Search results for "composites"
showing 10 items of 1905 documents
Creep Behavior of Poly(lactic acid) Based Biocomposites
2017
Polymer composites containing natural fibers are receiving growing attention as possible alternatives for composites containing synthetic fibers. The use of biodegradable matrices obtained from renewable sources in replacement for synthetic ones is also increasing. However, only limited information is available about the creep behavior of the obtained composites. In this work, the tensile creep behavior of PLA based composites, containing flax and jute twill weave woven fabrics, produced through compression molding, was investigated. Tensile creep tests were performed at different temperatures (i.e., 40 and 60 °C). The results showed that the creep behavior of the composites is strongly inf…
Characterization of Self-Growing Biomaterials Made of Fungal Mycelium and Various Lignocellulose-Containing Ingredients
2022
In this study, novel blends of mycelium biocomposites (MB) were developed. Various combinations of birch sawdust and hemp shives with birch bark (BB) and wheat bran (WB) additives were inoculated with basidiomycete Trametes versicolor to produce self-growing biomaterials. MB were characterized according to mycelial biomass increment in final samples, changes in chemical composition, elemental (C, H, N) analyses, granulometry of substrates, water-related and mechanical properties, as well as mold resistance and biodegradability. The mycelial biomass in manufactured MB increased by ~100% and ~50% in hemp and sawdust substrates, respectively. The lignocellulose ingredients during fungal growth…
Bis-urea macrocycles with a deep cavity.
2015
Two configurational isomers of bis-urea macrocycles have been synthesized, and their neutral molecule recognition was studied by X-ray crystallography and (1)H NMR experiments. Cooperative action between the deep cavity and the urea groups and the influence of dipole alignments on molecular recognition are discussed.
Preparation and characterization of polyolefin- based nanocomposite blown films for agricultural applications
2009
Polyolefin-based films were prepared in the presence of two different organo-modified clays and characterized. The influence of organo-modifier and matrix composition on film morphology and properties were investigated using SEM, XRD, UV-Vis, FT-IR, contact-angle measurements and mechanical tests. The filler increased the films' rigidity and tear strength. Transparencies were almost unchanged in the visible range, but were reduced for harmful radiation. The presence of the clay increases the greenhouse effect, i.e. it hinders the passage of thermal emission from the soil to the outer part of the greenhouse during the night. The wettability of the materials was not influenced by the presence…
Fluorescent Boron Oxide Nanodisks as Biocompatible Multi-messenger Sensors for Ultrasensitive Ni$^{2+}$ Detection
2023
Boron-based nanocomposites are very promising for a wide range of technological applications, spanning from microelectronics to nanomedicine. A large variety of B-based nanomaterials has been already observed, such as borospherene, B nanotubes and nanoparticles, and boron nitride nanoparticles. However, their fabrication usually involves toxic precursors or leads to very low yields or small boron atom concentration. In this work, we report the synthesis of nanometric B$_{2}$O$_{3}$ nanodisks, a family of nanomaterials with a quasi-2D morphology capable of intense fluorescence in the visible range. Such as boron-based nanomaterial, which we synthesized by pulsed laser ablation of a boron tar…
Raman and optical reflection spectra of germanate and silicate glasses
2005
Abstract Germanate and phosphosilicate glasses made in oxygen surplus conditions were studied by Raman and optical reflection methods. We found that the optical reflection spectra of the germanate glasses are quite similar to the one those of a GeO 2 crystal with the α-quartz structure. The reflection of phosphosilicate glasses is very close to silica glass-related spectra. Hence, the determining influence of the tetrahedral structure on reflection spectra is revealed. The Raman spectra of germanate samples are similar to those reported the one known in the literature. Octahedral entities, namely bands similar to stishovite vibration modes, were difficult to detect in phosphosilicate glasse…
Intraperitoneal adhesions-an ongoing challenge between biomedical engineering and the life sciences
2011
Peritoneal adhesions remain a relevant clinical problem despite the currently available prophylactic barrier materials. So far, the physical separation of traumatized serosa areas using barriers represents the most important clinical strategy for adhesion prevention. However, the optimal material has not yet been found. Further optimization or pharmacological functionalization of these barriers could give an innovative input for peritoneal adhesion prevention. Therefore, a more complete understanding of pathogenesis is required. On the basis of the pathophysiology of adhesion formation the main barriers currently in clinical practice as well as new innovations are discussed in the present r…
Finite-element simulation of residual stress induced by split-sleeve cold-expansion process of holes
2008
A three-dimensional finite-element simulation was conducted for a split-sleeve cold-expansion process in order to determine the residual stress field around an expanded hole. The commercial FEA software DEFORM-3D™, a Lagrangian implicit code designed for metal forming processes, was used to model the cold-expansion process of a fastener hole. The results show a through-thickness residual stress field in good agreement with the analytical solution developed by Guo. Moreover, the simulation has highlighted the effect of the split sleeve and the plate thickness on the residual stress field. © 2007 Elsevier B.V. All rights reserved.
Analytical bonding criteria for joint integrity prediction in friction stir welding of aluminum alloys
2014
Abstract In this study, two bonding criteria, previously used for porthole die extrusion, are applied to FSW starting from the local value of the main field variables calculated through a specifically developed 3D numerical model of the process. Their applicability and effectiveness have been assessed through an experimental and numerical campaign carried out with the main process parameters varying in a wide range. The pressure–time–flow criterion was demonstrated to be better suited for FSW processes when large welding speed is used.
Reinforcement Efficiency of Cellulose Microfibers for the Tensile Stiffness and Strength of Rigid Low-Density Polyurethane Foams
2020
Rigid low-density closed-cell polyurethane (PU) foams are widely used in both thermal insulation and structural applications. The sustainability of PU foam production can be increased by using bio-based components and fillers that ensure both enhanced mechanical properties and higher renewable material content. Such bio-based foams were produced using polyols derived from rapeseed oil and microcrystalline cellulose (MCC) fibers as filler. The effect of MCC fiber loading of up to 10 wt % on the morphology, tensile stiffness, and strength of foams has been evaluated. For estimation of the mechanical reinforcement efficiency of foams, a model allowing for the partial alignment of filler fibers…