Search results for "crystallization"
showing 10 items of 774 documents
CFD simulation of ZnO nanoparticle precipitation in a supercritical water synthesis reactor
2012
International audience; Continuous hydrothermal flow synthesis process has shown great advantages concerning the control of particle size and morphology through the optimization of supercritical water processing parameters. In particular, micromixing is a key issue of the process for controlling the nucleation mechanism. A Computational Fluid Dynamics (CFD) model is suggested for nanoparticle size determination using a population balance approach. Models for reaction kinetics, thermodynamics, nucleation and growth are presented. The effects of base concentration and hydrodynamics are investigated. Results show that the CFD may be valuable simulation tool for controlling the size and the sha…
Nitrofurantoīna kristalizācija un iegūto kristālisko formu ietekmējošie faktori
2017
Nitrofurantoīna kristalizācija un iegūto kristālisko formu ietekmējošie faktori. Trimdale A., darba vadītājs Dr. Chem. Bērziņš A. Maģistra darbs, 60 lappuses, 18 attēli, 13 tabulas, 7 pielikumi, 52 literatūras avoti. Latviešu valodā. Darbā apkopota informācija par cietvielu kristāliskajām formām, kristalizācijas procesu, to ietekmējošajiem faktoriem un kontroles iespējām, kristālisko fāžu un šķīdumu pētījumos izmantotajām metodēm (rentgendifraktometriju, termisko analīzi, protonu kodolmagnētiskās rezonanses spektroskopiju, infrasarkano spektroskopiju, kvantu ķīmiskajiem aprēķiniem) un nitrofurantoīnu. Eksperimentālajā daļā veikta kristalizēšana no dažādiem tīriem organiskajiem šķīdinātājiem…
Mercaptophenol-Protected Gold Colloids as Nuclei for the Crystallization of Inorganic Minerals: Templated Crystallization on Curved Surfaces
1999
The self-assembly of monolayers of thiols on gold(111) surfaces yields substrates that are able to template in a controlled manner, the nucleation and growth of crystals of calcium carbonate from solution. In the absence of additives, various factors such as the nature of the thiol, the temperature, and the pH are now established as influencing the nature and relative amounts of the different CaCO3 phases (calcite, vaterite, and aragonite). Recently, we have been able to extend the use of thiol/gold self-assembled monolayers as templates for the growth of inorganic crystals by utilizing protected gold colloids instead of flat gold surfaces. The thiol monolayers that protect the colloids pro…
Mechanochemical Access to Defect-Stabilized Amorphous Calcium Carbonate
2018
Amorphous calcium carbonate (ACC) is an important precursor in the biomineralization of crystalline CaCO3. The lifetime of transient ACC in nature is regulated by an organic matrix, to use it as an intermediate storage buffer or as a permanent structural element. The relevance of ACC in material science is related to our understanding of CaCO3 crystallization pathways. ACC can be obtained by liquid–liquid phase separation, and it is typically stabilized with the help of macromolecules. We have prepared ACC by milling calcite in a planetary ball mill. The ball-milled amorphous calcium carbonate (BM-ACC) was stabilized with small amounts of Na2CO3. The addition of foreign ions in form of Na2C…
New approach for quantifying water depth applied to the enigma of drowning of carbonate platforms
2002
This research illustrates application of a fluid-inclusion technique for quantifying water depth of ancient carbonate platforms. Jurassic limestones of Monte Kumeta, Italy, were cemented with submarine calcite during a transition to carbonate platform termination. The calcite cements contain fluid inclusions consisting of Jurassic seawater and immiscible gas bubbles trapped during the growth and penecontemporaneous recrystallization of the cements. Crushing analysis indicates that gas bubbles are under pressures indicative of entrapment in water depths of 23–112 m. Assuming simple deepening and acknowledging chronostratigraphic errors, rates of relative rise in sea level were initially less…
Calcitic radial palisadic fabric in freshwater stromatolites: diagenetic and recrystallized feature or physicochemical sinter crust?
1999
Abstract When favorable conditions occur for carbonate precipitation (physicochemical processes) in tufas and travertines, organisms intervene either directly (the framework created by organisms acts as a crystal support) or indirectly (organic products influencing the mineralogy, nucleation, growth and habit of primary crystals). In the literature, fluvial and travertine crystalline sparite crusts with palisadic or prismatic crystals are generally interpreted as the result of early recrystallization of micrite in algal buildups (mostly composed of Schizothrix). Therefore, biological mediation is essential for the construction of continental bioherms and biostromes, even if organic remains …
Early homogenous amorphous precursor stages of calcium carbonate and subsequent crystal growth in levitated droplets.
2008
An in situ study of the contact-free crystallization of calcium carbonate in acoustic levitated droplets is reported. The levitated droplet technique allows an in situ monitoring of the crystallization while avoiding any foreign phase boundaries that may influence the precipitation process by heterogeneous nucleation. The diffusion-controlled precipitation of CaCO3 at neutral pH starts in the initial step with the homogeneous formation of a stable, nanosized liquid-like amorphous calcium carbonate phase that undergoes in a subsequent step a solution-assisted transformation to calcite. Cryogenic scanning electron microscopy studies indicate that precipitation is not induced at the solution/a…
Calcium phosphate precipitation in a SBR operated for EBPR: interactions with the biological process.
2008
The aim of this paper is to study the precipitation process in a sequencing batch reactor (SBR) operated for EBPR (enhanced biological phosphorus removal) and the possible effects of this phosphorus precipitation in the biological process. Four experiments were carried out under different influent calcium concentration. The experimental results and the equilibrium study, based on the Saturation Index calculation, confirm that the process controlling the calcium behaviour in a SBR operated for EBPR is the calcium phosphate precipitation. This precipitation takes place at two stages initially precipitation of the ACP and later crystallization of HAP. Also the accumulation of phosphorus precip…
Phosphorus recovery by struvite crystallization in WWTPs: Influence of the sludge treatment line operation
2010
Phosphorus recovery by struvite (MgNH(4)PO(4).6H(2)O) crystallization is one of the most widely recommended technologies for treating sludge digester liquors especially in wastewater treatments plants (WWTP) with enhanced biological phosphorus removal (EBPR). In this paper, phosphorus recovery by struvite crystallization is assessed using the rejected liquors resulting from four different operational strategies of the sludge treatment line. Phosphorus precipitation and recovery efficiencies of between 80-90% and 70-85%, respectively, were achieved in the four experiments. The precipitates formed were mainly struvite, followed by amorphous calcium phosphate and, in some experiments, by calci…
Crystallized nano-sized alpha-tricalcium phosphate from amorphous calcium phosphate: microstructure, cementation and cell response
2015
New insight on the conversion of amorphous calcium phosphate (ACP) to nano-sized alpha tricalcium phosphate (α-TCP) provides a faster pathway to calcium phosphate bone cements. In this work, synthesized ACP powders were treated with either water or ethanol, dried, crystallized between 700 and 800 °C, and then cooled at different cooling rates. Particle size was measured in a scanning electron microscope, but crystallite size calculated by Rietveld analysis. Phase composition and bonding in the crystallized powder was assessed by x-ray diffraction and Fourier-transform infrared spectroscopy. Results showed that 50 nm sized α-TCP formed after crystallization of lyophilized powders. Water trea…