Search results for "cyano"
showing 10 items of 1058 documents
CCDC 178749: Experimental Crystal Structure Determination
2002
Related Article: J.Vicente, J.-A.Abad, A.D.Frankland, J.Lopez-Serrano, M.C.R.de Arellano, P.G.Jones|2002|Organometallics|21|272|doi:10.1021/om0104971
CCDC 1567348: Experimental Crystal Structure Determination
2017
Related Article: Maria-Gabriela Alexandru, Diana Visinescu, Sergiu Shova, Francesc Lloret, and Miguel Julve|2017|Inorg.Chem.|56|12594|doi:10.1021/acs.inorgchem.7b02050
CCDC 1567349: Experimental Crystal Structure Determination
2017
Related Article: Maria-Gabriela Alexandru, Diana Visinescu, Sergiu Shova, Francesc Lloret, and Miguel Julve|2017|Inorg.Chem.|56|12594|doi:10.1021/acs.inorgchem.7b02050
CCDC 188644: Experimental Crystal Structure Determination
2003
Related Article: I.Muga, J.M.Gutierrez-Zorrilla, P.Vitoria, P.Roman, F.Lloret|2002|Polyhedron|21|2631|doi:10.1016/S0277-5387(02)01240-8
Aza and cyanobridged tripodal dinuclear copper(II) complexes: Electrochemical studies and structural evidence for an original azacyanocarbanion
2014
International audience; The reactivity of the mononuclear [Cu(TMPA)(L)] n+ complex (TMPA: tris(2-methylpyridine) amine, L: CH3CN, H2O) towards two different bridging species (tetracyanoethylene, 4,40-bipyridine) was investigated. The dinuclear complex [(mu-4,40-bipy)Cu-II(TMPA)(2)](CF3SO3)(4) (1) was synthesised and analysed by Xray diffraction (XRD). Magnetic studies revealed that this derivative displays very weak antiferromagnetic interactions between the two metal centres (2J = -0.69 cm(-1)). Solution studies (EPR spectroscopy and voltammetry) evidenced the lability of the bridged neutral bipyridine ligand in acetonitrile. The reaction of TCNE (TCNE: tetracyanoethylene) with the copper(…
Selective Metal–Ligand Bond-Breaking Driven by Weak Intermolecular Interactions: From Metamagnetic Mn(III)-Monomer to Hexacyanoferrate(II)-Bridged Me…
2020
Metal–ligand coordination interactions are usually much stronger than weak intermolecular interactions. Nevertheless, here, we show experimental evidence and theoretical confirmation of a very rare...
Magnetostructural correlations in CuII−NC−WV linkage: the case of [CuII(diimine)]2+−[WV(CN)8]3− 0D assemblies
2009
International audience; We report on the syntheses, crystal structures, and magnetic properties of two cyano-bridged molecular assemblies: [CuII(phen)3]2{[CuII(phen)2]2[WV(CN)8]2}(ClO4)2·10H2O (phen = 1,10-phenanthroline) (1) and {[CuII(bpy)2]2[WV(CN)8]} {[CuII(bpy)2][WV(CN)8]}·4H2O (bpy = 2,2′-bipyridyl) (2). Compound 1 consists of cyano-bridged [CuII2WV2]2− molecular rectangles and isolated [CuII(phen)3]2+ complexes. The molecular structure of 2 reveals cyano-bridged trinuclear [CuII2WV]+ and dinuclear [CuIIWV]− ions. Magnetic interactions in 1 are interpreted in terms of the model of a tetranuclear moiety consisting of two ferromagnetic CuII−NC−WV units (J1 = +39(4) cm−1) interacting ant…
’Structural constraints in cyanobacteria-mediated whole-cell biotransformation of methoxylated and methylated derivatives of 2′-hydroxychalcone
2019
Halophilic and freshwater strains of cyanobacteria representing the Oscillatoriales, Nostocales, Chroococcales, and Synechococcales orders of Cyanophyta were examined to determine (i) the resistance of their cultures when suppressed by the presence of exogenous methoxylated and methylated derivatives of 2'-hydroxychalcone, (ii) morphological changes in cells treated with the tested chalcones and, most importantly, (iii) whether these photoautotrophic microorganisms transform chalcone derivatives in a structure- or strain-dependent manner. The growth of cyanobacterial cultures depended on chalcone derivatives and the strain; nevertheless, trends for correlations between these parameters are …
Algae in Biotechnological Processes
2018
As photoautotrophic organisms, algae possess all of the valuable features that determine their role as the primary producers in the biosphere. A wide range of tolerance based on their extremely efficient adaptation to biochemical processes, as well as the specific cellular structure of these organisms, when correlated with the ecological plasticity of microalgae in particular, predispose these biota to growing and developing under either laboratory or industrial conditions. Hence, the natural features of algae have opened wide the door for the multidirectional biotechnological use of these organisms, with a dynamically growing number of such applications fully supporting this thesis. Among …
The aminophosphonate glyphosine enhances phycobiliprotein yields from selected cyanobacterial cultures
2017
Among added-value products obtained from cyanobacterial cultures are phycobiliproteins, photosynthetic pigments that have found an increasing number of applications as natural dyes for food, cosmetics, pharmaceuticals, and antioxidants. To obtain sustainable production, we aimed at maximizing phycobilin yield through the increase of either the final biomass or the specific content of these pigments by varying culture parameters, such as chemical composition and pH of the medium or quality and intensity of the light. Here, we report that the addition to the culture medium of millimolar or submillimolar concentrations of the aminophosphonate glyphosine [(N,N-bis(phosphonomethyl)glycine], form…