6533b861fe1ef96bd12c4eab

RESEARCH PRODUCT

A C(π-hole)⋯Cl-Zn tetrel interaction driving a metal-organic supramolecular assembly

Carmen Ramírez De ArellanoEmilio EscrivàIbon AlkortaRafael Ballesteros-garridoBelén AbarcaJosé ElgueroRosa AdamRafael Ballesteros

subject

CrystallographyChemistryLigandSupramolecular chemistryGeneral Materials ScienceTriazolopyridineGeneral ChemistryMetallacycleCondensed Matter PhysicsSupramolecular assembly

description

A brominated pyrimidinyl triazolopyridine ligand (bptpy) forms a C(π-hole)⋯Cl-Zn tetrel interaction that plays a determining role in the formation of supramolecular layers through chain assembly in 18 membered metallacycle [(ZnCl2)2(μ-bptpy)2] crystals. Supramolecular chains are formed through C-H⋯X interactions. The observed interactions are supported by DFT calculations using model dimers. This journal is

yearjournalcountryeditionlanguage
2020-01-01CrystEngComm 22: 6979-6982 (2020)
10.1039/d0ce01272fhttp://hdl.handle.net/10261/224595