Search results for "coupling"
showing 10 items of 1862 documents
A new tetranuclear defective dicubane azide-bridged cobalt(II) complex
2013
Abstract The new tetranuclear cobalt(II) complex with formula [Co4(N3)8(4,5-diazafluoren-9-one)4] (1) is reported. Complex 1 is a cobalt(II) defective dicubane azide-bridged compound showing only azido bridging ligands in the μ1,1– and μ1,1,1– coordination modes. The magnetic properties of 1 are reported. Magnetic susceptibility measurements indicate ferromagnetic coupling. The magnetic data have been fitted to 2 K by considering two different superexchange coupling constants. The out-of-phase signal χM″ displays frequency-dependence below approximately 9 K.
A DFT study of the vicinal 3J(119Sn,13C) and 3J(119Sn,1H) coupling constants in trimethyl- and chlorodimethyl-stannyl propanoates.
2013
Abstract We have tested the performance of DFT protocols, both at the Scalar relativistic ZORA and non-relativistic level of theory, for the calculation of the 3 J( 119 Sn, 13 C) and 3 J( 119 Sn, 1 H) vicinal couplings for a series of flexible organotin(IV) derivatives with formula XMe2SnCHRCHR′COOMe (X = Me, Cl; R, R′ = Me, Ph). A satisfactory agreement between experimental and calculated vicinal couplings has been obtained by taking into account the conformational behaviour of the compounds investigated. The protocols used, mainly the relativistic one, were found to give a correct picture of the populations and a sufficiently high overall performance in calculating the vicinal couplings, …
2018
We present the design, fabrication and characterization of long-range surface plasmon polariton waveguide arrays with materials, mainly silicones, carefully selected with the aim to be used as mechanically flexible single-mode optical interconnections, the so-called “plasmonic arc” working at 1.55µm. The fabricated plasmonic arcs show a TM/TE polarization ratio of ~25 dB. By using the cut-back method, the straight propagation loss at 1.55µm is estimated to 0.5-1 dB/mm and coupling loss to ~1-2 dB/facet after dicing. In the free-standing S-curved configuration, the bending loss of single cladding plasmonic arc is 2.2-2.8 dB/90° at bending radius 2.5 mm. For double cladding plasmonic arcs, it…
Single and Twofold Metal- and Reagent-Free Anodic C-C Cross-Coupling of Phenols with Thiophenes.
2017
The first electrochemical dehydrogenative C-C cross-coupling of thiophenes with phenols has been realized. This sustainable and very simple to perform anodic coupling reaction enables access to two classes of compounds of significant interest. The scope for electrochemical C-H-activating cross-coupling reactions was expanded to sulfur heterocycles. Previously, only various benzoid aromatic systems could be converted, while the application of heterocycles was not successful in the electrochemical C-H-activating cross-coupling reaction. Here, reagent- and metal-free reaction conditions offer a sustainable electrochemical pathway that provides an attractive synthetic method to a broad variety …
Model predictive control for continuous lactide ring‐opening polymerization processes
2020
International audience; Polylactic acid (PLA) is an attractive environment-friendly thermoplastic that is bio-sourced and biodegradable. PLA is industrially produced by the ring-opening polymerization of Lactide. This reaction is sensitive to drifts in the operating conditions and impurities in the raw materials that may affect the reaction rate as well as the polymer properties, which can be very costly in continuous processes. It is therefore crucial to employ a control strategy that allows recovering the nominal conditions and maintaining the desired properties and conversion level in case of drift. Three control strategies are discussed in this paper: Proportional-Integral controller (P…
Cold-atom thermoelectrics
2013
Two coupled reservoirs of cold atoms can be used as a model system to study the thermoelectric effect. [Also see Report by Brantut et al. ]
Global conservative and multipeakon conservative solutions for the modified camassa-holm system with coupling effects
2014
Published version of an article in the journal: Mathematical Problems in Engineering. Also available from the publisher at: http://dx.doi.org/10.1155/2014/606249 This paper investigates the continuation of solutions to the modified coupled two-component Camassa-Holm system after wave breaking. The underlying problem is rather challenging due to the mutual coupling effect between two components in the system. By introducing a novel transformation that makes use of a skillfully defined characteristic and a set of newly defined variables, the original system is converted into a Lagrangian equivalent system, from which the global conservative solution is obtained, which further allows for the e…
Aspects of the characterization of cloverite by solid-state n.m.r. techniques
1993
Abstract Microporous gallophosphate cloverite has been studied by multinuclear ( 13 C, 19 F, 31 P, 71 Ga) solid-state n.m.r. spectroscopy. An extraordinarily strong quadrupolar coupling is shown to be the reason for a misleading line shape in 71 Ga MAS n.m.r. spectra. Using static 71 Ga n.m.r. spectroscopy, an estimate of the size of this quadrupolar coupling can be obtained. The limitations of the MAS technique for the study of quadrupolar nuclei in sites with very large quadrupolar couplings are addressed.
Exploiting Palladium-Catalyzed Cross-Coupling for the Synthesis of 2-Aryl-Substituted 1-Aminocyclopropylphosphonates
2015
A series of 2-aryl-substituted 1-aminocyclopropylphosphonates containing an additional remote phosphonate group have been synthesized starting from readily accessible dimethyl (1 R *,2 R *)-2-(4-bromophenyl)-1-formamidocyclopropylphosphonate using cross-coupling methodology. Different types of palladium-catalyzed reactions for carbon–carbon and carbon–phosphorus bond formation were realized. In each case the optimum conditions were found to obtain the desired products in high yield in both small- and large-scale experiments.
ChemInform Abstract: Synthesis of 3-Triazenopyrroles.
2010
Abstract The 3-triazenopyrroles, a new class of pyrrole derivatives, were synthesized in quantitative yield by coupling 3-diazopyrroles with secondary amines.