Search results for "computing"
showing 10 items of 25279 documents
Rencontres du Clos-Vougeot 2012 - Crises, mutations, innovations : le devenir du monde vitivinicole
2013
International audience
Situation démographique de la Bourgogne et de ses départements, Atelier de réflexion : Entre inadaptations et innovations, le logement social face au…
2014
International audience
Everyday creativity : boosting creative resources with Finnish models of education : teachers' handbook
2019
This Handbook is the result of several conversations and activities that took place during a blended in-service teacher education course “Everyday Creativity – Boosting the internal creative resources of European schools with Finnish models of education for creativity”. This course offered opportunities for teachers from Romania, Hungary, Italy and the Netherlands to map creative practices in their own school communities, come to Finland to reflect on their work in dialogue with Finnish teachers and education experts, and finally implement follow-up projects to further develop their creative pedagogical ideas . Instead of writing textbook-like material, we decided to emphasize teacher parti…
Actual and Potential Pedagogical Use of Tablets in Schools
2013
This study reviews the potential of tablet technology for teaching and learning. In autumn 2012, we conducted a focused survey comprising quantitative and qualitative questions with Finnish teachers (N = 171, from 54 schools). We focused on perceived pedagogical opportunities and the actualized pedagogical potential of tablets at schools. The survey results indicate that the actual usefulness of tablets in schools was significantly less than what teachers perceived as the pedagogical potential. However, the results demonstrate the positive impact these devices are having on teaching and learning, as well as prompting changes in pedagogical perspectives. Teachers stated that tablets can dive…
Characteristics of Intrapreneurs in Scale-Intensive Service Firms
2014
This empirical paper explores the work of employees in charge of service innovation when firms develop and launch new scale-intensive services by addressing two research questions: i) How do employees responsible for service innovation work? and ii) what are the related managerial implications when developing and launching new scale-intensive services? To this end, 21 qualitative, in-depth interviews were conducted with employees in five large scale-intensive service firms. The findings suggest that the involvement of internal professionals is an asset when new scale-intensive services are developed, and that internal professionals act as intrapreneurs when they are involved in the developm…
Palladium-Catalyzed Hydroxycarbonylation of Aryl and Vinyl Bromides by Mixed Acetic Formic Anhydride
2006
The palladium-catalyzed hydroxycarbonylation of aryl and vinyl bromides in the presence of acetic anhydride and lithium formate as a carbon monoxide source has been developed. The combination of palladium(II) acetate with 1,1'-bis(diphenylphosphino)ferrocene (dppf) is an efficient catalytic system when the reaction is carried out at 120 °C.
On the physicochemical properties of pyridohelicenes.
2014
A comprehensive study on the physicochemical properties of a series of mono- and diaza[5]helicenes as well as mono- and diaza[6]helicenes is reported. Through the use of both computational and experimental methods, these helically chiral pyridohelicenes with the nitrogen atom(s) in various positions are characterised according to their inversion barriers, protonation constants and redox potentials. By using DFT calculations, kinetic measurements, UV/Vis titrations, cyclic voltammetry and EPR spectroscopy, a self-contained picture of their behaviour under conventional treatment by heat, acids and oxidising/reducing agents is provided.
Equilibrium and structural studies of complexes with a hexadentate ligand containing amide, amine and pyridyl nitrogen donors. Crystal structures of …
2002
A novel potentially hexadentate ligand, 1,8-bis(2-pyridylcarbamoyl)-3,6-diazaoctane (pyctrien) has been synthesised as its tetrahydrochloride salt; its protonation constants and the stability constants of the copper(II) and nickel(II) chelates have been determined by potentiometry. Amide group deprotonation permits the formation of [MLH−1]+ and [MLH−2] species in all cases, whereas the detection of the neutral or the protonated species depends on the nature of the metal ions. The solid complexes of copper, nickel and cobalt with the neutral and the deprotonated ligand have been synthesised and characterised by IR and UV–VIS spectroscopy. The amidic groups are coordinated through the oxygen …
Allosteric regulation by Mg2+ of the vacuolar H(+)-PPase from Acer pseudoplatanus cells. Ca2+/Mg2+ interactions.
1996
The tonoplast H(+)-PPase was previously characterized in Acer pseudoplatanus cells (Pugin et al (1991) Plant Sci 73, 23-34; Fraichard et al (1993) Plant Physiol Biochem 31, 349-359). Tonoplast vesicles were obtained from vacuoles isolated from protoplasts of A pseudoplatanus suspension cultures and used to study kinetic effects of Mg2+ and Ca2+ on PPi hydrolysis. The concentrations of ionic species (free Mg2+, free PPi, and MgPPi complexes) were calculated with apparent dissociation constants of 55.3 microM for MgPPi and 59.6 microM for CaPPi. Our results indicated that the substrate of the tonoplast PPase was a MgPPi complex and that free Mg2+ was essential for PPi hydrolysis. With fixed f…
Preparation of polyelectrolyte-modified membranes for heavy metal ions removal
2017
ABSTRACTPolyethersulfone membranes were modified by polyelectrolyte (PE) multilayers, made of poly(allylamine hydrochloride) with poly(styrene sulfonate), to remove Cu2+, Zn2+ and Ni2+ heavy metal cations from aqueous solutions in a wide range of metal concentration (50–1200 ppm). After characterization of the modified membranes, the efficiency of the process was estimated for single heavy metal ions solution leading to high rejection rates (>90% for 50 ppm) and good adsorption capacities (7.0–8.5 mg cm−2) whatever the metal ion tested. The stability in time of the modified membranes was proved by repeating successive filtrations with the same membrane. The filtration process was also used …