Search results for "cop"

showing 10 items of 25502 documents

.Single-Ion Magnetic Behaviour in an Iron(III) Porphyrin Complex: A Dichotomy Between High Spin and 5/2-3/2 Spin Admixture

2020

International audience; A mononuclear iron(III) porphyrin compound exhibiting unexpectedly slow magnetic relaxation, which is a characteristic of single-ion magnet behaviour, is reported. This behaviour originates from the close proximity (approximate to 550 cm(-1)) of the intermediate-spinS=3/2 excited states to the high-spinS=5/2 ground state. More quantitatively, although the ground state is mostlyS=5/2, a spin-admixture model evidences a sizable contribution (approximate to 15 %) ofS=3/2 to the ground state, which as a consequence experiences large and positive axial anisotropy (D=+19.2 cm(-1)). Frequency-domain EPR spectroscopy allowed them(S)= |+/- 1/2⟩->|+/- 3/2&Rig…

porphyrinoids010402 general chemistry[MATH.MATH-FA]Mathematics [math]/Functional Analysis [math.FA]01 natural sciencesMolecular physicsCatalysislaw.inventionMagnetizationchemistry.chemical_compoundiron[PHYS.QPHY]Physics [physics]/Quantum Physics [quant-ph]lawMössbauer spectroscopy[CHIM.COOR]Chemical Sciences/Coordination chemistryAnisotropyElectron paramagnetic resonanceSpin (physics)010405 organic chemistryChemistryOrganic ChemistryGeneral ChemistryPorphyrin0104 chemical sciences[CHIM.THEO]Chemical Sciences/Theoretical and/or physical chemistryExcited statesingle-ion magnetsdensity functional calculationsmagnetic propertiesGround state
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Effect of Er3+-doping on 65GeS2-25Ga2S3-10CsCl glass probed by annihilating positrons

2019

Abstract Effect of Er3+-doping resulting in pronounced mid-IR fluorescence functionality was examined first in chalcohalide 65GeS2-25Ga2S3-10CsCl glass using positron annihilation lifetime (PAL) spectroscopy. The detected PAL spectra were reconstructed from unconstrained x2-term analysis employing two-state simple trapping model for one kind of positron trapping free-volume defects, the parameterization being performed at the example of 65GeS2-25Ga2S3-10CsCl glass doped with 0.6 at. % of Er3+. The observed decrease in positron trapping rate was proved to be primary void-evolution process in this Er-activated glass, like in many other chalcogenide glasses affected by rare earth doping. The n…

positron trapping reductionPhotoluminescenceMaterials scienceChalcogenide02 engineering and technologyTrapping010402 general chemistry01 natural sciencesMolecular physicsSpectral lineInorganic Chemistrychemistry.chemical_compoundPositron[CHIM]Chemical SciencesElectrical and Electronic EngineeringPhysical and Theoretical ChemistrySpectroscopyComputingMilieux_MISCELLANEOUSSpectroscopyOrganic ChemistryDoping021001 nanoscience & nanotechnologyFluorescenceAtomic and Molecular Physics and Opticschalcohalide glass0104 chemical sciencesElectronic Optical and Magnetic Materialschemistryrare earth dopingphotoluminescence0210 nano-technologyOptical Materials
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Applicazioni della Spettroscopia nel vicino infrarosso (fNIRS) e della Mirror Therapy per la riabilitazione dell’arto superiore in pazienti post-stor…

2021

L’ictus cerebrale negli ultimi 20 anni registra un aumento della sua incidenza sulla popolazione italiana, conseguente anche ad un aumento dell’è demografica media. L’ictus determina un’ampia gamma di deficit funzionali che possono essere recuperati con un progetto riabilitativo mirato ed anche rimanere in parte o in toto permanenti. Negli ultimi anni è stato affermato che l’approccio multidisciplinare sembra essere necessario per contribuire ad un recupero funzionale del paziente in tempi brevi. Cercando di garantire al paziente, quanto più possibile, la restituzione di una vita quanto più autonoma possibile, nell’espletamento delle attività di base di vita quotidiana. Lo scopo dell’interv…

post strokenear infrared spectroscopymirror therapy
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Trilogia su: la dimensione simbolica nell’epoca del post-moderno

2007

post-moderno simbolo psicopatologia
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Useful Evidence by Post-Mortem CT and Stereomicroscopy in Bone Injury: A Case Series from Forensic Practice

2023

The investigation of bone injuries is an essential topic in forensics. We sometimes have to deal with charred or dismembered human remains that have lost soft tissue, making it difficult to diagnose the mechanisms of injury that led to death. Our contribution aims to share with the scientific community how we approached two cases of very different bone injuries and the techniques used to differentiate relevant pathology findings of bone fragments. Two cases are analyzed from the case history of the forensic medicine institute of Palermo. PMCT made it possible to differentiate heat bone lesions from traumatic lesions. The stereomicroscope was superior to PMCT in being able to better characte…

post-mortem CTautopsyHealth Information ManagementSettore MED/43 - Medicina LegaleLeadership and ManagementHealth Policystereomicroscopybone injuryHealth Informaticsvirtopsy.forensicboneburning
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Victims' experiences concerning the actions of the authorities and the coping skills used for surviving partner stalking

