Search results for "conformation"

showing 10 items of 1414 documents

Influence of exogenous and endogenous ions on the properties of BSA

2012

conformational changeBovin serum albuminaggregationmetal ionSettore FIS/07 - Fisica Applicata(Beni Culturali Ambientali Biol.e Medicin)
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Hemoglobin dynamics probed by picosecond wide-angle x-ray scattering

2008

conformational changeprotein dynamicX-ray scattering
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Absence of mutation at the GAP-related domain of the neurofibromatosis type 1 gene in sporadic neurofibrosarcomas and other bone and soft tissue sarc…

1995

The NF1 gene encodes neurofibromin, a GTPase-activating protein containing a GAP-related domain (NF1-GRD) that is capable of downregulating ras by stimulating ras intrinsic GTPase activity. We tested 44 sarcomas, nine of which corresponded to sporadic neurofibrosarcomas, for mutations at the NF1-GRD by the polymerase chain reaction-single strand conformation polymorphism (PCR-SSCP) technique, finding no mutation in every sample tested. We suggest that inactivation of the NF1-GRD by gene mutation seems not to be an important event in the tumorigenesis of sarcomas.

congenital hereditary and neonatal diseases and abnormalitiesCancer ResearchNeurofibromatosis 1DNA Mutational AnalysisBone NeoplasmsSoft Tissue NeoplasmsGTPaseBiologyGene mutationmedicine.disease_causePolymerase Chain ReactionGeneticsmedicineHumansneoplasmsMolecular BiologyGenePolymorphism Single-Stranded ConformationalGeneticsMutationNeurofibromin 1ProteinsSarcomaSingle-strand conformation polymorphismmedicine.diseaseNeurofibromin 1eye diseasesnervous system diseasesNeurofibrosarcomaCancer researchbiology.proteinSarcomaCarcinogenesisCancer Genetics and Cytogenetics
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In vivo discovery of a peptide that prevents CUG-RNA hairpin formation and reverses RNA toxicity in myotonic dystrophy models

2011

6 pages, 5 figures. PMID:21730182[PubMed] PMCID: PMC3141925[Available on 2012/1/19]

congenital hereditary and neonatal diseases and abnormalitiesProtein ConformationRNA-binding proteinProtein Serine-Threonine KinasesBiologyMyotonic dystrophyMyotonin-Protein Kinasedrug discoveryMicechemistry.chemical_compoundnon-coding RNA diseasePeptide Librarymedicinal chemistryDrug DiscoveryGene expressionmedicineAnimalsMyotonic DystrophyMBNL1MultidisciplinaryMusclesdisease modelAlternative splicingRNA-Binding ProteinsRNADystrophyBiological Sciencesmedicine.diseaseRNA secondary structureMolecular biologyDNA-Binding ProteinschemistryRNA splicingDrosophilaTrinucleotide Repeat ExpansionOligopeptides
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Methionine in a protein hydrophobic core drives tight interactions required for assembly of spider silk

2019

Web spiders connect silk proteins, so-called spidroins, into fibers of extraordinary toughness. The spidroin N-terminal domain (NTD) plays a pivotal role in this process: it polymerizes spidroins through a complex mechanism of dimerization. Here we analyze sequences of spidroin NTDs and find an unusually high content of the amino acid methionine. We simultaneously mutate all methionines present in the hydrophobic core of a spidroin NTD from a nursery web spider’s dragline silk to leucine. The mutated NTD is strongly stabilized and folds at the theoretical speed limit. The structure of the mutant is preserved, yet its ability to dimerize is substantially impaired. We find that side chains of…

congenital hereditary and neonatal diseases and abnormalitiesProtein Foldinggenetic structuresProtein ConformationScienceSilkmacromolecular substancesCircular dichroismcomplex mixturesArticleMethionineddc:590ddc:570AnimalsAmino Acid Sequencelcsh:ScienceFluorescence spectroscopySequence Homology Amino AcidfungiQtechnology industry and agricultureSpidersSpectrometry FluorescenceMutationThermodynamicslcsh:QProtein MultimerizationFibroinsSolution-state NMRHydrophobic and Hydrophilic InteractionsAlgorithmsNature Communications
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The room temperature crystal structure of a bacterial phytochrome determined by serial femtosecond crystallography

