Search results for "complex mixtures"
showing 10 items of 825 documents
A LASER-INDUCED FLUORESCENCE (LIF) METHOD FOR MONITORING OXYGEN–ALKALI DELIGNIFICATION OF SOFTWOOD KRAFT PULP
2002
ABSTRACT A laser-induced fluorescence (LIF) method for monitoring the oxygen–alkali delignification of pine (Pinus sylvestris) kraft pulp was tested. The fluorescence intensity of the effluent was found to increase systematically during treatment as the lignin content of the pulp decreased. This emission method, compared, for example, to a UV/Vis absorption method, seems to have potential for large-scale applications. Owing both to the complex chemical nature of the effluent from oxygen–alkali delignification and to the complex nature of the fluorescence method, further work on this method is needed before it can be used for industrial purposes.
FTIR Monitoring of Chemical Changes in Softwood During Heating
2000
Abstract A multivariate chemometric method for monitoring the mass loss of Scots pine (Pinus sylvestris) and Norway spruce (Picea abies) by IR spectroscopic determination of chemical changes occurring during the heat treatment (160 - 260 °C, 2 - 8 h) of these wood materials was developed. The method was based on the handling of FTIR data on treated and untreated wood powder samples by the partial least squares (PLS) method. In addition, unknown samples (treated and untreated pine and spruce) were classified into separate groups by the principal component analysis (PCA) method. The chemical changes occurring in the wood samples during heating were also briefly discussed.
Thermochemical behavior of Norway spruce ( Picea abies ) at 180-225 °C
2002
Norway spruce (Picea abies) was heated for 2–8 h in the temperature range 180–225 °C, under a steam atmosphere. The chemical analyses of the treated feedstock samples indicated that during heating (total mass loss 1.5–12.5% of the initial DS) carbohydrates (hemicelluloses and cellulose) were clearly more amenable to various degradation reactions than lignin. In addition, major water-soluble products released from the feedstock material during the treatments were classified into several compound groups and changes in the relative mass portion of these groups were monitored by GC during a separate experiment.
Role of rock fragment cover on runoff generation and sediment yield in tilled vineyards
2017
The soil in conventional Mediterranean vineyards is an active and non-sustainable source of sediment and water. Lack of vegetation cover, small soil organic matter content and intense ploughing result in large rates of erosion in a millennia-old tillage system. There is a need for soil conservation strategies that enable sustainability of wine and grape production; therefore, it is essential to measure the rates and to investigate the processes and factors of soil erosion. This study evaluated factors that can reduce soil losses in traditional Mediterranean vineyards. The investigation was carried out with 96 rainfall simulation experiments at the pedon scale (0.24 m2) to measure soil detac…
Mechanisms for Translocation of Heavy Metals from Soil to Epigeal Mosses
2011
The mechanisms for translocation of heavy metals from soil to epigeal mosses were investigated. The first mechanism was demonstrated for (137)Cs and involved the uplifting of the pollutant-containing dust from the soil, followed by the local secondary deposition on surfaces of epigeal mosses and epiphytic lichens. The second mechanism involved the diffusion of metal cations from the soil through water wetting the moss into the gametophyte. The mechanism was demonstrated by measuring the electric conductance of wetted gametophytes with single ends immersed in solutions of Cu and Na salts. In addition, the concentrations of Cu and Cd were compared in moss samples exposed to the natural soil a…
Plant diversity enhances the natural attenuation of polycyclic aromatic compounds (PAHs and oxygenated PAHs) in grassland soils
2019
Increasing plant species richness stimulates microbial activity in soil, which might favor biodegradation of polycyclic aromatic compounds (PACs). To explore the relationship between plant community composition and PACs in grassland soils (Fluvisols exposed to an urban atmosphere), we determined the concentrations of 29 polycyclic aromatic hydrocarbons (PAHs) and 15 oxygenated PAHs (OPAHs) in topsoils of 80 plots of a grassland biodiversity experiment. The plots included different levels of plant species richness (1, 2, 4, 8, 16, 60 species) and 1–4 plant functional groups (grasses, small herbs, tall herbs, and legumes) in a randomized block design. The concentrations (ng g−1) of ∑29PAHs an…
Long-term effects of metal-containing farmyard manure and sewage sludge on soil organic matter in a fluvisol
2005
Abstract Our aim was to establish the long-term effects of repeated applications after 20 y of organic amendments (farmyard manure at 10 t ha −1 y −1 , and urban sewage sludge at two different rates, 10 t ha −1 y −1 and 100 t ha −1 every 2 y) on the quality of a sandy and poorly buffered soil (Fluvisol, pH 6). Chemical characteristics and biodegradability of the labile organic matter, which is mainly derived from microbial biomass and biodegradation products of organic residues, were chosen as indicators for soil quality. The organic C content had reached a maximal value (30.6 g C kg −1 in the 100 t sludge-treated soil), i.e. about 2.5 times that in the control. Six years after the last a…
Field and laboratory approaches for determining sodicity effects on saturated soil hydraulic conductivity
2006
Abstract Dilution of high-sodicity soil water by low-sodicity rainfall or irrigation water can cause declining soil hydraulic conductivity (K) by inducing swelling, aggregate slaking and clay particle dispersion. Investigations of sodicity-induced reduction in K are generally restricted to repacked laboratory cores of air-dried and sieved soil that are saturated and equilibrated with sodic solution before tests are conducted. This approach may not yield a complete picture of sodicity effects in the field, however, because of loss of antecedent soil structure, small sample size, detachment of the sample from the soil profile, reliance on chemical equilibrium, and differing time scales betwee…
Long-term effects of contrasting tillage systems on soil C and N pools and on main microbial groups differ by crop sequence
2021
Abstract Determining the best conservation agriculture practices for increasing soil organic carbon (C) and hence soil quality is of paramount importance in the semi-arid Mediterranean environment, where soils are experiencing a continuous decline in organic matter. Therefore, the aim of this long-term study was to assess the combined effects of tillage system and crop sequence on soil organic C and biochemical properties of soil generally used as indicators of soil quality. After 23 years of continuous application of contrasting tillage systems (conventional tillage [CT], vs. no tillage [NT]) and crop sequences (wheat monoculture vs. wheat-faba bean rotation), soil samples were collected f…
Soil profile dismantlement by land levelling and deep tillage damages soil functioning but not quality
2016
We investigated the effects of land levelling followed by deep tillage, thus inducing a drastic dismantlement of soil profile, on both soil functioning and quality by monitoring various bioindicators (microbial biomass and community structure, basal respiration, enzyme activities) expressed on either whole soil and TOC mass units, respectively. As expected, in disturbed soils all measured properties had much higher coefficients of variation (CVs), regardless of either whole soil or TOC mass basis, due to the induced spatial variability. The amount of total organic C in the first cubic meter of soil profile was of one order of magnitude greater in undisturbed soils compared to disturbed ones…