Search results for "clathrate"

showing 10 items of 233 documents

2018

Abstract. Sediments containing gas hydrate dispersed in the pore space are known to show a characteristic seismic anomaly which is a high attenuation along with increasing seismic velocities. Currently, this observation cannot be fully explained albeit squirt-flow type mechanisms on the microscale have been speculated to be the cause. Recent major findings from in situ experiments, using the gas in excess and water in excess formation method, and coupled with high-resolution synchrotron-based X-ray micro-tomography, have revealed the systematic presence of thin water films between the quartz grains and the encrusting hydrate. The data obtained from these experiments underwent an image proce…

010504 meteorology & atmospheric sciencesStratigraphyAttenuationFlow (psychology)Clathrate hydratePaleontologySoil ScienceMineralogyGeology010502 geochemistry & geophysics01 natural sciencesSynchrotronlaw.inventionGeophysicsGeochemistry and PetrologylawHydrate bearing sedimentsHydrateQuartzGeologyMicroscale chemistry0105 earth and related environmental sciencesEarth-Surface ProcessesSolid Earth
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Natural gas hydrate investigations by synchrotron radiation X-ray cryo-tomographic microscopy (SRXCTM)

2008

[1] We report the 3D microstructure analyses of natural gas hydrates sampled from Gulf of Mexico. The samples were characterized by synchrotron radiation X-ray cryo-tomographic microscopy (SRXCTM) using the ‘TOMCAT’ beam line at the Swiss Light Source (SLS). The SRXCTM demonstrates its applicability to unlock some microscopic features of the marine hydrates, in particular of crystallite size and grain boundary network. The gas hydrate domains are surrounded by a network of pores of typically a few micrometers, which are largely due to decomposition. Out of the SRXCTM data, the porosity, total volume of the voids, the void surface area and number of the total gas-filled voids have been calcu…

010504 meteorology & atmospheric sciencesbusiness.industryClathrate hydrateSynchrotron radiationMineralogy010502 geochemistry & geophysics01 natural sciencesGeophysicsNatural gasGeneral Earth and Planetary SciencesGrain boundaryCrystallitePorositybusinessHydrateGeologySwiss Light Source0105 earth and related environmental sciencesGeophysical Research Letters
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CCDC 717659: Experimental Crystal Structure Determination

2009

Related Article: K.Raatikainen, J.Huuskonen, M.Lahtinen, P.Metrangolo, K.Rissanen|2009|Chem.Commun.||2160|doi:10.1039/b901473j

17(14)-Dipiperazina-35912(14)-tetrabenzena-1011-diazacyclotridecaphane-10-ene 14-diiodo-2356-tetrafluorobenzene hemikis(chloroform) clathrateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 127936: Experimental Crystal Structure Determination

2001

Related Article: S.Kiviniemi, M.Nissinen, M.T.Lamsa, J.Jalonen, K.Rissanen, J.Pursiainen|2000|New J.Chem.|24|47|doi:10.1039/a907608e

18-Crown-6 bis(imidazolium) clathrate diperchlorateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 196107: Experimental Crystal Structure Determination

2004

Related Article: M.Nissinen, K.Rissanen|2003|Supramol.Chem.|15|581|doi:10.1080/10610270310001605179

281420-tetraethyl-46101216182224-octahydroxycalix(4)arene pyridine clathrate ethanol solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 666841: Experimental Crystal Structure Determination

2008

Related Article: K.Raatikainen, J.Huuskonen, E.Kolehmainen, K.Rissanen|2008|Chem.-Eur.J.|14|3297|doi:10.1002/chem.200701862

3^2^7^2^11^2^15^2^-Tetraamino-15913(14)-tetrapiperazina-371115(13)-tetrabenzenacyclohexadecaphane acetonitrile clathrate dichloromethane solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 104281: Experimental Crystal Structure Determination

1997

Related Article: J.Ratilainen, K.Airola, M.Nieger, M.Bohme, J.Huuskonen, K.Rissanen|1997|Chem.-Eur.J.|3|749|doi:10.1002/chem.19970030515

41016-Tri(14)benzena-359111517-hexaoxa-1713-tri(26)pyridinaoctadecaphane monohydrate clathrateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 149028: Experimental Crystal Structure Determination

2001

Related Article: A.Shivanyuk, M.Saadioui, F.Broda, I.Thondorf, M.O.Vysotsky, K.Rissanen, E.Kolehmainen, V.Bohmer|2004|Chem.-Eur.J.|10|2138|doi:10.1002/chem.200305633

46101216182224-Octahydroxy-281420-tetramethylcalix(4)arene bis(triethylammonium) dichloride clathrate acetonitrile solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 149027: Experimental Crystal Structure Determination

2001

Related Article: A.Shivanyuk, M.Saadioui, F.Broda, I.Thondorf, M.O.Vysotsky, K.Rissanen, E.Kolehmainen, V.Bohmer|2004|Chem.-Eur.J.|10|2138|doi:10.1002/chem.200305633

461618-Tetrahydroxy-10122224-tetrakis(p-tolylsulfonyloxy)-281420-tetraethylcalix(4)arene triethylammonium chloride clathrate ethanol solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 149024: Experimental Crystal Structure Determination

2001

Related Article: A.Shivanyuk, M.Saadioui, F.Broda, I.Thondorf, M.O.Vysotsky, K.Rissanen, E.Kolehmainen, V.Bohmer|2004|Chem.-Eur.J.|10|2138|doi:10.1002/chem.200305633

461618-Tetrahydroxy-10122224-tetrakis(p-tolylsulfonyloxy)-281420-tetrapentylcalix(4)arene bis(triethylammonium) dichloride clathrate acetonitrile solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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