2017

Tutkimuksemme on osa suomalaista VARJO-hanketta, jonka tarkoitus on kehittää palveluita eron jälkeisen vainon uhrien tueksi sekä ehkäisevään työhön ja kuntoutukseen liittyviä työmuotoja. Tutkimuksemme aineisto koostui naispuolisten vainon uhrien internetpohjaisen vertaisryhmän aikana käydyistä keskusteluista, joita tarkastelimme sisällönanalyysin avulla. Tutkimuksemme tarkoitus oli lisätä tietoisuutta vainon uhrien kokemuksista liittyen viranomaisten toimintaan ja tutkintaprosessiin sekä selviytymiskeinoista, jotka he kokivat hyödyllisiksi yrittäessään selviytyä eron jälkeisestä vainosta. Löysimme neljä pääluokkaa kuvaamaan uhrien kokemuksia viranomaistoiminnasta ja tutkintaprosessista. Näm…

post-separation stalking domestic violencevertaistukivainoaminencoping skillsselviytyminenpartner stalkingstalkingpeer supportparisuhdeväkivaltaviranomaisetauthorities
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Skutki dokonania czynności prawnej bez zgody tymczasowego nadzorcy sądowego

2019

postepowanie zabezpieczająceczynność zwykłego zarząduzgoda na czynność przekraczającą zakres zwykłego zarządusecurity proceedingsconsent to an activity exceeding the scope of ordinary managementoperation of ordinary managementtymczasowy nadzorca sądowytemporary court supervisiorRejent
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L'ESAME CAPILLAROSCOPICO ORALE: NUOVA METODICA DIAGNOSTICA

2005

The morphological-functional study of microcirculation is of fundamental importance; in fact, the microvascular bed is directly involved both in autoimmune etiopathogenesis pathologies, and in acute and chronic inflammatory etiopathogenesis pathologies. Oral capillaroscopy is a very stimulating method for studying microcirculation, because of the possibility of studying small vessels in vivo by means of a microscope. Today, it is becoming more reliable thanks to the improvement of the observation tools (photography, videomicroscopy).

postnatal hypothyroidismHypothyroidismMouth Diseases/pathologySettore MED/28 - Malattie OdontostomatologicheMicrocirculationCongenital HypothyroidismAutoimmune Diseases/pathologyMicroscopic Angioscopy/method
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Sponge‐Like Behaviour in Isoreticular Cu(Gly‐His‐X) Peptide‐Based Porous Materials

2015

We report two isoreticular 3D peptide-based porous frameworks formed by coordination of the tripeptides Gly-L-His-Gly and Gly-L-His-L-Lys to Cu(II) which display sponge-like behaviour. These porous materials undergo structural collapse upon evacuation that can be reversed by exposure to water vapour, which permits recovery of the original open channel structure. This is further confirmed by sorption studies that reveal that both solids exhibit selective sorption of H2 O while CO2 adsorption does not result in recovery of the original structures. We also show how the pendant aliphatic amine chains, present in the framework from the introduction of the lysine amino acid in the peptidic backbo…

postsynthetic modificationsPeptideTripeptideCatalysismetal–organic frameworksAdsorptionMetalloproteinsPolymer chemistryUreaMoleculePorositywater adsorptionchemistry.chemical_classificationMolecular Structurenanoporous materialsOrganic ChemistrySorptionGeneral ChemistryFull PaperschemistryChemical engineeringpeptidesMetal-organic frameworkAdsorptionPorous mediumOligopeptidesPorosityCopperChemistry – A European Journal
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ELEMENTI RICOSTRUTTIVI DELL’“IMPOSIZIONE SUL TURISMO”: OPPORTUNITÀ E LIMITI NEL CONTESTO DEL C.D. FEDERALISMO FISCALE - PRINCIPLES OF “TOURISM TAXATI…

2012

La “tassazione sul turismo” rappresenta una possibile frontiera di espansione dell’esercizio della potestà tributaria delle Regioni e degli Enti locali, con particolare riferimento ai Comuni. I “tributi sul turismo” rispondono ad esigenze finanziarie territoriali volte a coprire i costi ulteriori derivanti dai flussi turistici, connessi alle funzioni pubbliche (fondamentali e non), sulla base dei principi di autonomia, responsabilità, divieto di doppia imposizione, territorialità e continenza. L’articolo affronta la tematica dei diversi possibili modelli di entrata adottabili de iure condito e de iure condendo, delineandone i limiti costituzionali. Tributo o prelievo corrispettivo? In merit…

potestà impositiva regionale e locale principi di coordinamento turismo principio di territorialità imposta di soggiorno imposta di scopo.Settore IUS/12 - Diritto Tributario
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