Search results for "conductivity"
showing 10 items of 1988 documents
<title>Proton conducting polymer electrolytes for electrochromic devices</title>
1997
This report concerns a composite proton electrolyte suitable for use in electrochromic devices. The electrolyte consists of nanosize hydrated oxide (aluminum, silicon or antimonic) particles suspended in a poly(vinyl acetate) matrix. All of the water was strongly bonded, thus making the electrolytes less harmful without considerably decreasing the conductivity. The proton conductivity of the electrolyte was approximately 10-4 S/cm at room temperature, practically independent of its amount of absorbed water.© (1997) COPYRIGHT SPIE--The International Society for Optical Engineering. Downloading of the abstract is permitted for personal use only.
Protonic ceramic fuel cell : elaboration and characterization. Investigation of the BaZr0.8Y0.2O3-d electrolyte by electrochemical impedance spectros…
2021
One of the current global challenges is to find novel, clean and efficient techniques for the energy production. The use of electrochemical cells and hydrogen is one of the solutions. These cells convert the excess energy produced by conventional systems into hydrogen by steam electrolysis. The hydrogen can be stored and transformed into electricity when needed in the fuel cell mode. Among the different electrochemical cells, protonic ceramic electrochemical cells have attracted much attention due to their high efficiency at intermediate temperature (400 – 600 °C). In addition, these systems offer the advantage of not diluting the fuel in electrolysis mode. This thesis work focuses on the e…
Design of experiment approach applied to reducing and oxidizing tolerance of anode supported solid oxide fuel cell. Part I: Microstructure optimizati…
2011
The main drawback of Ni/YSZ anode supports for solid oxide fuel cell application is their low tolerance to reducing and oxidizing (RedOx) atmosphere changes, owing to the Ni/NiO volume variation. This work describes a structured approach based on design of experiments for optimizing the microstructure for RedOx stability enhancement. A full factorial hypercube design and the response surface methodology are applied with the variables and their variation range defined as: (1) NiO proportion (40-60 wt% of the ceramic powders), (2) pore-former proportion (0-30 wt% corresponding to 0-64 vol.%), (3) NiO particle size (0.5-8 mu m) and (4) 8YSZ particle size (0.6-9 mu m).
Tuning Of Organic Heterojunction Conductivity By The Substituents' Electronic Effects In Phthalocyanines For Ambipolar Gas Sensors
2021
Abstract Exploiting organic heterojunction effects in electrical devices are an important strategy to improve the electrical conductivity, which can be utilized into improving the conductometric gas sensors performances. In this endeavor, the present article reports fabrication of organic heterostructures in a bilayer device configuration incorporating octa-substituted nickel phthalocyanines (NiPc) and radical lutetium bis-phthalocyanine (LuPc2) and investigates their sensing properties towards NH3 vapor. NiPc having hexyl sulfanyl, hexyl sulfonyl and p-carboxyphenoxy moieties are synthesized, which electronic effects are electron donating, accepting and moderate accepting, respectively, al…
Bis(2-ethylhexyl)phosphoric acid/bis(2-ethylhexyl)amine mixtures as solvent media for lithium-ions: A dynamical study
2016
Abstract The self-diffusion coefficient, the spin-lattice relaxation times and ionic conductivity of lithium ions in liquid mixtures composed of bis(2-ethylhexyl)amine (BEEA) and bis(2-ethylhexyl)phosphoric acid (HDEHP) have been thoroughly investigated as a function of composition and temperature by NMR spectroscopy and conductometry. While the temperature and composition dependence of diffusion coefficients of lithium ions follow the same trend observed for those of the surfactant molecules, the spin-lattice relaxation times of lithium ions and 1 H are remarkably different. The observed behavior has been interpreted in terms of lithium ions diffusion occurring through its association with…
Development and analysis of the Soil Water Infiltration Global database
2018
27 Pags.- 11 Tabls.- 8 Figs. © Author(s) 2018. This work is distributed under the Creative Commons Attribution 4.0 License.
Analysis of thermally induced flows in the laboratory by geoelectrical 3-D tomography
2010
[1] Many natural bodies as well as materials inside industrial installations, such as the Earth's mantle and the glass inside melting furnaces, exchange matter through convection. These processes result from differences in temperature, density, and chemical concentration. In this analysis, we focus on the visualization of thermally driven flows in the laboratory. In nature and in industrial installations, it is difficult to measure the temperature inside the object of interest directly. We benchmark a new DC-geoelectrical 3-D tomography method for temperature measurements that allows obtaining temperature values without influencing the flow pattern. For verification of the method, we use di…
In-flight temperature of solid micrometric powders during cold spray additive manufacturing
2020
Abstract During cold dynamic gas spray additive manufacturing, the thermal field within particles is generally simplified by a state of an instantaneous uniform distribution over the particle's media at any position inside and outside the De-Laval nozzle. This paper addresses critical discussions using analytical and computational analysis of the transient heat transfer within the solid particles due to the convective exchange with the flowing gas. An analytical criterion depicts conditions of instantaneous uniform temperature over the range of typical cold spray data including various particle thermal conductivity, particle size range, dragging velocities, gas nature and gas setting condit…
Analysis of the dopant segregation effects at the floating zone growth of large silicon crystals
1997
Abstract A computer simulation is carried out to study the dopant concentration fields in the molten zone and in the growing crystal for the floating zone (FZ) growth of large (> 100mm) Si crystals with the needle-eye technique and with feed/crystal rotation. The mathematical model developed in the previous work is used to calculate the shape of the molten zone and the velocity field in the melt. The influence of melt convection on the dopant concentration field is considered. The significance of the rotation scheme of the feed rod and crystal on the dopant distribution is investigated. The calculated dopant concentration directly at the growth interface is used to determine the normalized …
Magnetic field controlled FZ single crystal growth of intermetallic compounds
2005
Abstract Intermetallic rare-earth-transition-metal compounds with their coexistence of magnetic ordering and superconductivity are still of great scientific interest. The crystal growth of bulk single crystals is very often unsuccessful due to an unfavorable solid–liquid interface geometry enclosing concave fringes. The aim of the work is the contactless control of heat and material transport during floating-zone single crystal growth of intermetallic compounds. This control is provided by a tailored design of the electromagnetic field and the resulting electromagnetically driven convection. Numerical simulations for the determination of the electromagnetic field configuration induced by th…