Search results for "cycle"
showing 10 items of 3119 documents
Spin Cross-Over (SCO) Complex Based on Unsymmetrical Functionalized Triazacyclononane Ligand: Structural Characterization and Magnetic Properties
2019
International audience; The unsymmetrical ligand 1-(2-aminophenyl)-4,7-bis(pyridin-2-ylmethyl)-1,4,7-triazacyclononane (L6) has been prepared and characterized by NMR spectroscopy. The L6 ligand is based on the triazamacrocycle (tacn) ring that is functionalized by two flexible 2-pyridylmethyl and one rigid 2-aminophenyl groups. Reaction of this ligand with Fe(ClO4)2·xH2O led to the complex [Fe(L6)](ClO4)2 (1), which was characterized as the first Fe(II) complex based on the unsymmetrical N-functionalized tacn ligand. The crystal structure revealed a discrete monomeric [FeL6]2+ entity in which the unsymmetrical N-functionalized triazacyclononane molecule (L6) acts as hexadentate ligand. As …
A C(π-hole)⋯Cl-Zn tetrel interaction driving a metal-organic supramolecular assembly
2020
A brominated pyrimidinyl triazolopyridine ligand (bptpy) forms a C(π-hole)⋯Cl-Zn tetrel interaction that plays a determining role in the formation of supramolecular layers through chain assembly in 18 membered metallacycle [(ZnCl2)2(μ-bptpy)2] crystals. Supramolecular chains are formed through C-H⋯X interactions. The observed interactions are supported by DFT calculations using model dimers. This journal is
2,5-Bis[(E)-2-phenylethenyl]-3,6-bis(pyridin-2-yl)pyrazine
2020
The molecule of the title compound, C30H22N4, exhibits inversion symmetry adopting the shape of a St Andrew's Cross. It shows dihedral angles between adjacent aryl units of around 50° whereas torsion angles of ca 10° are found along the arylene vinylene path.
Sonnenbarke und zyklisches Weltbild. Überlegungen zum Verständnis der spätbronzezeitlichen Ikonographie in Mitteleuropa
2005
International audience
Effects of Gliding Properties of Cross-Country Skis on the Force Production during Skating Technique in Elite Cross-Country Skiers
2013
The aim of the present study was to examine how different gliding conditions of skis affect performance, cycle characteristics and leg and pole force production during V2 skating. Ten elite skiers skied on 100 m uphill (4°) at three different constant speeds (4.0, 4.8 and 5.6 m/s) and maximum speed using two differently prepared skating skis (fast and slow ski). With the slow ski, maximum speed was 6.4 % slower than with the fast ski. With constant speeds, cycle time got shorter due to a decrease in the recovery time of the leg and pole. Peak pole force and average cycle force increased as well as lateral leg forces while there were no changes in the vertical leg forces. A strategy for how…
Numerical and Experimentical Study of Motion Control Using Pressure Feedback
2013
This paper is concerned with the inherent oscillatory nature of pressure compensated motion control of a hydraulic cylinder subjected to a negative load and suspended by means of an overcenter valve. A pressure feedback scheme that indirectly eliminates the oscillations is investigated. The indirect control scheme utilizes pressure feedback to electronically compensate the metering-out allowing for the removal of the compensator and, subsequently, elimination of the oscillations. The suggested electronic compensation scheme is implemented and examined in a single degree-of-freedom test rig actuated by means of a double acting hydraulic cylinder. The control scheme is compared with other con…
Versatile Direct and Transpose Matrix Multiplication with Chained Operations: An Optimized Architecture Using Circulant Matrices
2016
With growing demands in real-time control, classification or prediction, algorithms become more complex while low power and small size devices are required. Matrix multiplication (direct or transpose) is common for such computation algorithms. In numerous algorithms, it is also required to perform matrix multiplication repeatedly, where the result of a multiplication is further multiplied again. This work describes a versatile computation procedure and architecture: one of the matrices is stored in internal memory in its circulant form, then, a sequence of direct or transpose multiplications can be performed without timing penalty. The architecture proposes a RAM-ALU block for each matrix c…
Synthesizing on a reconfigurable chip an autonomous robot image processing system
2003
This paper deals with the implementation, in a high density reconfigurable device, of an entire log-polar image processing system. The log-polar vision reduces the amount of data to be stored and processed, simplifying several vision algorithms and making it possible the implementation of a complete processing system on a single chip. This image processing system is specially appropriated for autonomous robotic navigation, since these platforms have typically power consumption, size and weight restrictions. Furthermore, the image processing algorithms involved are time consuming and many times they have also real-time restrictions. A reconfigurable approach on a single chip combines hardwar…
Miltirone Induces G2/M Cell Cycle Arrest and Apoptosis in CCRF-CEM Acute Lymphoblastic Leukemia Cells
2015
Miltirone (1) is a diterpene quinone extracted from a well-known Chinese traditional herb (Salvia miltiorrhiza). We investigated the cytotoxic effects of miltirone toward sensitive and multidrug-resistant acute lymphoblastic leukemia cell lines. Miltirone inhibited multidrug-resistant P-glycoprotein (P-gp)-overexpressing CEM/ADR5000 cells better than drug-sensitive CCRF-CEM wild-type cells, a phenomenon termed collateral sensitivity. Flow cytometric analyses revealed that miltirone induced G2/M arrest and apoptosis. Furthermore, miltirone stimulated reactive oxygen species (ROS) generation and mitochondrial membrane potential (MMP) disruption, which in turn induced DNA damage and activation…
Ikaros-1 couples cell cycle arrest of late striatal precursors with neurogenesis of enkephalinergic neurons
2010
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