD). Interestingly, their potential as solvents for asymmetric catalysis has been overlooked for a long time. The aim of this work is to evaluate organic carbonates and other organic solvents like THF, CH2Cl2, and acetonitrile as well as members of the AHD-family (DMF, DMSO, etc.) as media for homogeneous asymmetric hydrogenation. For this reason cationic Rh-complexes based on chiral phosphine ligands were tested in the hydrogenation of typical benchmark substrates. In several trials, significant advantages of organic carbonates were found. In contrast to DMS…