Search results for "composite"

The role of micro-structural and mechanical properties in the framework of the model for damage inception and growth from air-filled voids in Polyeth…

2007

An innovative, physical, aging and life model for polymeric insulation systems, founded on damage inception and growth at the level of microscopic cavities, was developed previously by the authors. This paper is focused on the role played by micro-structural and mechanical properties (such as crystallinity and Young's modulus) in the framework of such model. These concepts are applied to the case of LDPE, HDPE and XLPE matrixes. The relevant estimates of damage growth rate and time-to-failure as a function of void size and applied electric field in typical working conditions for HVDC power cables are performed. The results show that, under the assumptions made, the crystallinity level itsel…

Modelling the Water Retention Domain of a Compacted Scaly Clay

2012

A body of experimental data on the water retention behaviour of compacted samples of an Italian scaly clay is analysed. The mechanical and the hydraulic behaviour of compacted samples of this clay are governed by multi-scale arrangement of scales and aggregates, which characterises the compacted clay fabric. At least two different pore networks, namely intra-aggregate and inter-aggregate, may be identified, which interact one with the other along coupled hydro-mechanical paths. The retention behaviour is interpreted in the framework of a comprehensive multi-scale modelling approach recently proposed for compacted clays of low and medium activity, which proves to be able to account for the i…

A new FESEM procedure for assessment of XRD microstructural data of kaolinites

2007

Abstract A sample preparation method for FESEM microstructural analysis of sheet silicates using oriented aggregates on metallic strips parallel to the electronic beam is described. The method allows the easy measurement of thickness of kaolinite crystallites. The results have been compared to the apparent crystallite size measured by XRD The performed measurements for a set of selected kaolinites are in the range 15–60 nm and show a good correlation with XRD crystallite thickness (in the range 11–48 nm) obtained by the Voigt function method.

Influence of delay between dental bleaching with 35% hydrogen peroxide and orthodontic brackets on the bond strength at the enamel/adhesive interface

2019

Background The aim of this study was to evaluate the influence of waiting time between the bleaching with 35% hydrogen peroxide and orthodontic brackets bonding on shear bond strength (SBS) in enamel. Material and Methods Eighty bovine teeth were randomly divided into four groups (G): G1(negative control) and G2, G3 and G4 (experimental groups). The experimental groups were submitted to bleaching. Prior to orthodontic brackets bonding to enamel the procedure was adopted different waiting times, as follows: G2 (1 day); G3 (7 days) and G4 (14 days). It was performed enamel etching (30s), washing water (30s), application of adhesive system followed by photoactivation (20s). A thin layer of com…

Photocatalysis: a promising route for 21st century organic chemistry

2007

One of the main goals of 21st century chemistry is to replace environmentally hazardous processes with energy efficient routes allowing to totally avoid the use and production of harmful chemicals and to maximise the quantity of raw material that ends up in the final product. Selective photocatalytic conversions will play a major role in this evolution and this account shows how photocatalysis is offering an alternative green route for the production of organics.

Improvement of high modulus asphalt mixtures with average quality aggregate and bitumen by application of polymeric additives

2018

Abstract The paper deals with the development of asphalt mixtures for high performing binder and base courses, modified with both commercial and waste polymeric additives, via dry process. The focus was on the mix design of high performing mixtures making use of average quality aggregate and average penetration grade bitumen (as locally available) instead of the usually required high quality components, manly very hard bitumen, thus aiming to improve the reference mixture as made possible by suitable polymers. Mixtures were subjected not only to conventional tests for mix design purposes, but also to advanced tests for performance evaluation such as rutting resistance and fatigue resistance…

VALORIZATION OF ANCHOVY FISHBONE WASTES FOR THE PREPARATION OF BIOPOLYMERIC BASED GREEN COMPOSITES FOR FOOD PACKAGING APPLICATIONS

A FTIR study on low hydration saccharide amorphous matrices: Thermal behaviour of the Water Association Band

2011

Abstract We report a study on the thermal behaviour of the infrared Water Association Band (WAB) in dry binary saccharide–water systems (containing trehalose, sucrose, maltose, and raffinose). This is a follow-up of preceding studies on analogous carboxymyoglobin-saccharide–water ternary systems, which pointed out a mutual protein-matrix influence (coupling). A comparison between binary and ternary systems, for all the saccharides studied, evidences a reduction in the residual water content in the latter and, except for trehalose, a sizable modification in the thermal behaviour, which is discussed in terms of structure and hydrogen bonding properties of the sugars. The study allowed us also…

Assessment of protection treatments for carbonatic stone using nanocomposite coatings

2020

In this paper the effect of the application of four kinds of polymer dispersions containing nanoparticles, used as protectives, on two type of carbonatic lithotypes, White Noto and Comiso stone, is reported. The study was conducted by analysing the contribution of each component of the system. After the structural characterization of the coating itself, the performance of those colloidal systems has been studied upon application on the calcarenites, preferring non-invasive techniques and microdestructive techniques. Effect of the nanoparticles presence on hydrorepellency and roughness of the stone surface and on chromatic changes has also been considered. The tests conducted have proven tha…

Testing Soil Encasing Materials for Measuring Hydraulic Conductivity of a Sandy-Loam Soil by the Cube Methods

2008

The Cube Method (CM) and the Modified Cube Method (MCM) were developed for measuring vertical (K v ) and horizontal (K h ) saturated hydraulic conductivity of a single soil sample. By these methods, a cube of soil is carved out in situ and a suitable material is applied to enclose the cube in a tightly fitting casing before moving the sample to the laboratory. Problems may be associated with the use of gypsum, originally used to encase soil. The suitability of molten wax and expandable polyurethane foam to encase a soil cube was tested for a sandy-loam soil. Wax-treated samples yielded lower conductivity results than untreated samples by a maximum factor of 3.7. The observed discrepancies w…