2016

Scientific reports 6, 35279 (2016). doi:10.1038/srep35279

crystal structure000Protein ConformationREARRANGEMENTSTemperaturePROTEINCrystallography X-RayphytochromeskidetiedeTRANSDUCTIONArticleX-RAY-DIFFRACTIONCHROMOPHORE-BINDING DOMAINGROUND-STATEddc:000RED LIGHT3111 BiomedicineDeinococcusPhytochromesense organsBACTERIOPHYTOCHROMEFLUORESCENCEroom temperatureCrystallizationPHOTOCONVERSION
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Crystal structure of 2-[chloro(4-methoxyphenyl)methyl]-2-(4-methoxyphenyl)-5,5-dimethylcyclohexane-1,3-dione

2016

One of the methyl groups and the 4-meth­oxy­phenyl substituent are in axial positions and the chloro­(4-meth­oxy­phen­yl)methyl substituent is in the equatorial position of the cyclo­hexane ring which adopts a chair conformation. The packing features inversion-symmetric dimeric units and strands along [100] and [010] established by weak C—H⋯O and C—H⋯Cl contacts.

crystal structure010405 organic chemistryStereochemistryCyclohexane conformationSubstituentweak C—H⋯O and C—H⋯Cl inter­actionsGeneral ChemistryCrystal structureMeth-010402 general chemistryCondensed Matter PhysicsRing (chemistry)01 natural sciencesResearch Communications0104 chemical sciencesweak C—H...O and C—H...Cl interactionsHexanelcsh:Chemistrychemistry.chemical_compoundchemistrylcsh:QD1-999General Materials ScienceActa Crystallographica Section E: Crystallographic Communications
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Crystal structure of 1-(2-fluoro­benzo­yl)-2,7-di­meth­oxy­naphthalene

2014

The asymmetric unit of the compound contains two independent conformers. Each conformer is stacked along the a axis to form columns through van der Waals inter­actions only.

crystal structureCrystallographyAromaticityGeneral ChemistryCrystal structureDihedral angleCondensed Matter PhysicsRing (chemistry)Bioinformatics1-aroyl­naphthalene compoundResearch Communicationschemistry.chemical_compoundsymbols.namesakeCrystallographynon-coplanarly accumulated aromatic rings structurechemistryQD901-999symbolsMoleculeGeneral Materials Sciencevan der Waals forceConformational isomerism1-aroylnaphthalene compoundNaphthalenespatial organizationActa Crystallographica Section E: Structure Reports Online
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Crystal structure and Hirshfeld surface analysis of 3-octyl-4-oxo-2,6-bis(3,4,5-trimethoxyphenyl)piperidinium chloride

2018

The title compound was synthesized by a one-pot Mannich condensation reaction. In the crystal, centrosymmetric dimers are linked into layers parallel to (011) by N—H⋯Cl and C—H⋯Cl hydrogen bonds. A Hirshfeld surface analysis indicates that O—H (20.5%) inter­actions make the largest contribution to the crystal packing.

crystal structureCyclohexane conformationCrystal structure010403 inorganic & nuclear chemistryRing (chemistry)01 natural sciencesMedicinal chemistryChlorideResearch CommunicationsCrystalchemistry.chemical_compoundMannich reactionmedicineHirshfeld surface analysisGeneral Materials ScienceBenzeneMannich reactionCrystallography010405 organic chemistryHydrogen bondChemistryGeneral ChemistryCondensed Matter Physics0104 chemical sciencesQD901-999piperidine-4-onemedicine.drugActa Crystallographica Section E Crystallographic Communications
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Crystal structure and Hirshfeld surface analysis of poly[[bis[μ4-N,N′-(1,3,5-oxadiazinane-3,5-diyl)bis(carbamoylmethanoato)]nickel(II)tetrapotassium]…

2021

The complex nickel(II) anion comprises a pseudomacrocyclic hydrazide-based ligand with an L shape. In the crystal, such anions are connected with the potassium cations and the water solvent mol­ecules, forming a three-dimensional polymeric framework, which is stabilized by an extensive system of hydrogen bonds.

crystal structureCyclohexane conformationshape analysischemistry.chemical_elementCrystal structure010402 general chemistryRing (chemistry)01 natural sciencesResearch Communicationspseudomacrocyclic ligandchemistry.chemical_compoundtemplate reactionSHAPE analysisAmidehirshfeld surface analysisHirshfeld surface analysisGeneral Materials ScienceCrystallography010405 organic chemistryHydrogen bondnickel(ii) complexGeneral ChemistryCondensed Matter Physicsnickel(II) complex3. Good health0104 chemical sciencesTemplate reactionNickelCrystallographychemistryQD901-999Hydratehydrazide-based ligand
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