Search results for "complex"
showing 10 items of 5889 documents
Dioxomolybdenum(VI) complexes of hydrazone phenolate ligands -syntheses and activities in catalytic oxidation reactions
2021
The new cis-dioxomolybdenum(VI) complexes [MoO2(L2)(H2O)] (2) and [MoO2(L3) (H2O)] (3) containing the tridentate hydrazone-based ligands (H2L2 = N'-(3,5-di-tert-butyl-2-hydroxybenzylidene)-4-methylbenzohydrazide and H2L3 = N'-(2-hydroxybenzylidene)-2-(hydroxyimino)propanehydrazide) have been synthesised and characterized via IR, 1H and 13C NMR spectroscopy, mass spectrometry, and single crystal X-ray diffraction analysis. The catalytic activities of complexes 2 and 3, and the analogous known complex [MoO2(L1)(H2O)] (1) (H2L1 = N'-(2-hydroxybenzylidene)-4-methylbenzohydrazide) have been evaluated for various oxidation reactions, viz. oxygen atom transfer from dimethyl sulfoxide to triphenylp…
Jauni ieskati kvantu automātu stāvokļu skaita efektivitātē
2022
Kvantu galīgi automāti var sasniegt eksponenciālu stāvokļu skaitu efektivitāti, salīdzinot ar determinētiem galīgiem automātiem. Viena problēma, kurā ir zināms, ka kvantu galīgiem automātiem ir eksponenciālas priekšrocības, ir MODn problēma, taču nav zināma metode, kā uzkonstruēt tādu kvantu automātu. Šajā darbā eksponenciāli efektīvie MODn algoritmi tiek vispārināti jaunā algoritmā, kas samazina vajadzīgo stāvokļu skaitu. Jaunā algoritma saaistības ar esošiem virzieniem literatūrā tiek aprakstītas, un tiek piedāvātas divas jaunas skaitļu virknes, kuras varētu izmantot, lai uzkonstruētu tādus kvantu automātus.
Preparation and physico-chemical study of inclusion complexes between idebenone and modified beta-cyclodextrins
1996
The inclusion properties of modifiedβ-cyclodextrins (trimethyl-β-cyclodextrin, dimethyl-β-cyclodextrin and hydroxypropyl-β-cyclodextrin) towards idebenone were compared with naturalβ-cyclodextrin. The inclusion complexes were prepared by different methods (coprecipitation, kneading, and freeze-drying) and characterized by differential scanning calorimetry, X-ray diffractometry, UV, CD and NMR spectroscopy. The results obtained by CD and NMR spectroscopy indicate a different orientation of idebenone in dimethyl-β-cyclodextrin with respect to other cyclodextrins. Stability constants of the complexes were determined in water at various temperatures and consequently thermodynamic parameters wer…
On the semantic interpretation of complex causatives in Finnish: An experimental morphology approach
2009
It is well documented that in some languages, such as in Finnish, it is possible to stack derivational morphemes iteratively to word stems. However, such complex words are seldom used in real communication, and it is unclear whether they are interpreted compositionally in tandem with their morphological structure. Here I studied the matter by eliciting semantic interpretations from ten native speakers of Finnish for words whose complexity and morphemic content were systematically varied. The results show that although the frequency of semantic interpretation decreases linearly as a function of the number of morphemes in a word (contrary to the case of ungrammatical words where the semantic …
Durum wheat root and foot rot complex in Sicily
2009
Recipes of success : the case of pulp and paper industry 1989-2015
2017
Explaining the variation in competitive positioning actions across firms in the face of environmental change has long inspired debates in the field of strategic management. Despite the importance of these questions, little effort has been done to examine the complex interdependencies among industry, organizational attributes, and strategic actions that potentially underlie the organizational performance in one model without controlling one or more of the three factors. Most of the studies on competitive dynamics primarily have focused on independently exploring the effects of organizational characteristics or the industry structure on competitive actions and reactions, which, in turn, impac…
Strategies for Exploring Functions from Dynamic Combinatorial Libraries
2020
Dynamic combinatorial chemistry (DCC) is a powerful approach for creating complex chemical systems, giving access to the studies of complexity and exploration of functionality in synthetic systems. However, compared with more advanced living systems, the man‐made chemical systems are still less functional, due to their limited complexity and insufficient kinetic control. Here we start by introducing strategies to enrich the complexity of dynamic combinatorial libraries (DCLs) for exploiting unexpected functions by increasing the species of building blocks and/or templates used. Then, we discuss how dynamic isomerization of photo‐switchable molecules help DCLs increase and alter the systemic…
Information Dynamics of Electric Field Intensity before and during the COVID-19 Pandemic.
2022
This work investigates the temporal statistical structure of time series of electric field (EF) intensity recorded with the aim of exploring the dynamical patterns associated with periods with different human activity in urban areas. The analyzed time series were obtained from a sensor of the EMF RATEL monitoring system installed in the campus area of the University of Novi Sad, Serbia. The sensor performs wideband cumulative EF intensity monitoring of all active commercial EF sources, thus including those linked to human utilization of wireless communication systems. Monitoring was performed continuously during the years 2019 and 2020, allowing us to investigate the effects on the patterns…